VANADIUM(III) CHLORIDE
- Product Name
- VANADIUM(III) CHLORIDE
- CAS No.
- 7718-98-1
- Chemical Name
- VANADIUM(III) CHLORIDE
- Synonyms
- VCl3;VANADIUM CHLORIDE;VANADIUM TRICHLORIDE;trichlorovanadium;Vanadium(Ⅲ)chloride;Vanadium(Ⅳ)chloride;VANADIUM(III) CHLORIDE;vanadiumchloride(vcl3);Trichlorovanadium(III);Vanadium chloride (VCl3)
- CBNumber
- CB0753498
- Molecular Formula
- Cl3V
- Formula Weight
- 157.29
- MOL File
- 7718-98-1.mol
VANADIUM(III) CHLORIDE Property
- Melting point:
- 250 °C
- Density
- 3 g/mL at 25 °C(lit.)
- storage temp.
- no restrictions.
- solubility
- Soluble in tetrahydrofuran, alcohol, ether and hydrocarbons.
- form
- Powder
- color
- Dark blue to violet to black
- Specific Gravity
- 3.
- Water Solubility
- decomposes in H2O; soluble alcohol, ether [HAW93]
- Sensitive
- Moisture Sensitive
- Exposure limits
- NIOSH: Ceiling 0.05 mg/m3
- CAS DataBase Reference
- 7718-98-1(CAS DataBase Reference)
- EPA Substance Registry System
- Vanadium chloride (VCl3) (7718-98-1)
Safety
- Hazard Codes
- C
- Risk Statements
- 22-34
- Safety Statements
- 26-27-28-36/39-45
- RIDADR
- UN 2475 8/PG 3
- WGK Germany
- 3
- RTECS
- YW2800000
- F
- 3-10
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 28273990
- Toxicity
- LD50 orally in Rabbit: 350 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 208272
- Product name
- Vanadium(III) chloride
- Purity
- 97%
- Packaging
- 1g
- Price
- $39.2
- Updated
- 2024/03/01
- Product number
- 208272
- Product name
- Vanadium(III) chloride
- Purity
- 97%
- Packaging
- 5g
- Price
- $48.8
- Updated
- 2024/03/01
- Product number
- 1.12393
- Product name
- Vanadium(III) chloride
- Purity
- 99+
- Packaging
- 25g
- Price
- $180
- Updated
- 2024/03/01
- Product number
- 014039
- Product name
- Vanadium(III) chloride
- Purity
- 99% (metals basis)
- Packaging
- 10g
- Price
- $103
- Updated
- 2024/03/01
- Product number
- 014039
- Product name
- Vanadium(III) chloride
- Purity
- 99% (metals basis)
- Packaging
- 50g
- Price
- $443
- Updated
- 2023/06/20
VANADIUM(III) CHLORIDE Chemical Properties,Usage,Production
Chemical Properties
Pink, deliquescent crystals. Decomposes on heating. Soluble in absolute alcohol and ether; decomposes in water.
Uses
Vanadium(III) chloride has been used as a catalyst for Biginelli condensation. As a reducing agent, it is capable of converting nitrate to nitrite in water samples, allowing for the direct detection of nitrates.
Uses
Preparation of vanadium dichloride and organovanadium compounds.
General Description
Vanadium trichloride acts as a reducing agent.
Air & Water Reactions
Deliquescent. Generates acid mists when exposed to moist air. Dissolves in water with formation of an acidic solution and generation of acidic fumes.
Reactivity Profile
VANADIUM(III) CHLORIDE attacks many organic compounds. Can catalyze organic reactions. Aqueous solutions react as acids to neutralize bases. These neutralizations generate heat, but less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. Combination of the trichloride with methylmagnesium iodide, or other Grignard type reagents, can be violently explosive under a variety of conditions, Chem. Rev., 1955, 55, 560.
Health Hazard
TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
Flammability and Explosibility
Not classified
Safety Profile
Poison by ingestion and subcutaneous routes. A corrosive irritant to skin, eyes, and mucous membranes. Extremely violent reaction with methyl magnesium iodide and other Grignard reagents. When heated to decomposition it emits toxic fumes of VOx and Cl-. See also VANADIUM COMPOUNDS and HYDROCHLORIC ACID.
VANADIUM(III) CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
VANADIUM(III) CHLORIDE Suppliers
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View Lastest Price from VANADIUM(III) CHLORIDE manufacturers
- Product
- VANADIUM(III) CHLORIDE 7718-98-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11