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SCANDIUM SULFIDE

Product Name
SCANDIUM SULFIDE
CAS No.
12166-29-9
Chemical Name
SCANDIUM SULFIDE
Synonyms
SCANDIUM SULFIDE;scandium(III) sulfide;discandium trisulphide;SCANDIUM(III) SULFIDE, 99.99%;Scandium (III) sulfide, 99.9% (metals basis)
CBNumber
CB0755230
Molecular Formula
H2SSc
Formula Weight
79.03
MOL File
12166-29-9.mol
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SCANDIUM SULFIDE Property

Melting point:
1775°C
Density 
2.910
form 
yellow orthorhombic crystals
color 
yellow orthorhombic crystals, crystalline
crystal system
Nogata
Space group
Fddd
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
1.0410.7382.2059090901.694
EPA Substance Registry System
Scandium sulfide (Sc2S3) (12166-29-9)
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
ING0026157
Product name
SCANDIUM SULFIDE
Purity
95.00%
Packaging
5MG
Price
$451.35
Updated
2021/12/16
Rare Earth Products
Product number
S2118
Product name
Scandium sulfide, 99.9% (REO)
Purity
99.9% (REO)
Packaging
1gm
Price
$57
Updated
2021/12/16
Rare Earth Products
Product number
S2118
Product name
Scandium sulfide, 99.9% (REO)
Purity
99.9% (REO)
Packaging
5gm
Price
$269
Updated
2021/12/16
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SCANDIUM SULFIDE Chemical Properties,Usage,Production

Preparation

Scandium(III) sulfide, Sc2S3, is a yellow solid. Metal sulfides are typically prepared by heating mixtures of the two elements, but in the case of scandium, this method results in the formation of scandium monosulfide, ScS. Sc2S3 can be produced by heating scandium(III) oxide under flowing hydrogen sulfide in a graphite crucible to 1550℃ or higher for 2-3 hours. The crude product is subsequently purified by chemical vapor transport at 950℃  utilizing iodine as the transport agent.
Sc2O3+3H2S→Sc2S3 +3H2O

Structure and conformation

The crystal structure of Sc2S3 is similar to that of sodium chloride, in that it is based on a cubic close-packed array of anions. While NaCl has all the octahedral interstices in the anion lattice occupied by cations, Sc2S3 has one-third of them vacant. The vacancies are ordered, but in a very complicated pattern, resulting in a large, orthorhombic unit cell belonging to the space group Fddd. Above 1100℃, Sc2S3 loses sulfur, resulting in nonstoichiometric compounds such as Sc1.37S2.

SCANDIUM SULFIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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