tributyl((methoxymethoxy)methyl)stannane

Product Name: tributyl((methoxymethoxy)methyl)stannane
CAS No.: 100045-83-8
Chemical Name: tributyl((methoxymethoxy)methyl)stannane
Synonyms: SKL977;(MethoxyMethoxyMethyl)tributyltin;TRIBUTYL(METHOXYMETHOXYMETHYL)STANNANE;[(Methoxymethoxy)methyl]tributylstannane;Tributyl[(methoxymethoxy)methyl]stannane AldrichCPR
CBNumber: CB0384872
Molecular Formula: C15H34O2Sn
Formula Weight: 365.14
MOL File: 100045-83-8.mol

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tributyl((methoxymethoxy)methyl)stannane Property

Boiling point:: 84-87 °C(Press: 0.05 Torr)
solubility: soluble in Chloroform, Dichloromethane, Ethyl Acetate, Methanol
form: Liquid
color: Colourless

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Safety

Hazard Codes: T,N
Risk Statements: 21-25-36/38-48/23/25-50/53
Safety Statements: 36/37/39-45-60-61
RIDADR: UN 3146 6.1 / PGII
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: SYX00050
Product name: Tributyl[(methoxymethoxy)methyl]stannane
Purity: AldrichCPR
Packaging: 1g
Price: $320
Updated: 2024/03/01

TRC

Product number: M263000
Product name: [(Methoxymethoxy)methyl]tributylstannane
Packaging: 100mg
Price: $80
Updated: 2021/12/16

TRC

Product number: M263000
Product name: [(Methoxymethoxy)methyl]tributylstannane
Packaging: 1g
Price: $215
Updated: 2021/12/16

TRC

Product number: M263000
Product name: [(Methoxymethoxy)methyl]tributylstannane
Packaging: 5G
Price: $925
Updated: 2021/12/16

Matrix Scientific

Product number: 070168
Product name: Tributyl[(methoxymethoxy)methyl]stannane
Purity: 94%
Packaging: 1g
Price: $360
Updated: 2021/12/16

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tributyl((methoxymethoxy)methyl)stannane Chemical Properties,Usage,Production

Chemical Properties

Colourless Liquid

Uses

Tributyl((methoxymethoxy)methyl)stannane is a reagent used to conduct (Methoxymethoxy)methyl additions.

Synthesis

The Preparative Method of tributyl((methoxymethoxy)methyl)stannane: The most convenient preparation involves the two-step procedure outlined in eq 1. The first step involves the addition of Tri-n-butylstannyllithium to Paraformaldehyde, as Still described. In the second step, methoxymethylation is achieved via acetal exchange with Dimethoxymethane, promoted by Boron Trifluoride Etherate and Molecular Sieves. This procedure provides the desired reagent in higher yields compared to an alternative procedure which uses Phosphorus(V) Oxide to promote the acetal exchange step. This method is also superior to an alternative approach, which involves alkylation of (tributylstannyl)methanol with Chloromethyl Methyl Ether.

Precautions

As with all organostannanes, precautions should be taken to avoid all contact with tributyl[(methoxymethoxy)methyl]stannane. The reagent should be handled in a fume hood. The reagent can be stored neat in a freezer under nitrogen for several months.

tributyl((methoxymethoxy)methyl)stannane Preparation Products And Raw materials

Raw materials

Preparation Products

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tributyl((methoxymethoxy)methyl)stannane Suppliers

Canada 1 China 26 China Hong Kong 1 Germany 1 India 1 United States 10 Global 40

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100045-83-8, tributyl((methoxymethoxy)methyl)stannaneRelated Search:

tributyl((methoxymethoxy)methyl)stannane 3-Methyl-3-methoxybutanol Poly(dimethylsiloxane)

(MethoxyMethoxyMethyl)tributyltin

Tributyl[(methoxymethoxy)methyl]stannane AldrichCPR

TRIBUTYL(METHOXYMETHOXYMETHYL)STANNANE

[(Methoxymethoxy)methyl]tributylstannane

SKL977

100045-83-8

C15H34O2Sn

Miscellaneous Reagents

Stannanes