ChemicalBook > CAS DataBase List > (1,3-Dimesitylimidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate)

(1,3-Dimesitylimidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate)

Product Name
(1,3-Dimesitylimidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate)
CAS No.
2230140-59-5
Chemical Name
(1,3-Dimesitylimidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate)
Synonyms
Ni(IMes)(Di-tert-butyl Fumarate)2;(1,3-Dimesitylimidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate);(1,3-Dimesityl-2,3-dihydro-1H-imidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate);[1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]bis(di-tert-butyl Fumarate) Nickel(0)
CBNumber
CB08142838
Molecular Formula
C45H60N2NiO8
Formula Weight
815.67
MOL File
2230140-59-5.mol
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(1,3-Dimesitylimidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate) Property

form 
powder
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H350May cause cancer

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P285In case of inadequate ventilation wear respiratory protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P341IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

P314Get medical advice/attention if you feel unwell.

P321Specific treatment (see … on this label).

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P342+P311IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
908711
Product name
Ni(IMes)(di-t-butyl fumarate)2
Packaging
100MG
Price
$148
Updated
2024/03/01
Sigma-Aldrich
Product number
908711
Product name
Ni(IMes)(di-t-butyl fumarate)2
Packaging
250MG
Price
$266
Updated
2024/03/01
Strem Chemicals
Product number
28-1040
Product name
Bis(di-tert-butyl fumarate)(1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene)nickel(0), 96%
Purity
96%
Packaging
100mg
Price
$187
Updated
2023/06/20
Strem Chemicals
Product number
28-1040
Product name
Bis(di-tert-butyl fumarate)(1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene)nickel(0), 96%
Purity
96%
Packaging
500mg
Price
$746
Updated
2023/06/20
Chem-Impex
Product number
40666
Product name
(1,3-Dimesitylimidazol-2-ylidene)nickel(0)bis(di-tert-butylfumarate),98%(Assaybytitration)
Purity
98%(Assaybytitration)
Packaging
100MG
Price
$256.48
Updated
2021/12/16
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(1,3-Dimesitylimidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate) Chemical Properties,Usage,Production

Uses

Ni(IMes)(di-t-butyl fumarate)2 is an NHC-Ni(0) precatalyst developed in the Montgomery lab used for a variety of synthetic transformations including reductive couplings of aldehydes and alkynes and N-arylation of amines.

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

(1,3-Dimesitylimidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate) Preparation Products And Raw materials

Raw materials

Preparation Products

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(1,3-Dimesitylimidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate) Suppliers

TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75

2230140-59-5, (1,3-Dimesitylimidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate)Related Search:


  • (1,3-Dimesitylimidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate)
  • (1,3-Dimesityl-2,3-dihydro-1H-imidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate)
  • [1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]bis(di-tert-butyl Fumarate) Nickel(0)
  • Ni(IMes)(Di-tert-butyl Fumarate)2
  • 2230140-59-5