DIETHYL 2-ANILINOMALONATE

Product Name: DIETHYL 2-ANILINOMALONATE
CAS No.: 6414-58-0
Chemical Name: DIETHYL 2-ANILINOMALONATE
Synonyms: Diethyl 2-(phenylamino);DIETHYL 2-ANILINOMALONATE;DIETHYL 2-PHENYLAMINOMALONATE;diethyl 2-anilinopropanedioate;2-Anilinomalonic acid diethyl ester;Diethyl 2-(phenylamino)malonate 95+%;2-Phenylamino-malonic acid diethyl ester;2-(Phenylamino)propanedioic acid diethyl ester;1H-Pyrazole,5-bromo-1-(tetrahydro-2H-pyran-4-yl)-;Propanedioic acid, 2-(phenylamino)-, 1,3-diethyl ester
CBNumber: CB0507130
Molecular Formula: C13H17NO4
Formula Weight: 251.28
MOL File: 6414-58-0.mol

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DIETHYL 2-ANILINOMALONATE Property

Melting point:: 43-45 °C
Boiling point:: 340.6±22.0 °C(Predicted)
Density: 1.167±0.06 g/cm3(Predicted)
storage temp.: 2-8°C(protect from light)
pka: 14.73±0.59(Predicted)
Appearance: White to off-white Solid

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Safety

HazardClass: IRRITANT
HS Code: 2922390090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Activate Scientific

Product number: AS68228
Product name: Diethyl 2-(phenylamino)malonate
Purity: 95+%
Packaging: 1g
Price: $160
Updated: 2021/12/16

AK Scientific

Product number: 7283AE
Product name: 2-Phenylamino-malonicaciddiethylester
Packaging: 1g
Price: $194
Updated: 2021/12/16

Matrix Scientific

Product number: 059213
Product name: 2-Phenylamino-malonic acid diethyl ester
Purity: 95+%
Packaging: 1g
Price: $284
Updated: 2021/12/16

Activate Scientific

Product number: AS68228
Product name: Diethyl 2-(phenylamino)malonate
Purity: 95+%
Packaging: 5G
Price: $557
Updated: 2021/12/16

AK Scientific

Product number: 7283AE
Product name: 2-Phenylamino-malonicaciddiethylester
Packaging: 5g
Price: $612
Updated: 2021/12/16

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DIETHYL 2-ANILINOMALONATE Chemical Properties,Usage,Production

Synthesis

685-87-0

6414-58-0

(1) Synthesis of diethyl anilino malonate: Aniline (18.6 g, 0.20 mol) was dissolved in anhydrous benzene (125 mL), followed by the addition of diethyl bromomalonate (23.9 g, 0.10 mol). The reaction mixture was heated to reflux under continuous stirring and maintained for 37 hours. Upon completion of the reaction, the reaction mixture was washed with dilute hydrochloric acid to remove unreacted aniline. The organic layer was separated, washed three times with water and dried with anhydrous magnesium sulfate. Subsequently, the solvent was removed by distillation under reduced pressure. The crude product was purified by silica gel column chromatography using hexane/ethyl acetate (10:1, v/v) as eluent to afford 7.5 g (30% yield) of diethyl anilino malonate. The product was characterized by nuclear magnetic resonance (NMR) with the following data: 1H NMR (δ, TMS, CCl4): 1.20 (6H, t, J = 7 Hz), 4.20 (4H, q, J = 7 Hz), 4.66 (2H, s, br; changed to 1H after addition of D2O), 6.5-7.3 (5H, m).

References

[1] Patent: US4421914, 1983, A

DIETHYL 2-ANILINOMALONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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DIETHYL 2-ANILINOMALONATE Suppliers

China 16 India 1 United Kingdom 2 United States 6 Global 25

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6414-58-0, DIETHYL 2-ANILINOMALONATERelated Search:

TIMTEC-BB SBB006857 N-PHENYLGLYCINE ETHYL ESTER TIMTEC-BB SBB006901 2-AMINODIETHYLMALONATE DIETHYL 2-(4-CHLOROANILINO)MALONATE DIMETHYL 2-AMINOMALONATE, TECH DIETHYL 2-ANILINOMALONATE Aminomalonic acid

Diethyl 2-(phenylamino)malonate 95+%

diethyl 2-anilinopropanedioate

DIETHYL 2-ANILINOMALONATE

DIETHYL 2-PHENYLAMINOMALONATE

2-(Phenylamino)propanedioic acid diethyl ester

2-Anilinomalonic acid diethyl ester

2-Phenylamino-malonic acid diethyl ester

Diethyl 2-(phenylamino)

Propanedioic acid, 2-(phenylamino)-, 1,3-diethyl ester

1H-Pyrazole,5-bromo-1-(tetrahydro-2H-pyran-4-yl)-

6414-58-0