2-Methyl-[1,1'-biphenyl]-3-carbaldehyde
- Product Name
- 2-Methyl-[1,1'-biphenyl]-3-carbaldehyde
- CAS No.
- 89951-60-0
- Chemical Name
- 2-Methyl-[1,1'-biphenyl]-3-carbaldehyde
- Synonyms
- 2-methyl-3-phenylbenzaldehyde;2-Methyl-[1,1'-biphenyl]-3-carbaldehyde
- CBNumber
- CB03334786
- Molecular Formula
- C14H12O
- Formula Weight
- 196.24
- MOL File
- 89951-60-0.mol
2-Methyl-[1,1'-biphenyl]-3-carbaldehyde Property
- Boiling point:
- 326.2±21.0 °C(Predicted)
- Density
- 1.074±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- Appearance
- White to light yellow Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M335305
- Product name
- 2-Methyl-[1,1''-biphenyl]-3-carbaldehyde
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- M335305
- Product name
- 2-Methyl-[1,1''-biphenyl]-3-carbaldehyde
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 4096DA
- Product name
- 2-Methyl-[1,1'-biphenyl]-3-carbaldehyde
- Packaging
- 1g
- Price
- $157
- Updated
- 2021/12/16
- Product number
- 4096DA
- Product name
- 2-Methyl-[1,1'-biphenyl]-3-carbaldehyde
- Packaging
- 5g
- Price
- $428
- Updated
- 2021/12/16
- Product number
- CD43000910
- Product name
- 2-Methyl-[1,1'-biphenyl]-3-carbaldehyde
- Purity
- 95+%
- Packaging
- 1g
- Price
- $59
- Updated
- 2021/12/16
2-Methyl-[1,1'-biphenyl]-3-carbaldehyde Chemical Properties,Usage,Production
Synthesis
76350-90-8
89951-60-0
General procedure for the synthesis of 2-methyl-[1,1'-biphenyl]-3-carbaldehyde from 2-methyl-3-phenylbenzenemethanol: To a solution of dichloromethane (60 mL) containing (2-methylbiphenyl-3-yl)methanol (TCI, Art. No. H0777, 4.12 g, 20.8 mmol) was slowly added Dess-Martin periodinane ( 9.25 g, 21.8 mmol). The reaction mixture was stirred at room temperature for 30 minutes. After completion of the reaction, the reaction mixture was washed sequentially with saturated NaHCO3 solution, water and brine. The organic layer was separated, dried with anhydrous Na2SO4, filtered and concentrated under reduced pressure. The crude product was purified by fast chromatography on silica gel column with gradient elution of hexane solution with eluent from 0 to 30% ethyl acetate to obtain the target product 2-methyl-[1,1'-biphenyl]-3-carboxaldehyde (3.30 g, 80% yield).Results of LC-MS analysis: Calculated value of C14H13O(M + H)+: m/z = 197.2; Measured value: 197.2.
References
[1] Patent: US2017/320875, 2017, A1. Location in patent: Paragraph 0298-0299
[2] Patent: US2018/177784, 2018, A1. Location in patent: Paragraph 0522-0523
[3] Patent: WO2017/87777, 2017, A1. Location in patent: Page/Page column 61-62
2-Methyl-[1,1'-biphenyl]-3-carbaldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
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