tert-Butyl peroxyneodecanoate Property

Density 

0.898[at 20℃]

vapor pressure 

4.65Pa at 25℃

Water Solubility 

13mg/L at 25℃

InChI

InChI=1S/C14H26O4/c1-12(2,3)9-7-8-10-14(17-18-14)11(15)16-13(4,5)6/h7-10H2,1-6H3

InChIKey

JOIPTRRGOVGQPJ-UHFFFAOYSA-N

SMILES

C(OC(C)(C)C)(=O)C1(OO1)CCCCC(C)(C)C

LogP

5 at 25℃

CAS DataBase Reference

26748-41-4

EPA Substance Registry System

Neodecaneperoxoic acid, 1,1-dimethylethyl ester (26748-41-4)

Safety

RIDADR 

3115

HazardClass 

5.2

PackingGroup 

II

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H242Heating may cause a fire

H315Causes skin irritation

H317May cause an allergic skin reaction

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P234Keep only in original container.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P363Wash contaminated clothing before reuse.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P411Store at temperatures not exceeding … oC/…oF.

P420Store away from other materials.

P501Dispose of contents/container to..…

tert-Butyl peroxyneodecanoate Chemical Properties,Usage,Production

Uses

t-Butyl Peroxyneodecanoate is useful as a low-temperature initiator for radicalcatalyzed polymerization of vinyl monomers.

General Description

tert-Butyl peroxyneodecanoate is sensitive to heat. Storage of tert-Butyl peroxyneodecanoate must be done so with stringent temperature control measures. It's explosion hazard is also mitigated by mixing the peroxide in an organic solvent slurry. Responders should try to identify solvent.

Reactivity Profile

TERT-BUTYL PEROXYNEODECANOATE explodes with great violence when rapidly heated to a critical temperature; pure form is shock sensitive and detonable [Bretherick 1979 p. 602].

Flammability and Explosibility

Not classified