(+)-DIACETYL-L-TARTARIC ANHYDRIDE

ChemicalBook > CAS DataBase List > (+)-DIACETYL-L-TARTARIC ANHYDRIDE

(+)-DIACETYL-L-TARTARIC ANHYDRIDE

Product Name: (+)-DIACETYL-L-TARTARIC ANHYDRIDE
CAS No.: 6283-74-5
Chemical Name: (+)-DIACETYL-L-TARTARIC ANHYDRIDE
Synonyms: DATA;NSC 7712;DIACETYL-L-TARTARIC ANHYDRIDE;DI-O-ACETYL-L-TARTARIC ANHYDRIDE;(+)-DIACETYL-L-TARTARIC ANHYDRIDE;(+)-Diacetyl-L-tartaric Anhydride;(+)-DI-O-ACETYL-L-WEINSURE-ANHYDRID;(+)-Diacetyl-L-tartaricAnhydride>(+)-DI-O-ACETYL-L-TARTARIC ANHYDRIDE;O,O-diacetyl tartaric acid anhydride
CBNumber: CB0717661
Molecular Formula: C8H8O7
Formula Weight: 216.14
MOL File: 6283-74-5.mol

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(+)-DIACETYL-L-TARTARIC ANHYDRIDE Property

Melting point:: 130-135 °C(lit.)
Boiling point:: 316.55°C (rough estimate)
Density: 1.5197 (rough estimate)
refractive index: 90 ° (C=0.5, CHCl3)
storage temp.: 2-8°C
solubility: Acetone, Chloroform (Slightly, Heated)
form: Crystals or Needles
color: White
optical activity: [α]20/D +59°, c = 6 in acetone
Water Solubility: Soluble in methanol and dichloromethane. Slightly soluble in water.
Sensitive: Moisture Sensitive
BRN: 87315
CAS DataBase Reference: 6283-74-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
F: 3-10-21
HS Code: 29321900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 358924
Product name: (+)-O,O′-Diacetyl-L-tartaric anhydride
Purity: 97%
Packaging: 50g
Price: $198
Updated: 2024/03/01

TCI Chemical

Product number: D1911
Product name: (+)-Diacetyl-L-tartaric Anhydride
Purity: >97.0%(T)
Packaging: 25g
Price: $61
Updated: 2024/03/01

TRC

Product number: D400570
Product name: Di-O-acetyl-L-tartaricAnhydride
Packaging: 1g
Price: $55
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD22450
Product name: Di-O-acetyl-L-tartaric anhydride
Packaging: 250g
Price: $750
Updated: 2021/12/16

Medical Isotopes, Inc.

Product number: 9093
Product name: Di-O-acetyl-L-tartaricAnhydride
Packaging: 1g
Price: $850
Updated: 2021/12/16

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(+)-DIACETYL-L-TARTARIC ANHYDRIDE Chemical Properties,Usage,Production

Chemical Properties

White Crystalline Solid

Uses

Di-O-acetyl-L-tartaric Anhydride (cas# 6283-74-5) is a compound useful in organic synthesis.

Uses

(+)-O,O′-Diacetyl-L-tartaric anhydride may be used as a chiral derivatizating agent in the following:

determination of enantiomeric vigabatrin in mouse serum samples using ultra-high performance liquid chromatography-quadrupole-time-of-flight mass spectrometry (UHPLC-Q-TOF-M)????????
determination of trantinterol in rat plasma by ultra performance liquid chromatography–electrospray ionization mass spectrometry (UPLC–MS/MS)

General Description

(+)-O,O′-Diacetyl-L-tartaric anhydride is an HPLC derivatization reagent for UV/Vis detection. It is mainly employed as a reagent for the chiral derivatization of amino alcohols. It also reacts with alkanoamines in aprotic medium containing trichloroacetic acid and produces tartaric acid monoesters.

Purification Methods

If the IR is good, i.e. no OH bands, then keep it in a vacuum desiccator overnight (over P2O5/paraffin) before use. If OH bands are present then reflux 4g in Ac2O (12.6mL) containing a few drops of conc H2SO4 for 10minutes (use a relatively large flask), pour onto ice, collect the crystals, wash with dry *C6H6 (2 x 2mL), stir with 17mL of cold Et2O, filter and dry in it a vacuum desiccator as above, or store it in dark evacuated ampoules under N2 in small aliquots. It is not very stable in air, the melting point of the crystals drop one degree in the first four days then remains constant (132-134o). If placed in a stoppered bottle, it becomes gummy and the m falls 100o in three days. Recrystllisation leads to decomposition. If good quality anhydride is required it, should be prepared freshly from tartaric acid. It sublimes in a CO2 atmosphere. [Shriner & Furrow Org Synth Coll Vol IV 242 1963, Bell Aust J Chem 34 671 1981, Beilstein 18 III/IV 2296.]

