Cupric nitrate trihydrate
Description Chemical Properties Reference- Product Name
- Cupric nitrate trihydrate
- CAS No.
- 10031-43-3
- Chemical Name
- Cupric nitrate trihydrate
- Synonyms
- COPPER(II) NITRATE TRIHYDRATE;COPPER NITRATE TRIHYDRATE;COPPER (II) NITRATE;COPPER(II) NITRATE 3-HYDRATE;Gerhardite;Copper(Ⅱ)nitrate;CUPRIC NITRATE 3H2O;Copper(Ii)NitrateAr;copper(2+) dinitrate;COPPER(II) NITRATE 3H2O
- CBNumber
- CB0400536
- Molecular Formula
- CuH3NO4
- Formula Weight
- 144.57
- MOL File
- 10031-43-3.mol
Cupric nitrate trihydrate Property
- Melting point:
- 114 °C
- Boiling point:
- 170°C
- Density
- 2,32 g/cm3
- storage temp.
- Store at +5°C to +30°C.
- solubility
- 2670g/l
- form
- Fine Powder
- Specific Gravity
- 2.32
- color
- Cream to brown
- PH
- 3-4 (50g/l, H2O, 20℃)
- Water Solubility
- soluble
- Stability:
- Stable. Strong oxidant - may ignite combustible material. Moisture sensitive. Incompatible with anhydrides, ammonia, amides, cyanides.
- CAS DataBase Reference
- 10031-43-3(CAS DataBase Reference)
- NIST Chemistry Reference
- Copper dinitrate(10031-43-3)
Safety
- Hazard Codes
- O,C,Xn,N
- Risk Statements
- 8-22-34-36/38-50/53-41-38
- Safety Statements
- 17-26-36/37/39-45-37/39-61-60-39
- RIDADR
- UN 3085 5.1/PG 2
- WGK Germany
- 2
- RTECS
- GL7875000
- F
- 3
- HazardClass
- 5.1
- PackingGroup
- II
- HS Code
- 28342930
- Toxicity
- LD50 orally in Rabbit: 940 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H272May intensify fire; oxidizer
H314Causes severe skin burns and eye damage
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 61194
- Product name
- Copper(II) nitrate trihydrate
- Purity
- puriss. p.a., 99-104%
- Packaging
- 100g
- Price
- $97.9
- Updated
- 2024/03/01
- Product number
- 61194
- Product name
- Copper(II) nitrate trihydrate
- Purity
- puriss. p.a., 99-104%
- Packaging
- 500g
- Price
- $377
- Updated
- 2024/03/01
- Product number
- 1.02753
- Product name
- Copper(II) nitrate trihydrate
- Purity
- for analysis EMSURE?
- Packaging
- 250g
- Price
- $80.8
- Updated
- 2024/03/01
- Product number
- 1.02753
- Product name
- Copper(II) nitrate trihydrate
- Purity
- for analysis EMSURE?
- Packaging
- 1kg
- Price
- $206
- Updated
- 2024/03/01
- Product number
- 1.02753
- Product name
- Copper(II) nitrate trihydrate
- Purity
- for analysis EMSURE?
- Packaging
- 25kg
- Price
- $4070
- Updated
- 2024/03/01
Cupric nitrate trihydrate Chemical Properties,Usage,Production
Description
Cupric nitrate is the cupric salt of nitrate. Cupric nitrate has various applications: a major application is its conversion to copper oxide, a powerful catalyst organic chemistry. It can also be used in textiles and polishing agents of other metals. It can also be used to demonstrate chemical voltaic cell reactions in schools. During organic synthesis, it can be combined with acetic anhydride to be used as an effective reagent for nitration of aromatic compounds. Its hydrate form can catalyze oxidative coupling of 2, 6-dimethylphenol to produce a polymer which is an important engineering material. Its tri-hydrate form can catalyze the solvent-free synthesis of 3-aminopropenones and 3-aminopropenoates. Its pentahydrate form may be used in the preparation of novel coordination polymers. It also has applications in medicine, as an insecticide, in chemical analysis, in making light sensitive papers.
Chemical Properties
Copper(II) nitrate trihydrate, Cu(NO3)2·3H2O, [10031-43-3], MW 241.59, MP 114.5°C, d 2.32, is a deep blue deliquescent material that crystallizes as rhombic platelets.Copper(II) nitrate trihydrate is very soluble in water, 77.4 g/100 g solution, and in methanol and ethanol. The anhydrous salt has been prepared by reaction of copper metal with N2O4 in ethylacetate, but it is not available commercially.
Reference
https://en.wikipedia.org/wiki/Copper(II)_nitrate
https://www.sigmaaldrich.com/catalog/product/aldrich/229636?lang=en®ion=US
https://www.sigmaaldrich.com/catalog/product/sigald/61194?lang=en®ion=US
https://www.sigmaaldrich.com/catalog/product/sigald/223395?lang=en®ion=US
https://cameochemicals.noaa.gov/chemical/3023
Chemical Properties
Hygroscopic blue crystal with an order of nitric a
Uses
Analytical Reagent
Uses
Copper(II) nitrate trihydrate may be used in the preparation of the following mononuclear copper(II) complexes (phen = 1,10-phenanthroline, dpq = dipyrido[3,2-d:2′,3′-f]quinoxaline and dppz = dipyrido[3,2-a:2′,3′-c]phenazine):
[Cu(dpq)(NO3)2]
[Cu(dpq)(NO3)(H2O)2](NO3)
[Cu(dpq)(NO3)2(H2O)2]·2H2O
[Cu(dppz)(NO3)2(H2O)]·H2O
General Description
Copper(II) nitrate trihydrate is a hydrated copper salt. It participates as catalyst in the solvent-free synthesis of 3-aminopropenones and 3-aminopropenoates.
Purification Methods
Crystallise it from weak aqueous HNO3 (0.5mL/g) by cooling from room temperature. The anhydrous salt can be prepared by dissolving copper metal in a 1:1 mixture of liquid NO2 and ethyl acetate and purified by sublimation [Evans et al. J Chem Soc, Faraday Trans 1 75 1023 1979]. The hexahydrate dehydrates to the trihydrate at 26o, and the anhydrous salt sublimes between 150 and 225o, but melts at 255-256o and is deliquescent.
Cupric nitrate trihydrate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Cupric nitrate trihydrate manufacturers
- Product
- Cupric nitrate 10031-43-3
- Price
- US $20.00-10.00/kg
- Min. Order
- 99kg
- Purity
- 99%
- Supply Ability
- 20tons
- Release date
- 2023-05-11
- Product
- Copper Nitrate 10031-43-3
- Price
- US $78.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 10T
- Release date
- 2024-05-06
- Product
- Copper Nitrate 10031-43-3
- Price
- US $78.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 10T
- Release date
- 2024-04-30