ChemicalBook > CAS DataBase List > 1,3-Butadiene diepoxide

1,3-Butadiene diepoxide

Product Name
1,3-Butadiene diepoxide
CAS No.
1464-53-5
Chemical Name
1,3-Butadiene diepoxide
Synonyms
R 181;M 8838;CB 1181;Bioxiran;Bioxirane;ENT-26592;iepoxybutane;alkylepoxides;Diepoxybutane;Butadiendioxyd
CBNumber
CB0444763
Molecular Formula
C4H6O2
Formula Weight
86.09
MOL File
1464-53-5.mol
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1,3-Butadiene diepoxide Property

Melting point:
2-4 °C(lit.)
Boiling point:
56-58 °C25 mm Hg(lit.)
alpha 
0°(neat)
Density 
1.113 g/mL at 25 °C(lit.)
vapor pressure 
25 mm Hg ( 56 °C)
refractive index 
n20/D 1.434(lit.)
Flash point:
114 °F
storage temp. 
0-6°C
Specific Gravity
1.1
color 
Colorless liquid
Water Solubility 
Soluble in water (1000 g/L).
Merck 
14,3676
BRN 
79831
CAS DataBase Reference
1464-53-5(CAS DataBase Reference)
IARC
(Vol. 11, Sup 7) 1987
EPA Substance Registry System
Diepoxybutane (1464-53-5)
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Safety

Hazard Codes 
T+
Risk Statements 
45-46-24/25-26-34-10
Safety Statements 
53-45-36/37/39-28-26
RIDADR 
UN 3384 6.1/PG 1
WGK Germany 
1
RTECS 
EJ8225000
8-10-18
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29109000
Hazardous Substances Data
1464-53-5(Hazardous Substances Data)
Toxicity
LD50 orl-rat: 78 mg/kg AMIHBC 10,61,54
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H301Toxic if swalloed

H314Causes severe skin burns and eye damage

H340May cause genetic defects

H350May cause cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
202533
Product name
1,3-Butadiene diepoxide
Purity
97%
Packaging
1g
Price
$33.72
Updated
2024/03/01
Sigma-Aldrich
Product number
202533
Product name
1,3-Butadiene diepoxide
Purity
97%
Packaging
5g
Price
$63.5
Updated
2024/03/01
Alfa Aesar
Product number
L03919
Product name
Butadiene diepoxide, 95%
Packaging
1g
Price
$32.7
Updated
2023/06/20
Alfa Aesar
Product number
L03919
Product name
Butadiene diepoxide, 95%
Packaging
5g
Price
$83
Updated
2023/06/20
Sigma-Aldrich
Product number
202533
Product name
1,3-Butadiene diepoxide
Purity
97%
Packaging
25g
Price
$221
Updated
2024/03/01
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1,3-Butadiene diepoxide Chemical Properties,Usage,Production

Description

Diepoxybutane is a flammable, colorless liquid. Molecular weight=86.09; Boiling point=57℃ at25℃; Freezing/Melting point=19℃; also reported at2-4℃; Flash point=44.8℃. Hazard Identification (basedon NFPA-704 M Rating System): Health 3, Flammability 0,Reactivity 0. Mixes with water.

Chemical Properties

clear colorless to very slightly yellow liquid

Uses

Diepoxybutane has been used as a research chemical, as a chemical intermediate, as a curing agent for polymers, as a cross-linking agent for textile fabrics, and to prevent microbial spoilage (IARC 1976, HSDB 2009). It has also been used to synthesize erythritol and pharmaceuticals (HSDB 2009). Because of its cross-linking properties, diepoxybutane is used as a test agent in the diagnosis of Fanconi anemia, which is characterized by chromosomal instability (Auerbach et al. 1989).

Uses

Curing of polymers; cross-linking of textile fibers; prevention of microbial spoilage

Uses

Butadiene diepoxide is used as a research chemical, as a chemical intermediate, as a curing agent for polymers, as a cross-linking agent for textile fabrics, and to prevent microbial spoilage. It is also been used to synthesize erythritol and pharmaceuticals.

Uses

1,3-Butadiene Diepoxide is used as a substance in the evaluation of anti-diabetic and anti-ulcer potential of selected fresh fruits samples and their GC/MS analysis. Also in the inhibitory potency of 4-carbon alkanes and alkenes towards CYD2E1 activity.

Definition

ChEBI: Diepoxybutane is an epoxide. It has a role as a mutagen.

Production Methods

Diepoxybutane is prepared by chlorination of butadiene followed by epoxidation with peracetic acid, with subsequent hydrolysis of the epoxide group and final reepoxidation with caustic.

General Description

Colorless liquid. Used in curing polymers; crosslinking textile fibers and to prevent spoilage.

Air & Water Reactions

Highly Flammable

Reactivity Profile

Epoxides, such as 1,3-BUTADIENE DIEPOXIDE, are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Hazard

Probable carcinogen; neoplastigen; tumorigenic; poison; mutagen.

Health Hazard

Severe skin and eye irritant. Accidental minor exposure caused swelling of the eyelids, upper respiratory tract irritation and painful eye irritation 6 hours after exposure.NOTE: The dl- and meso-forms (CAS Registry Numbers 298-18-0 and 564-00-1, respectively) as well as the L(-) form (CAS Registry Number 30031-64-2) have all been determined to be positive animal carcinogens.

Fire Hazard

When heated to decomposition 1,3-BUTADIENE DIEPOXIDE emits acrid smoke and irritating fumes.

Safety Profile

Confirmed carcinogen withexperimental tumorigenic data. Poison by ingestion,inhalation, skin contact, and intraperitoneal routes.Human mutation data reported. A severe skin and eyeirritant. When heated to decomposition it emits acridsmoke and irritat

Potential Exposure

DEB is primarily used in researchand experimental work; as a curing agent for polymers; asa crosskicking agent for textile fabrics; and in preventingmicrobial spoilage in substances. DEB is also used commercially as mixed stereoisomers and as individual isomers in the preparation of erythritol and otherpharmaceuticals.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

Carcinogenicity

Diepoxybutane is reasonably anticipated to be a human carcinogenbased on sufficient evidence of carcinogenicity from studies in experimental animals.

storage

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with diepoxybutane you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, wellventilated area. A regulated, marked area should be established where this chemical is handled, used, or stored incompliance with OSHA Standard 1910.1045.

Shipping

Toxic liquids, flammable, organic, n.o.s. requirea shipping label of “POISONOUS/TOXIC MATERIALS,FLAMMABLE LIQUID.” It falls in Hazard Class 6.1 andPacking Group I.

1,3-Butadiene diepoxide Preparation Products And Raw materials

Raw materials

Preparation Products

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1,3-Butadiene diepoxide Suppliers

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View Lastest Price from 1,3-Butadiene diepoxide manufacturers

hebei hongtan Biotechnology Co., Ltd
Product
1,3-Butadiene diepoxide 1464-53-5
Price
US $30.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
3000kg
Release date
2024-03-22
Hebei Weibang Biotechnology Co., Ltd
Product
1,3-Butadiene diepoxide 1464-53-5
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-05
Hebei Yanxi Chemical Co., Ltd.
Product
1,3-Butadiene diepoxide 1464-53-5
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-09-05

1464-53-5, 1,3-Butadiene diepoxideRelated Search:


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