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(+)-CHLOROMETHYL MENTHYL ETHER

Product Name
(+)-CHLOROMETHYL MENTHYL ETHER
CAS No.
103128-76-3
Chemical Name
(+)-CHLOROMETHYL MENTHYL ETHER
Synonyms
(+)-CHLOROMETHYL MENTHYL ETHER;(+)-Chloromethyl menthyl ether;(+)-Chloromethyl menthyl ether, 97% ee;(1R,2S,4S)-2-(chloromethoxy)-1-isopropyl-4-methyl-cyclohexane;(1R,2S,4S)-2-(CHLOROMETHYLOXY)-1-ISOPROPYL-4-METHYLCYCLOHEXANE;Cyclohexane, 2-(chloromethoxy)-4-methyl-1-(1-methylethyl)-, (1R,2S,4S)-
CBNumber
CB0771672
Molecular Formula
C11H21ClO
Formula Weight
204.74
MOL File
103128-76-3.mol
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(+)-CHLOROMETHYL MENTHYL ETHER Property

Boiling point:
72 °C/0.4 mmHg (lit.)
Density 
0.994 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.467(lit.)
Flash point:
225 °F
storage temp. 
-20°C
optical activity
[α]24/D +181.0°, c = 2 in methylene chloride
CAS DataBase Reference
103128-76-3
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
349925
Product name
(+)-Chloromethyl menthyl ether
Purity
97%
Packaging
5g
Price
$170
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
HCH0009236
Product name
(+)-CHLOROMETHYL MENTHYL ETHER
Purity
95.00%
Packaging
5G
Price
$915.02
Updated
2021/12/16
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(+)-CHLOROMETHYL MENTHYL ETHER Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

(+)-Chloromethyl menthyl ether can be used:

  • As a starting material for the synthesis of 1-methyl-3-(+)-methylmenthoxide imidazolium chloride, a key intermediate for the preparation of Ag(I) N-heterocyclic carbene, applicable as a catalyst in the diboration of alkenes.
  • As a substrate in the synthesis of commercially important O-substituted α-methoxymethylketones.
  • To determine enantiomeric excess (ee) of an iron chiral auxiliary named [Fe(CO)(η;5- C2H5)(PPh3)COCH3].

(+)-CHLOROMETHYL MENTHYL ETHER Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-CHLOROMETHYL MENTHYL ETHER Suppliers

Belgium 1 China 6 France 1 Germany 1 Japan 1 Switzerland 1 United States 4 Global 15
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
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Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51471
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Birdo (Shanghai) Medical Technology Co., Ltd.
Tel
021-021-021-58099077-8102-8041-8041 18601625411
Email
sales@birdotech.com
Country
China
ProdList
8675
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Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
4008210725 4008210725
Email
malulu@leyan.com
Country
China
ProdList
55023
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Shanghai Aladdin Biochemical Technology Co.,Ltd.
Tel
+86-18521732826
Email
market@aladdin-e.com
Country
China
ProdList
48467
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Henan Tianfu Chemical Co.,Ltd.
Tel
+86-0371-55170693 +86-19937530512
Fax
0371-55170693
Email
info@tianfuchem.com
Country
China
ProdList
21689
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Aladdin Scientific
Tel
+1-833-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
52927
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58

103128-76-3, (+)-CHLOROMETHYL MENTHYL ETHERRelated Search:

(-)-CHLOROMETHYL MENTHYL ETHER (-)-CHLOROMETHYL MENTHYL ETHER (+)-Chloromethyl menthyl ether, 95%, 97% e.e. (+)-MENTHYL CHLOROFORMATE CHLOROMETHYL CYCLOHEXYL ETHER (+)-CHLOROMETHYL MENTHYL ETHER

  • (1R,2S,4S)-2-(CHLOROMETHYLOXY)-1-ISOPROPYL-4-METHYLCYCLOHEXANE
  • (+)-CHLOROMETHYL MENTHYL ETHER
  • (+)-Chloromethyl menthyl ether, 97% ee
  • Cyclohexane, 2-(chloromethoxy)-4-methyl-1-(1-methylethyl)-, (1R,2S,4S)-
  • (1R,2S,4S)-2-(chloromethoxy)-1-isopropyl-4-methyl-cyclohexane
  • (+)-Chloromethyl menthyl ether
  • 103128-76-3
  • Ethers
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  • Chiral Building Blocks
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • Ethers
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