4-(BENZYLAMINO)PHENOL

Product Name: 4-(BENZYLAMINO)PHENOL
CAS No.: 103-14-0
Chemical Name: 4-(BENZYLAMINO)PHENOL
Synonyms: 4-(Benzylamino);P-BENZYLAMINOPHENOL;p-Benzylaminoethanol;4-(BENZYLAMINO)PHENOL;p-(benzylamino)-pheno;4-n-benzylaminophenol;N-Benzyl-p-aminophenol;4-(N-Benzylamino)phenol;p-(N-Benzylamino)phenol;Phenol, p-(benzylamino)-
CBNumber: CB0366678
Molecular Formula: C13H13NO
Formula Weight: 199.25
MOL File: 103-14-0.mol

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4-(BENZYLAMINO)PHENOL Property

Melting point:: 83 °C
Boiling point:: 195 °C / 5mmHg
Density: 1.0671 (rough estimate)
refractive index: 1.5500 (estimate)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
pka: 11.00±0.26(Predicted)
BRN: 1874039
CAS DataBase Reference: 103-14-0(CAS DataBase Reference)
EPA Substance Registry System: Phenol, 4-[(phenylmethyl)amino]- (103-14-0)

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Safety

Risk Statements: 20/21/22
Safety Statements: 26-36/37/39
RTECS: SJ7580000
TSCA: TSCA listed
HazardClass: IRRITANT
HS Code: 2922290090
Toxicity: LDLo orl-rat: 500 mg/kg JPETAB 90,260,47

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Biosynth Carbosynth

Product number: FB122210
Product name: 4-(Benzylamino)phenol
Packaging: 250mg
Price: $50
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB122210
Product name: 4-(Benzylamino)phenol
Packaging: 500mg
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 062870
Product name: 4-(Benzylamino)phenol
Packaging: 500mg
Price: $88
Updated: 2021/12/16

Apolloscientific

Product number: OR21741
Product name: 4-(Benzylamino)phenol
Purity: 98%
Packaging: 1g
Price: $96
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4756-1-46
Product name: 4-(Benzylamino)phenol
Packaging: 1g
Price: $114
Updated: 2021/12/16

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4-(BENZYLAMINO)PHENOL Chemical Properties,Usage,Production

Chemical Properties

Light brown powder. Solubility of 50% in anhydrous methanol, 50% in 95% ethanol, 0.06% in water; 0.1–0.5% in gasoline, varying with chemical nature of gasoline.

Uses

In cracked gasoline, in concentration of 0.001– 0.004% by weight to prevent gum formation.

Synthesis Reference(s)

Tetrahedron Letters, 20, p. 2733, 1979 DOI: 10.1016/S0040-4039(01)86401-7

Safety Profile

Moderately toxic by ingestion.When heated to decomposition it emits toxic vapors ofNOx.

Synthesis

123-30-8

100-52-7

103-14-0

General method: 4-Aminophenol (1.1 eq.) and benzaldehyde (1 eq.) were dissolved in CH2Cl2 or toluene, Hantzsch ester (1.2 eq.) and S-benzyl isothiourea chloride (0.1 eq.) were added. The reaction mixture was stirred for 12 hours at room temperature (using CH2Cl2 as solvent) or at 70 °C (using toluene as solvent). After completion of the reaction, the mixture was filtered to recover the catalyst and washed several times with CH2Cl2. The filtrate was evaporated and the residue was purified by fast chromatography to give pure p-benzylaminophenol.

References

[1] Tetrahedron Letters, 2011, vol. 52, # 39, p. 5004 - 5007
[2] Journal of the American Chemical Society, 2018, vol. 140, # 23, p. 7292 - 7300
[3] Catalysis Science and Technology, 2016, vol. 6, # 12, p. 4554 - 4564
[4] Journal of Fluorine Chemistry, 2010, vol. 131, # 8, p. 879 - 882
[5] Journal of Chemical Research, 2009, # 11, p. 686 - 688

4-(BENZYLAMINO)PHENOL Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(BENZYLAMINO)PHENOL Suppliers

Belgium 1 China 52 Germany 2 India 1 Japan 1 United Kingdom 5 United States 9 Global 71

J & K SCIENTIFIC LTD.

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Amadis Chemical Company Limited

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View Lastest Price from 4-(BENZYLAMINO)PHENOL manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: 4-(BENZYLAMINO)PHENOL 103-14-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: 4-(BENZYLAMINO)PHENOL 103-14-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-01-14

103-14-0, 4-(BENZYLAMINO)PHENOLRelated Search:

4-Aminophenol N-(2-Hydroxynaphthoyl)-2,4-dimethoxy-5-chloroanilide 2-CHLORO-N-(4-HYDROXYPHENYL)BENZAMIDE 3-Hydroxy-4'-methoxy-2-naphthanilide 2-Hydroxy-N-(4-hydroxyphenyl)-benzamide N-(4-HYDROXYPHENYL)PHTHALIMIDE 4-CHLORO-N-(4-ETHOXYPHENYL)BENZAMIDE 4-CHLORO-N-(4-HYDROXYPHENYL)BENZAMIDE N-(4-METHOXY-PHENYL)-PHTHALAMIC ACID N-(3,4-DIMETHOXYBENZYL)-4-METHOXYANILINE P-BENZANISIDIDE 3-(benzylamino)phenol 4-methoxy-N-[(4-methoxyphenyl)methyl]aniline 2,4-dichloro-N-(4-hydroxyphenyl)benzamide N-[(4-chlorophenyl)methyl]-4-ethoxyaniline 2-[(4-ETHOXY-PHENYLAMINO)-METHYL]-PHENOL AURORA 6742

n-(4-hydroxyphenyl)benzylamine

N-Benzyl-p-aminophenol

p-(benzylamino)-pheno

p-Benzylaminoethanol

Phenol, 4-[(phenylmethyl)amino]-

Phenol, p-(benzylamino)-

N-BENZYL-4-HYDROXYANILINE

P-BENZYLAMINOPHENOL

4-((phenylmethyl)amino)-pheno

4-(N-Benzylamino)phenol

4-(BENZYLAMINO)PHENOL

4-(Benzylamino)phenol 98%

4-[(Phenylmethyl)amino]phenol

4-n-benzylaminophenol

p-(N-Methylphenylamino)phenol

p-(N-Benzylamino)phenol

N-Benzyl-4-hydroxyaniline, N-(4-Hydroxyphenyl)benzylamine

4-(Benzylamino)

103-14-0