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2,2-DIMETHOXYPROPIONIC ACID METHYL ESTER

Product Name
2,2-DIMETHOXYPROPIONIC ACID METHYL ESTER
CAS No.
10076-48-9
Chemical Name
2,2-DIMETHOXYPROPIONIC ACID METHYL ESTER
Synonyms
METHYL 2,2-DIMETHOXYPROPIONATE;METHYL 2,2-DIMETHOXYPROPANOATE;METHYL PYRUVATE DIMETHYL ACETAL;Methyl2,2-Dimethoxypropionate>Dimethoxypropionicacidmethylester;2,2-DIMETHOXYPROPIONIC ACID METHYL ESTER;Propanoic acid, 2,2-dimethoxy-, methyl ester;2,2-DIMETHOXYPROPIONIC ACID METHYL ESTER, 96+%
CBNumber
CB0755447
Molecular Formula
C6H12O4
Formula Weight
148.16
MOL File
10076-48-9.mol
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2,2-DIMETHOXYPROPIONIC ACID METHYL ESTER Property

Boiling point:
70 °C / 13mmHg
Density 
1.07
refractive index 
1.4100-1.4120
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
clear liquid
color 
Colorless to Almost colorless
CAS DataBase Reference
10076-48-9
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Safety

HS Code 
2918.19.9000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
D2382
Product name
Methyl 2,2-Dimethoxypropionate
Purity
>96.0%(GC)
Packaging
25g
Price
$241
Updated
2025/07/31
TRC
Product number
M303733
Product name
Methyl2,2-Dimethoxypropanoate
Packaging
250mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
0266AA
Product name
Methyl2,2-dimethoxypropanoate
Packaging
25g
Price
$370
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0007543
Product name
2,2-DIMETHOXYPROPIONIC ACID METHYL ESTER
Purity
95.00%
Packaging
5MG
Price
$500.6
Updated
2021/12/16
Ambeed
Product number
A167678
Product name
Methyl2,2-dimethoxypropanoate
Purity
98%
Packaging
5g
Price
$60
Updated
2021/12/16
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2,2-DIMETHOXYPROPIONIC ACID METHYL ESTER Chemical Properties,Usage,Production

Synthesis

600-22-6

149-73-5

10076-48-9

General procedure for the synthesis of methyl 2,2-dimethoxypropionate from methyl pyruvate and trimethyl orthoformate: 100 g (979 mmol) of methyl pyruvate was mixed with 135 g (1273 mmol) of trimethyl orthoformate in 240 ml of methanol. After adding 0.96 g (9.79 mmol) of concentrated sulfuric acid, the mixture was heated to reflux for 4 hours. Subsequently, the solvent was distilled out over 2 h. The crude product was cooled to 10 °C and added to a solution of 2.4 g of potassium hydroxide in 1200 ml of water at 10 °C. After repeated extraction with ether, the organic phases were combined and dried over anhydrous sodium sulfate, filtered and concentrated. The residue was distilled under reduced pressure and the fractions with boiling points of 50-55°C (10 mbar) were collected. Finally 118 g (77% yield) of the target product was obtained.1H NMR (CDCl3) data were as follows: δ = 1.53 (s, 3H, C-CH3), 3.29 (s, 6H, CH3-OCO-CH3), 3.82 (s, 3H, COOCH3).

References

[1] Journal of the American Chemical Society, 1983, vol. 105, # 7, p. 2021 - 2029
[2] Patent: US2015/245616, 2015, A1. Location in patent: Paragraph 0189; 0190

2,2-DIMETHOXYPROPIONIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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