hexahydro-3,6-methanophthalic anhydride
- Product Name
- hexahydro-3,6-methanophthalic anhydride
- CAS No.
- 6004-79-1
- Chemical Name
- hexahydro-3,6-methanophthalic anhydride
- Synonyms
- Einecs 227-852-8;hexahydro-3,6-methanophthalic anhydride;4-Oxatricyclo[5.2.1.02,6]decane-3,5-dione;Hexahydro-4,7-Methanoisobenzofuran-1,3-dione;4,7-Methanoisobenzofuran-1,3-dione, hexahydro-;Bicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride;3a,4,5,6,7,7a-Hexahydro-4,7-methanoisobenzofuran-1,3-dione
- CBNumber
- CB0887494
- Molecular Formula
- C9H10O3
- Formula Weight
- 166.17
- MOL File
- 6004-79-1.mol
hexahydro-3,6-methanophthalic anhydride Property
- Boiling point:
- 325.2±11.0 °C(Predicted)
- Density
- 1.345
- InChI
- InChI=1S/C9H10O3/c10-8-6-4-1-2-5(3-4)7(6)9(11)12-8/h4-7H,1-3H2
- InChIKey
- LQOPXMZSGSTGMF-UHFFFAOYSA-N
- SMILES
- C1(=O)C2C(C3CC2CC3)C(=O)O1
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- CHM0392697
- Product name
- HEXAHYDRO-4,7-METHANOISOBENZOFURAN-1,3-DIONE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $505.66
- Updated
- 2021/12/16
- Product number
- 6004791
- Product name
- Hexahydro-4,7-methanoisobenzofuran-1,3-dione
- Packaging
- 1g
- Price
- $615.44
- Updated
- 2021/12/16
- Product number
- CM158221
- Product name
- hexahydro-4,7-methanoisobenzofuran-1,3-dione
- Purity
- 95%
- Packaging
- 1g
- Price
- $729
- Updated
- 2021/12/16
- Product number
- CD11096752
- Product name
- Hexahydro-4,7-methanoisobenzofuran-1,3-dione
- Purity
- 95+%
- Packaging
- 1g
- Price
- $772
- Updated
- 2021/12/16
hexahydro-3,6-methanophthalic anhydride Chemical Properties,Usage,Production
Synthesis
The production method uses maleic anhydride and mixed C5s as raw materials, generates Nadic anhydride by absorbing cyclopentadiene with maleic anhydride directly at a temperature of 0-5°C, and crystallizes to obtain a pure product; and a Cu-Ni/ZnO-ZrO2 or Co-Ni/ZnO-ZrO2 catalyst is added to the generated Nadic anhydride, carrying out a catalytic hydrogenation reaction in a high-pressure autoclave for 4-6 hours at a temperature of 100-140°C and under a hydrogen pressure of 1-4 MPa, the catalyst is filtered after cooling, and reduced pressure distilling to obtain the hexahydro-3,6-methanophthalic anhydride.[1]
References
[1] Endo-methylene hexahydrophthalic anhydride and production method thereof. Patent EP2495241A1.
hexahydro-3,6-methanophthalic anhydride Preparation Products And Raw materials
Raw materials
Preparation Products
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