(+)-DIACETYL-L-TARTARIC ANHYDRIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (+)-DIACETYL-L-TARTARIC ANHYDRIDE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (+)-DIACETYL-L-TARTARIC ANHYDRIDE 6283-74-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: (+)-O,O′-Diacetyl-L-tartaric anhydride 6283-74-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

6283-74-5, (+)-DIACETYL-L-TARTARIC ANHYDRIDERelated Search:

(+/-)-3-HYDROXY-GAMMA-BUTYROLACTONE (+)-DIACETYL-L-TARTARIC ANHYDRIDE 4-Iodophenol Ethyl ethoxyacetate (-)-1,4-ANHYDRO-L-THREITOL Methyl (R)-(+)-lactate METHYL 2-METHOXYPROPIONATE Acetoxyacetic acid (R)-(+)-2-Acetoxysuccinic anhydride (R)-(+)-2-METHOXYPROPIONIC ACID (R)-(+)-ALPHA-HYDROXY-GAMMA-BUTYROLACTONE (+)-DIBENZOYL-L-TARTARIC ANHYDRIDE ALPHA-HYDROXY-GAMMA-BUTYROLACTONE DI-(4-TOLUOYL)-L-TARTARIC ANHYDRIDE (+/-)-2-ACETOXYPROPIONIC ACID L-Threonolactone (R)-3-ACETOXY-GAMMA-BUTYROLACTONE (-)-DIACETYL-D-TARTARIC ANHYDRIDE

(R,R)-DIACETYLTARTARIC ACID ANHYDRIDE

(+)-DIACETYL-L-TARTARIC ANHYDRIDE

DIACETYL-L-TARTARIC ANHYDRIDE

DATA

(+)-DI-O-ACETYL-L-TARTARIC ACID ANHYDRIDE

(+)-DI-O-ACETYL-L-TARTARIC ANHYDRIDE

DI-O-ACETYL-L-TARTARIC ANHYDRIDE

L-(+)-O,O'-DIACETYL-TARTARIC ACID ANHYDRIDE

(3R-trans)-dihydro-2,5-dioxofuran-3,4-diyl diacetate

(+)-DI-O-ACETYLTARTARIC ACID ANHYDRIDE

L-(+)-3,4-DIACETOXYTETRAHYDROFURAN-2,5-DIONE

(+)-O,Oμ-Diacetyl-L-tartaric anhydride

(+)-2-O,3-O-Diacetyl-L-tartaric anhydride

(2R,3R)-2,3-Diacetoxysuccinic anhydride

(3R)-2,5-Dioxotetrahydrofuran-3α,4β-diol diacetate

(3R)-3α,4β-Bis(acetyloxy)-3,4-dihydro-2,5-furandione

(3R)-3α,4β-Diacetoxyoxolane-2,5-dione

[3R,4R,(+)]-3,4-Di(acetyloxy)-3,4-dihydrofuran-2,5-dione

(+)-Diacetyl-L-tartaric anhydride,97%

(+)-DI-O-ACETYL-L-WEINSURE-ANHYDRID

O,O-diacetyl tartaric acid anhydride

(+)-Diacetyl-L-tartaric anhydride, 97% 25GR

(2R,3R)-Di-O-acetyltartaric Acid Anhydride

(3R,4R)-3,4-Bis(acetyloxy)dihydro-2,5-furandione

(R,R)-2,3-Diacetoxy-1,4-butanedioic Anhydride

NSC 7712

(3R,4R)-2,5-Dioxotetrahydrofuran-3,4-diyl diacetate

2,5-Furandione, 3,4-bis(acetyloxy)dihydro-, (3R,4R)-

(+)-O,O'-Diacetyl-L-tartaric anhydride 97%

(+)-Diacetyl-L-tartaricAnhydride&gt

(+)-O,O'-Diacetyl-L-tartaric anhydride

Di-O-Acetyl-L-tartaric anhydrideQ: What is Di-O-Acetyl-L-tartaric anhydride Q: What is the CAS Number of Di-O-Acetyl-L-tartaric anhydride Q: What is the storage condition of Di-O-Acetyl-L-tartaric anhydride

(+)-Diacetyl-L-tartaric Anhydride

(AOTH) (+)-DIACETYL-L-TARTARIC ANHYDRIDE

6283-74-5

C8H8O7

for Resolution of Bases

Optical Resolution

Asymmetric Synthesis

Chiral Resolution Reagents

Chiral Resolving Reagents

UV-VIS

Chiral Reagents

for Resolution of Bases

Optical Resolution

Synthetic Organic Chemistry