THIOPHENOL COPPER(I) SALT
- Product Name
- THIOPHENOL COPPER(I) SALT
- CAS No.
- 1192-40-1
- Chemical Name
- THIOPHENOL COPPER(I) SALT
- Synonyms
- PhSCu;phenylthiocopper;COPPER(1) THIOPHENOXIDE;Copper(I) thiophenolate >=98.0% (RT);Copper(I) thiophenoxide, Phenylthiocopper(I), Thiophenol copper(I) salt
- CBNumber
- CB0497299
- Molecular Formula
- C6H5SCu
- Formula Weight
- 0
- MOL File
- 1192-40-1.mol
THIOPHENOL COPPER(I) SALT Property
- Melting point:
- 280 °C (dec.)(lit.)
- form
- solid
- BRN
- 3709171
Safety
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3263 8/PG 2
- WGK Germany
- 3
- F
- 1-10-13
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
N-Bromosuccinimide Price
- Product number
- 89025
- Product name
- Copper(I) thiophenolate
- Purity
- ≥98.0% (RT)
- Packaging
- 25g
- Price
- $396
- Updated
- 2023/06/20
- Product number
- ING0004002
- Product name
- COPPER(I) THIOPHENOLATE
- Purity
- 95.00%
- Packaging
- 25G
- Price
- $1180.85
- Updated
- 2021/12/16
THIOPHENOL COPPER(I) SALT Chemical Properties,Usage,Production
Uses
Reagents used as the source of nucleophilic phenyl sulfide for preparation of lithiumalkyl(phenylthio)cuprates and organophosphinecopper(I) phenylthiolatecomplexes
Preparation
One method to preparing Thiophenol Copper(I) salt is to treat Thiophenol with Copper(I) Oxide in ethanol at reflux to give phenylthiocopper as a yellow suspension. Alternatively, lithiation of thiophenol and quenching with Copper(I) Iodide affords a yellow solution, which is typically reacted in situ with organometallic reagents.
reaction suitability
core: copper
reagent type: catalyst
Purification Methods
The Cu salt can be extracted from a thimble (Soxhlet) with boiling MeOH. It is a green-brown powder which gives a yellow-green solution in pyridine. Wash it with EtOH and dry it in a vacuum. It can be precipitated from a pyridine solution by adding H2O, collecting the precipitate, washing it with EtOH and drying in a vacuum. [Posner et al. Synthesis 662 1974, Krebs et al. Chem Ber 90 425 1957, Beilstein 6 IV 1465.]
THIOPHENOL COPPER(I) SALT Preparation Products And Raw materials
Raw materials
Preparation Products
THIOPHENOL COPPER(I) SALT Suppliers
- Tel
- 021-61259108 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40228
- Advantage
- 62
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
- Country
- China
- ProdList
- 42958
- Advantage
- 64
- Tel
- 400-6206333 18021050169
- Fax
- 021-50323701
- market@aladdin-e.com
- Country
- China
- ProdList
- 25003
- Advantage
- 65
- Tel
- 021-61415566 800-8193336
- orderCN@merckgroup.com
- Country
- China
- ProdList
- 51456
- Advantage
- 80
- Tel
- 021-58432009 400-005-6266
- Fax
- 021-58436166
- marketing1@energy-chemical.com
- Country
- China
- ProdList
- 44807
- Advantage
- 58
- Tel
- 18902340307 18902340307
- Fax
- 0751-2819901
- 3356812514@qq.com
- Country
- China
- ProdList
- 9244
- Advantage
- 58
- Tel
- 183-076230-3607 19396072537
- lyna@wolfabio.com
- Country
- China
- ProdList
- 312
- Advantage
- 58
- Tel
- 029-89586681 15829046862
- 1020@dideu.com
- Country
- China
- ProdList
- 8485
- Advantage
- 58
- Tel
- 025-66061636 18013972705
- qqyang@aikonchem.com
- Country
- China
- ProdList
- 10238
- Advantage
- 58
- Tel
- --
- Fax
- --
- chenjw@absin.cn
- Country
- CHINA
- ProdList
- 6705
- Advantage
- 58
- Tel
- --
- Fax
- --
- weibochem@163.com
- Country
- China
- ProdList
- 6187
- Advantage
- 67