Reaction
ChemicalBook > CAS DataBase List > RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL

RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL

Reaction
Product Name
RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL
CAS No.
255836-67-0
Chemical Name
RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL
Synonyms
TrixiePhos;2-(DI-TERT-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL;2-(Di-tert;98% TrixiePhos;TrixiePhos 97%;rac-2-(Di-tert-butylphosphino)-1,1;2-Di-t-butylphosphino-1,1'-binaphthyl;RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL;2-[Di(tert-Butyl)phosphino]-1,1'-binaphthyl;2-(Di-tert-butylphosphino)-1,1''-binaphthyl
CBNumber
CB0688569
Molecular Formula
C28H31P
Formula Weight
398.52
MOL File
255836-67-0.mol
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RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL Property

Melting point:
144-148 °C
Boiling point:
519.5±29.0 °C(Predicted)
storage temp. 
2-8°C, protect from light, stored under nitrogen
form 
crystal
color 
white
InChI
InChI=1S/C28H31P/c1-27(2,3)29(28(4,5)6)25-19-18-21-13-8-10-16-23(21)26(25)24-17-11-14-20-12-7-9-15-22(20)24/h7-19H,1-6H3
InChIKey
QGBQGMHXBSLYLZ-UHFFFAOYSA-N
SMILES
P(C1=CC=C2C(=C1C1=C3C(C=CC=C3)=CC=C1)C=CC=C2)(C(C)(C)C)C(C)(C)C
CAS DataBase Reference
255836-67-0
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
WGK Germany 
3
TSCA 
No
HS Code 
29029090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
710342
Product name
rac-2-(Di-tert-butylphosphino)-1,1′-binaphthyl
Purity
97%
Packaging
500mg
Price
$134.9
Updated
2025/07/31
Strem Chemicals
Product number
15-1043
Product name
racemic-2-Di-t-butylphosphino-1,1'-binaphthyl, 98% TrixiePhos
Packaging
250mg
Price
$66
Updated
2024/03/01
Strem Chemicals
Product number
15-1043
Product name
racemic-2-Di-t-butylphosphino-1,1'-binaphthyl, 98% TrixiePhos
Packaging
1g
Price
$198
Updated
2024/03/01
Strem Chemicals
Product number
15-1043
Product name
racemic-2-Di-t-butylphosphino-1,1'-binaphthyl, 98% TrixiePhos
Packaging
5g
Price
$794
Updated
2024/03/01
TRC
Product number
D493766
Product name
2-(Di-tert-butylphosphino)-1,1''-binaphthyl98%TrixiePhos
Packaging
250mg
Price
$165
Updated
2021/12/16
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RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL Chemical Properties,Usage,Production

Reaction

  1. Ligand for the Pd-catalyzed formation of oxygen heterocycles.
  2. Ligand for the intermolecular Pd-catalyzed synthesis of aryl ethers.
  3. Ligand for the intramolecular Pd-catalyzed synthesis of aryl ethers.
  4. Ligand for the synthesis of carbazoles by Pd-catalyzed double N-arylation reaction.
  5. Ligand for the Pd-catalyzed cyanation of (hetero)arylchlorides.
  6. Ligand for the Pd-catalyzed intramolecular synthesis of carbazoles via C-H functionalization.

Chemical Properties

White to pale yellow crystalline powder

Uses

2-(Di-tert-butylphosphino)-1,1''-binaphthyl 98% TrixiePhos is a reagent used as ligand in palladium-catalyzed C-O, C-N, and C-C bond forming reactions.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings

RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL Preparation Products And Raw materials

Raw materials

Preparation Products

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RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL Suppliers

Xinxiang Runyu Material Co., Ltd.
Tel
166-166-37336996 15690792173
Fax
0373-7759608
Email
chenxi.song@runvmat.com
Country
China
ProdList
285
Advantage
55
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-010-82967028 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12000
Advantage
60
China DongFan Chemical Co.,LTD
Tel
86-0571-85151182
Fax
86-0571-85151182
Country
China
ProdList
5691
Advantage
66
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11705
Advantage
57
SpringPharma Tech Co.,Ltd
Tel
+86-25-68710855, +86-25-68710897
Fax
025-68710856
Email
sales@springpharma.net
Country
China
ProdList
1261
Advantage
62
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Nanjin Cynthia chemicals Technology Co.,Ltd
Tel
0550-5618439 15951861180
Fax
0550-5610690
Email
cynthiachem@163.com
Country
China
ProdList
291
Advantage
62
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View Lastest Price from RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
[1,1'-Binaphthalen]-2-yldi-tert-butylphosphine 255836-67-0
Price
US $2.00-5.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-26
Hebei Chuanghai Biotechnology Co., Ltd
Product
RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL 255836-67-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-12-10
Career Henan Chemical Co
Product
RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL 255836-67-0
Price
US $1.00/KG
Min. Order
1G
Purity
98%
Supply Ability
1MT
Release date
2018-08-10

255836-67-0, RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYLRelated Search:


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  • 255836-67-0
  • C28H31P
  • Achiral Phosphine
  • Aryl Phosphine
  • Buchwald Ligands Series
  • Buchwald Ligands&Precatalysts