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ChemicalBook > CAS DataBase List > (S)-(+)-KETOPINIC ACID

(S)-(+)-KETOPINIC ACID

Uses
Product Name
(S)-(+)-KETOPINIC ACID
CAS No.
40724-67-2
Chemical Name
(S)-(+)-KETOPINIC ACID
Synonyms
(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid;(1S)-7;(+)-Ketopinic acid;(S)-(+)-onepinic acid;(S)-(+)-KETOPINIC ACID;(1S)-(+)-KETOPINIC ACID;(S)-(+)-KetopinicAcid>(1S)-(+)-Ketopinic acid 99%;(1S)-(+)-KETOPINIC ACID 97+%;(1S,4R)-2-Oxobornane-10-oic acid
CBNumber
CB0748218
Molecular Formula
C10H14O3
Formula Weight
182.22
MOL File
40724-67-2.mol
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(S)-(+)-KETOPINIC ACID Property

Melting point:
237-239 °C(lit.)
alpha 
58 º (C=1 IN CHLOROFORM)
Boiling point:
313.3±25.0 °C(Predicted)
Density 
1.238±0.06 g/cm3(Predicted)
refractive index 
25.5 ° (C=0.65, MeOH)
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
pka
3.67±0.40(Predicted)
color 
White to Almost white
optical activity
[α]23/D +58°, c = 1 in chloroform
BRN 
4180005
CAS DataBase Reference
40724-67-2(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
2918300090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
420964
Product name
(1S)-(+)-Ketopinic acid
Purity
99%
Packaging
1g
Price
$77
Updated
2024/03/01
TCI Chemical
Product number
K0028
Product name
(S)-(+)-Ketopinic Acid
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$72
Updated
2024/03/01
TCI Chemical
Product number
K0028
Product name
(S)-(+)-Ketopinic Acid
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$285
Updated
2024/03/01
TRC
Product number
D460165
Product name
7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylicAcid
Packaging
500mg
Price
$175
Updated
2021/12/16
Chem-Impex
Product number
39504
Product name
(S)-(+)-Ketopinicacid,98%(Assaybytitration,GC)
Purity
98%(Assaybytitration,GC)
Packaging
5G
Price
$241.92
Updated
2021/12/16
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(S)-(+)-KETOPINIC ACID Chemical Properties,Usage,Production

Uses

7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic Acid is a useful reactant for the preparation of alkenyl nitrile electrophiles for the possible use of covalent protein labeling.

Uses

(1S)-(+)-Ketopinic acid may be used to prepare:

  • Chiral phosphine-oxazoline ligands, which can used in asymmetric palladium-catalyzed Heck reaction of aryl or alkenyl triflates with cyclic alkenes.
  • A chiral imino-phosphine ligand, which can be used in palladium-catalyzed asymmetric Diels–Alder reactions to prepare six-membered carbocycles.
  • A chiral iminopyridine ligand, which can be used in copper-catalyzed Henry (nitro aldol) reaction between nitromethane and o-anisol to form the corresponding β-hydroxynitroalkane.

Uses

7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic Acid is a useful reactant for the preparation of alkenyl nitrile electrophiles for the possible use of covalent protein labeling.

General Description

(1S)-(+)-Ketopinic acid is a chiral ketone.

(S)-(+)-KETOPINIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(+)-KETOPINIC ACID Suppliers

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View Lastest Price from (S)-(+)-KETOPINIC ACID manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(S)-(+)-KETOPINIC ACID 40724-67-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
(S)-(+)-KETOPINIC ACID 40724-67-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
(S)-(+)-KETOPINIC ACID 40724-67-2
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2020-01-12

40724-67-2, (S)-(+)-KETOPINIC ACIDRelated Search:


  • (1S)-(+)-KETOPINIC ACID
  • (1S)-(+)-KETOPINIC ACID 97+%
  • (1s)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
  • (S)-7,7-DIMETHYL-2-OXO-BICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID
  • (S)-(+)-KETOPINIC ACID
  • rac-(1S*,4R*)-2-Oxobornane-10-oic acid
  • (1S,4R)-2-Oxobornane-10-oic acid
  • (1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]-1-carboxylic acid
  • (1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
  • (4α)-2-Oxo-7,7-dimethylbicyclo[2.2.1]heptane-1β-carboxylic acid
  • Bicyclo[2.2.1]heptane-1-carboxylic acid, 7,7-dimethyl-2-oxo-, (1S,4R)-
  • (1S)-(+)-Ketopinic acid,(1S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
  • (1S)-(+)-Ketopinic acid 99%
  • (1S)-7
  • 7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanecarboxylic acid
  • (S)-(+)-KetopinicAcid&gt
  • (1S,4R)-7,7-dimethyl-2-oxo-bicyclo[2.2.1]heptane-1-methanoic acid
  • (S)-(+)-onepinic acid
  • (+)-Ketopinic acid
  • 40724-67-2
  • Chiral Building Blocks
  • Carboxylic Acids
  • Terpenes
  • Asymmetric Synthesis
  • Bicyclic Monoterpenes
  • Organic Building Blocks
  • Asymmetric Synthesis
  • Bicyclic Monoterpenes
  • Biochemistry
  • Synthetic Organic Chemistry
  • Terpenes
  • Chiral Reagents