ChemicalBook > CAS DataBase List > 4-BROMO-N-METHOXY-N-METHYLBENZAMIDE

4-BROMO-N-METHOXY-N-METHYLBENZAMIDE

Product Name
4-BROMO-N-METHOXY-N-METHYLBENZAMIDE
CAS No.
192436-83-2
Chemical Name
4-BROMO-N-METHOXY-N-METHYLBENZAMIDE
Synonyms
4-BROMO-N-METHOXY-N-METHYLBENZAMIDE;Benzamide, 4-bromo-N-methoxy-N-methyl-;4-[Methoxy(methyl)carbamoyl]bromobenzene
CBNumber
CB0752002
Molecular Formula
C9H10BrNO2
Formula Weight
244.09
MOL File
192436-83-2.mol
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4-BROMO-N-METHOXY-N-METHYLBENZAMIDE Property

refractive index 
1.5680 to 1.5720
storage temp. 
Sealed in dry,Room Temperature
form 
clear liquid
color 
Colorless to Light yellow
CAS DataBase Reference
192436-83-2
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Safety

HS Code 
2928009090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B5728
Product name
4-Bromo-N-methoxy-N-methylbenzamide
Purity
>95.0%(GC)
Packaging
1g
Price
$64
Updated
2025/07/31
TCI Chemical
Product number
B5728
Product name
4-Bromo-N-methoxy-N-methylbenzamide
Purity
>95.0%(GC)
Packaging
5g
Price
$194
Updated
2025/07/31
TRC
Product number
B686868
Product name
4-Bromo-N-methoxy-N-methylbenzamide
Packaging
50mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
J51089
Product name
4-Bromo-N-methoxy-N-methylbenzamide
Packaging
25g
Price
$840
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0023209
Product name
4-BROMO-N-METHOXY-N-METHYLBENZAMIDE
Purity
95.00%
Packaging
50G
Price
$2820.86
Updated
2021/12/16
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4-BROMO-N-METHOXY-N-METHYLBENZAMIDE Chemical Properties,Usage,Production

Synthesis

6638-79-5

586-75-4

192436-83-2

To a stirred dichloromethane solution (300 mL) of 4-bromobenzoyl chloride (20.0 g, 91.1 mmol) was added triethylamine (28.0 mL, 200.0 mmol) and O,N-dimethylhydroxylamine hydrochloride (9.33 g, 95.6 mmol) at -78 °C. The reaction mixture was slowly warmed to room temperature and stirred continuously for 1.5 hours. After completion of the reaction, the mixture was concentrated to remove the solvent. The residue was ground with acetone and the solid obtained was dissolved in ethyl acetate and washed sequentially with water and brine. The organic layer was dried with anhydrous magnesium sulfate, filtered and concentrated to give 4-bromo-N-methoxy-N-methylbenzamide (18.6 g, 84% yield).

References

[1] Angewandte Chemie - International Edition, 2010, vol. 49, # 17, p. 3073 - 3076
[2] Bioorganic and Medicinal Chemistry Letters, 2015, vol. 25, # 17, p. 3694 - 3698
[3] European Journal of Organic Chemistry, 2017, vol. 2017, # 46, p. 6840 - 6850
[4] Bioorganic and Medicinal Chemistry Letters, 2010, vol. 20, # 4, p. 1415 - 1419
[5] Patent: US2007/66628, 2007, A1. Location in patent: Page/Page column 15

4-BROMO-N-METHOXY-N-METHYLBENZAMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-BROMO-N-METHOXY-N-METHYLBENZAMIDE Suppliers

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View Lastest Price from 4-BROMO-N-METHOXY-N-METHYLBENZAMIDE manufacturers

Qingdao RENAS Polymer Material Co., Ltd.
Product
4-bromo-N-methoxy-N-methylbenzamide 192436-83-2
Price
US $0.00/kg
Min. Order
20kg
Purity
99%
Supply Ability
20 tons
Release date
2025-05-12

192436-83-2, 4-BROMO-N-METHOXY-N-METHYLBENZAMIDERelated Search:

4-BROMO-N-CYCLOPROPYL-2-METHYL-BENZAMIDE(WXG00232) 4-BroMo-2-(diMethylaMino)pyridine N-METHOXY-N-METHYLBENZAMIDE N-[4-(aminosulfonyl)phenyl]-5-bromo-2-methoxy-3-methylbenzamide 3-BROMO-N-METHOXY-N-METHYLBENZAMIDE N-BENZYL-3-BROMO-4-METHOXY-N-METHYLBENZAMIDE N-[2-(4-acetyl-1-piperazinyl)phenyl]-5-bromo-2-methoxy-3-methylbenzamide 4-BROMO-3-METHOXY-N-METHYLBENZAMIDE 3-bromo-4-methoxy-N-methylbenzamide N-(2,1,3-benzothiadiazol-4-yl)-5-bromo-2-methoxy-3-methylbenzamide N-(4-aminophenyl)-2-bromo-5-methoxy-N-methylbenzamide 4-BROMO-2-FLUORO-N-METHOXY-N-METHYLBENZAMIDE 4-BROMO-3-FLUORO-N-METHOXY-N-METHYL-BENZAMIDE 4-bromo-N-hydroxybenzamide 4-BROMO-N-METHOXY-N-METHYLBENZAMIDE

  • 4-BROMO-N-METHOXY-N-METHYLBENZAMIDE
  • 4-[Methoxy(methyl)carbamoyl]bromobenzene
  • Benzamide, 4-bromo-N-methoxy-N-methyl-
  • 192436-83-2