1,4-Diacetylbenzene

Product Name: 1,4-Diacetylbenzene
CAS No.: 1009-61-6
Chemical Name: 1,4-Diacetylbenzene
Synonyms: P-DIACETYLBENZENE;1,4-DIACETYLBENZENE;TIMTEC-BB SBB008588;Benzene, p-diacetyl-;4-ACETYLACETOPHENONE;4'-ACETYLACETOPHENONE;P-ACETYL ACETOPHENONE;1,4-Diacetylbenzene>PARA-ACETYLACETOPHENONE;1,4-Diacetylbenzene,98%
CBNumber: CB0433622
Molecular Formula: C10H10O2
Formula Weight: 162.19
MOL File: 1009-61-6.mol

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1,4-Diacetylbenzene Property

Melting point:: 111-113 °C (lit.)
Boiling point:: 120 °C / 1mmHg
Density: 1.0613 (rough estimate)
refractive index: 1.5120 (estimate)
storage temp.: Sealed in dry,Room Temperature
form: powder to crystaline
color: White to Almost white
Water Solubility: 6.309mg/L(25 ºC)
BRN: 1907515
InChI: InChI=1S/C10H10O2/c1-7(11)9-3-5-10(6-4-9)8(2)12/h3-6H,1-2H3
InChIKey: SKBBQSLSGRSQAJ-UHFFFAOYSA-N
SMILES: C1(C(=O)C)=CC=C(C(=O)C)C=C1
CAS DataBase Reference: 1009-61-6(CAS DataBase Reference)
NIST Chemistry Reference: Ethanone, 1,1'-(1,4-phenylene)bis-(1009-61-6)
EPA Substance Registry System: Ethanone, 1,1'-(1,4-phenylene)bis- (1009-61-6)

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Safety

Risk Statements: 36/37/38
Safety Statements: 22-24/25
WGK Germany: 3
HS Code: 29143990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H304May be fatal if swallowed and enters airways

H350May cause cancer

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P281Use personal protective equipment as required.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P308+P313IF exposed or concerned: Get medical advice/attention.

P331Do NOT induce vomiting.

P403Store in a well-ventilated place.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: D8208
Product name: 1,4-Diacetylbenzene
Purity: 99%
Packaging: 5g
Price: $302
Updated: 2024/03/01

TCI Chemical

Product number: D0066
Product name: 1,4-Diacetylbenzene
Purity: >99.0%(GC)
Packaging: 5g
Price: $62
Updated: 2024/03/01

TCI Chemical

Product number: D0066
Product name: 1,4-Diacetylbenzene
Purity: >99.0%(GC)
Packaging: 25g
Price: $167
Updated: 2024/03/01

TRC

Product number: P997790
Product name: 1,1''-(1,4-phenylene)bis-Ethanone
Packaging: 5g
Price: $110
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD69972
Product name: 1,4-Diacetylbenzene
Packaging: 5G
Price: $120
Updated: 2021/12/16

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1,4-Diacetylbenzene Chemical Properties,Usage,Production

Chemical Properties

ALMOST WHITE TO LIGHT BROWN CRYSTALLINE POWDER

Uses

1,1''-(1,4-phenylene)bis-Ethanone can undergo oxidative C-C Bond Cleavage to synthesize an aryl carboxylic acid with an iodine catalyst . 1,1''-(1,4-phenylene)bis-Ethanone is also capable of Suzuki-Miyaura coupling.

Synthesis Reference(s)

The Journal of Organic Chemistry, 26, p. 4308, 1961 DOI: 10.1021/jo01069a031
Synthetic Communications, 26, p. 3175, 1996 DOI: 10.1080/00397919608004626

Purification Methods

Crystallise it from EtOH (m 114o) or *benzene and dry it in a vacuum over CaCl2. Also purify it by dissolving it in acetone, treating with Norit, evaporating and recrystallising from MeOH. The dioxime has m 248-259o. [Wagner et al. J Am Chem Soc 108 7727 1986]. [Beilstein 7 H 686, 7 II 624, 7 III 3504, 7 IV 2156.]

1,4-Diacetylbenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1,4-Diacetylbenzene Suppliers

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View Lastest Price from 1,4-Diacetylbenzene manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 1,4-Diacetylbenzene 1009-61-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000KG
Release date: 2024-08-02

Zhuozhou Wenxi import and Export Co., Ltd

Product: 1,4-DIACETYLBENZENE 1009-61-6
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: 1,4-Diacetylbenzene 1009-61-6
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

1009-61-6, 1,4-DiacetylbenzeneRelated Search:

Pigment Red 122 1,4-DIBENZOYLBENZENE Pigment Red 202 Quinacridone Vat Violet 13 1,4-Diacetylbenzene METHANONE, 1,1'-(1,4-PHENYLENE)BIS[1-(4-FLUOROPHENYL)-] 5,7,12,14-Pentacenetetrone 1-[4-(2-Oxo-2-phenylacetyl)phenyl]-2-phenylethane-1,2-dione M-ACETYL ACETOPHENONE,M-DIACETYLBENZENE,1,3-Diacetylbenzene,97%,1,3-DIACETYLBENZENE 1,2-DIACETYLBENZENE,1,2-DIACETYLBENZENE, FOR FLUORESCENCE Benzoylacetone N,N'-Diacetylbenzene-1,4-diamine A,A'-TEREPHTHALOYLBIS-5-CHLORO-2,4-DIMETHOXYACETANILIDE 1,4-DI(CYANOACETYL)BENZENE 1,4-Bis(4-phenoxybenzoyl)benzene pyrene-1,8-dione (E)-3-Phenyl-1-(4-[(E)-(3-phenyl-acryloyl)]-phenyl)-propenone

1-(4-Acetyl-phenyl)-ethanone

1,1’-(1,4-phenylene)bis-ethanon

Benzene, p-diacetyl-

P-ACETYL ACETOPHENONE

P-DIACETYLBENZENE

TIMTEC-BB SBB008588

1,4-DIACETYLBENZENE

4'-ACETYLACETOPHENONE

4-ACETYLACETOPHENONE

Ethanone,1,1’-(1,4-phenylene)bis-

PARA-ACETYLACETOPHENONE

Ethanone,1,1'-(1,4-phenyle

1,4-DIACETYLBENZENE 99+%

1,1'-(p-Phenylene)bisethanone

1,1'-p-Phenylenebisethanone

1,4-Diacetylbenzene,98%

1-(4-Acetylphenyl)ethan-1-one

1,1'-(1,4-Phenylene)diethanone

1,4-Diacetylbenzene 99%

1,4-Diacetylbenzene&gt

1009-61-6

C6H4COCH32

Building Blocks

C10

Carbonyl Compounds

Organic Building Blocks

Ketones

C10

Carbonyl Compounds

Ketones

Aromatic Ketones (substituted)