Description Chemical Properties Reference
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Cupric nitrate trihydrate

Description Chemical Properties Reference
Product Name
Cupric nitrate trihydrate
CAS No.
10031-43-3
Chemical Name
Cupric nitrate trihydrate
Synonyms
COPPER(II) NITRATE TRIHYDRATE;COPPER NITRATE TRIHYDRATE;COPPER (II) NITRATE;COPPER(II) NITRATE 3-HYDRATE;Gerhardite;Copper(Ⅱ)nitrate;CUPRIC NITRATE 3H2O;Copper(Ii)NitrateAr;copper(2+) dinitrate;COPPER(II) NITRATE 3H2O
CBNumber
CB0400536
Molecular Formula
CuH3NO4
Formula Weight
144.57
MOL File
10031-43-3.mol
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Cupric nitrate trihydrate Property

Melting point:
114 °C
Boiling point:
170°C
Density 
2,32 g/cm3
storage temp. 
Store at +5°C to +30°C.
solubility 
2670g/l
form 
Fine Powder
Specific Gravity
2.32
color 
Cream to brown
PH
3-4 (50g/l, H2O, 20℃)
Water Solubility 
soluble
Stability:
Stable. Strong oxidant - may ignite combustible material. Moisture sensitive. Incompatible with anhydrides, ammonia, amides, cyanides.
CAS DataBase Reference
10031-43-3(CAS DataBase Reference)
NIST Chemistry Reference
Copper dinitrate(10031-43-3)
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Safety

Hazard Codes 
O,C,Xn,N
Risk Statements 
8-22-34-36/38-50/53-41-38
Safety Statements 
17-26-36/37/39-45-37/39-61-60-39
RIDADR 
UN 3085 5.1/PG 2
WGK Germany 
2
RTECS 
GL7875000
3
HazardClass 
5.1
PackingGroup 
II
HS Code 
28342930
Toxicity
LD50 orally in Rabbit: 940 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H272May intensify fire; oxidizer

H314Causes severe skin burns and eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
61194
Product name
Copper(II) nitrate trihydrate
Purity
puriss. p.a., 99-104%
Packaging
100g
Price
$97.9
Updated
2024/03/01
Sigma-Aldrich
Product number
61194
Product name
Copper(II) nitrate trihydrate
Purity
puriss. p.a., 99-104%
Packaging
500g
Price
$377
Updated
2024/03/01
Sigma-Aldrich
Product number
1.02753
Product name
Copper(II) nitrate trihydrate
Purity
for analysis EMSURE?
Packaging
250g
Price
$80.8
Updated
2024/03/01
Sigma-Aldrich
Product number
1.02753
Product name
Copper(II) nitrate trihydrate
Purity
for analysis EMSURE?
Packaging
1kg
Price
$206
Updated
2024/03/01
Sigma-Aldrich
Product number
1.02753
Product name
Copper(II) nitrate trihydrate
Purity
for analysis EMSURE?
Packaging
25kg
Price
$4070
Updated
2024/03/01
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Cupric nitrate trihydrate Chemical Properties,Usage,Production

Description

Cupric nitrate is the cupric salt of nitrate. Cupric nitrate has various applications: a major application is its conversion to copper oxide, a powerful catalyst organic chemistry. It can also be used in textiles and polishing agents of other metals. It can also be used to demonstrate chemical voltaic cell reactions in schools. During organic synthesis, it can be combined with acetic anhydride to be used as an effective reagent for nitration of aromatic compounds. Its hydrate form can catalyze oxidative coupling of 2, 6-dimethylphenol to produce a polymer which is an important engineering material. Its tri-hydrate form can catalyze the solvent-free synthesis of 3-aminopropenones and 3-aminopropenoates. Its pentahydrate form may be used in the preparation of novel coordination polymers. It also has applications in medicine, as an insecticide, in chemical analysis, in making light sensitive papers.

Chemical Properties

Copper(II) nitrate trihydrate, Cu(NO3)2·3H2O, [10031-43-3], MW 241.59, MP 114.5°C, d 2.32, is a deep blue deliquescent material that crystallizes as rhombic platelets.Copper(II) nitrate trihydrate is very soluble in water, 77.4 g/100 g solution, and in methanol and ethanol. The anhydrous salt has been prepared by reaction of copper metal with N2O4 in ethylacetate, but it is not available commercially.

Reference

https://en.wikipedia.org/wiki/Copper(II)_nitrate
https://www.sigmaaldrich.com/catalog/product/aldrich/229636?lang=en&region=US
https://www.sigmaaldrich.com/catalog/product/sigald/61194?lang=en&region=US
https://www.sigmaaldrich.com/catalog/product/sigald/223395?lang=en&region=US
https://cameochemicals.noaa.gov/chemical/3023

Chemical Properties

Hygroscopic blue crystal with an order of nitric a

Uses

Analytical Reagent

Uses

Copper(II) nitrate trihydrate may be used in the preparation of the following mononuclear copper(II) complexes (phen = 1,10-phenanthroline, dpq = dipyrido[3,2-d:2′,3′-f]quinoxaline and dppz = dipyrido[3,2-a:2′,3′-c]phenazine):
[Cu(dpq)(NO3)2]
[Cu(dpq)(NO3)(H2O)2](NO3)
[Cu(dpq)(NO3)2(H2O)2]·2H2O
[Cu(dppz)(NO3)2(H2O)]·H2O

General Description

Copper(II) nitrate trihydrate is a hydrated copper salt. It participates as catalyst in the solvent-free synthesis of 3-aminopropenones and 3-aminopropenoates.

Purification Methods

Crystallise it from weak aqueous HNO3 (0.5mL/g) by cooling from room temperature. The anhydrous salt can be prepared by dissolving copper metal in a 1:1 mixture of liquid NO2 and ethyl acetate and purified by sublimation [Evans et al. J Chem Soc, Faraday Trans 1 75 1023 1979]. The hexahydrate dehydrates to the trihydrate at 26o, and the anhydrous salt sublimes between 150 and 225o, but melts at 255-256o and is deliquescent.

Cupric nitrate trihydrate Preparation Products And Raw materials

Raw materials

Preparation Products

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Cupric nitrate trihydrate Suppliers

Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
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China
ProdList
18738
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57
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
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China
ProdList
40228
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3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
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China
ProdList
15839
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Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12438
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Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
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Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
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China Langchem Inc.
Tel
0086-21-58956006
Fax
0086-21-58956100
Country
China
ProdList
7811
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57
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
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57
Sinopharm Chemical Reagent Co,Ltd.
Tel
86-21-63210123
Fax
86-21-63290778 86-21-63218885
Email
sj_scrc@sinopharm.com
Country
China
ProdList
9815
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79
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
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View Lastest Price from Cupric nitrate trihydrate manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Cupric nitrate 10031-43-3
Price
US $20.00-10.00/kg
Min. Order
99kg
Purity
99%
Supply Ability
20tons
Release date
2023-05-11
Yujiang Chemical (Shandong) Co.,Ltd.
Product
Copper Nitrate 10031-43-3
Price
US $78.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
10T
Release date
2024-05-06
Yujiang Chemical (Shandong) Co.,Ltd.
Product
Copper Nitrate 10031-43-3
Price
US $78.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
10T
Release date
2024-04-30

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