1-Pyrenecarboxaldehyde
- Product Name
- 1-Pyrenecarboxaldehyde
- CAS No.
- 3029-19-4
- Chemical Name
- 1-Pyrenecarboxaldehyde
- Synonyms
- PYRENE-1-CARBOXALDEHYDE;Pyrene-1-carbaldehyde;1-FORMYLPYRENE;pyrene-1-aldehyde;NSC 30811;Pyrenaldehyde;3-Formylpyrene;1-Pyrenaldehyde;1-PyrenecarboxaL;1-Pyrenealdehyde
- CBNumber
- CB0373236
- Molecular Formula
- C17H10O
- Formula Weight
- 230.26
- MOL File
- 3029-19-4.mol
1-Pyrenecarboxaldehyde Property
- Melting point:
- 123-126 °C (lit.)
- Boiling point:
- 312.25°C (rough estimate)
- Density
- 1.1350 (rough estimate)
- refractive index
- 1.4500 (estimate)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Solid
- color
- yellow
- Water Solubility
- Insoluble in water.
- Sensitive
- Air Sensitive
- BRN
- 1874889
- InChI
- InChI=1S/C17H10O/c18-10-14-7-6-13-5-4-11-2-1-3-12-8-9-15(14)17(13)16(11)12/h1-10H
- InChIKey
- RCYFOPUXRMOLQM-UHFFFAOYSA-N
- SMILES
- C1(C=O)=C2C3=C4C(C=C2)=CC=CC4=CC=C3C=C1
- CAS DataBase Reference
- 3029-19-4(CAS DataBase Reference)
- NIST Chemistry Reference
- 1-Pyrene-carboxaldehyde(3029-19-4)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 144037
- Product name
- 1-Pyrenecarboxaldehyde
- Purity
- 99%
- Packaging
- 10g
- Price
- $177.65
- Updated
- 2025/07/31
- Product number
- 144037
- Product name
- 1-Pyrenecarboxaldehyde
- Purity
- 99%
- Packaging
- 50g
- Price
- $774
- Updated
- 2025/07/31
- Product number
- P1448
- Product name
- 1-Pyrenecarboxaldehyde
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $27
- Updated
- 2025/07/31
- Product number
- P1448
- Product name
- 1-Pyrenecarboxaldehyde
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $89
- Updated
- 2025/07/31
- Product number
- P989200
- Product name
- 1-Pyrenecarboxaldehyde
- Packaging
- 25g
- Price
- $195
- Updated
- 2021/12/16
1-Pyrenecarboxaldehyde Chemical Properties,Usage,Production
Chemical Properties
Dark Yellow Solid
Uses
1-Pyrenecarboxaldehyde is a important intermediate used in agrochemical, pharmaceutical and dyestuff field. It is used as a highly polarity-sensitive fluorophore for SNP typing.
Uses
A novel base-discriminating fluorescent (BDF) compound: a highly polarity-sensitive fluorophore for SNP typing.
Synthesis
24463-15-8
3029-19-4
General procedure for the synthesis of 1-pyrenecarboxaldehyde from 1-pyrenemethanol: To a round-bottom flask were added 1-pyrenemethanol (2 mmol), copper trifluoromethanesulfonate (CuOTf, 0.1 mmol, 0.05 eq.), (S)-5-(pyrrolidin-2-yl)-1H-tetrazole (0.1 mmol, 0.05 eq.), 2,2,6,6-tetramethylpiperidine-1-yloxy ( TEMPO, 0.1 mmol, 0.05 eq.), 4-dimethylaminopyridine (DMAP, 0.15 mmol, 0.075 eq.) and acetonitrile (CH3CN, 5 mL). The reaction mixture was stirred and exposed to air at 25 °C until the reaction was completed, and the progress of the reaction was monitored by thin layer chromatography (TLC). After completion of the reaction, the acetonitrile was removed by evaporation under vacuum. The residue was diluted with dichloromethane (CH2Cl2, 5 mL) and filtered through a silica gel plug to obtain the target product 1-pyrenecarboxaldehyde.
Purification Methods
Recrystallise the aldehyde three times from aqueous EtOH. [Beilstein 7 IV 1821.]
References
[1] Chemical Communications, 2003, # 6, p. 758 - 759
[2] Inorganic Chemistry, 2016, vol. 55, # 12, p. 6114 - 6123
[3] Inorganic Chemistry, 2017, vol. 56, # 22, p. 14084 - 14100
[4] Tetrahedron, 2014, vol. 70, # 52, p. 9791 - 9796
[5] Chemistry - A European Journal, 2016, vol. 22, # 26, p. 8814 - 8822
1-Pyrenecarboxaldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
1-Pyrenecarboxaldehyde Suppliers
- Tel
- --
- Fax
- --
- brunschwig@brunschwig.nl
- Country
- The Netherlands
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- 4996
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View Lastest Price from 1-Pyrenecarboxaldehyde manufacturers
- Product
- 1-Pyrenecarboxaldehyde 3029-19-4
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-10-09
- Product
- 1-Pyrenecarboxaldehyde 3029-19-4
- Price
- US $188.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-01-05
- Product
- 1-Pyrenecarboxaldehyde 3029-19-4
- Price
- US $35.00-25.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 Ton
- Release date
- 2023-10-07