ChemicalBook > CAS DataBase List > hexahydro-3,6-methanophthalic anhydride

hexahydro-3,6-methanophthalic anhydride

Product Name
hexahydro-3,6-methanophthalic anhydride
CAS No.
6004-79-1
Chemical Name
hexahydro-3,6-methanophthalic anhydride
Synonyms
Einecs 227-852-8;hexahydro-3,6-methanophthalic anhydride;4-Oxatricyclo[5.2.1.02,6]decane-3,5-dione;Hexahydro-4,7-Methanoisobenzofuran-1,3-dione;4,7-Methanoisobenzofuran-1,3-dione, hexahydro-;Bicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride;3a,4,5,6,7,7a-Hexahydro-4,7-methanoisobenzofuran-1,3-dione
CBNumber
CB0887494
Molecular Formula
C9H10O3
Formula Weight
166.17
MOL File
6004-79-1.mol
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hexahydro-3,6-methanophthalic anhydride Property

Boiling point:
325.2±11.0 °C(Predicted)
Density 
1.345
InChI
InChI=1S/C9H10O3/c10-8-6-4-1-2-5(3-4)7(6)9(11)12-8/h4-7H,1-3H2
InChIKey
LQOPXMZSGSTGMF-UHFFFAOYSA-N
SMILES
C1(=O)C2C(C3CC2CC3)C(=O)O1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
CHM0392697
Product name
HEXAHYDRO-4,7-METHANOISOBENZOFURAN-1,3-DIONE
Purity
95.00%
Packaging
5MG
Price
$505.66
Updated
2021/12/16
Alichem
Product number
6004791
Product name
Hexahydro-4,7-methanoisobenzofuran-1,3-dione
Packaging
1g
Price
$615.44
Updated
2021/12/16
Chemenu
Product number
CM158221
Product name
hexahydro-4,7-methanoisobenzofuran-1,3-dione
Purity
95%
Packaging
1g
Price
$729
Updated
2021/12/16
Crysdot
Product number
CD11096752
Product name
Hexahydro-4,7-methanoisobenzofuran-1,3-dione
Purity
95+%
Packaging
1g
Price
$772
Updated
2021/12/16
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hexahydro-3,6-methanophthalic anhydride Chemical Properties,Usage,Production

Synthesis

The production method uses maleic anhydride and mixed C5s as raw materials, generates Nadic anhydride by absorbing cyclopentadiene with maleic anhydride directly at a temperature of 0-5°C, and crystallizes to obtain a pure product; and a Cu-Ni/ZnO-ZrO2 or Co-Ni/ZnO-ZrO2 catalyst is added to the generated Nadic anhydride, carrying out a catalytic hydrogenation reaction in a high-pressure autoclave for 4-6 hours at a temperature of 100-140°C and under a hydrogen pressure of 1-4 MPa, the catalyst is filtered after cooling, and reduced pressure distilling to obtain the hexahydro-3,6-methanophthalic anhydride.[1]

References

[1] Endo-methylene hexahydrophthalic anhydride and production method thereof. Patent EP2495241A1.

hexahydro-3,6-methanophthalic anhydride Preparation Products And Raw materials

Raw materials

Preparation Products

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hexahydro-3,6-methanophthalic anhydride Suppliers

Henan Research New Material Co., Ltd.
Tel
86-18903931531 18903931628
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sales036@researchvip.com
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China
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Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66028182 18626450290
Email
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China
ProdList
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Advantage
50
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
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sales@amadischem.com
Country
China
ProdList
131957
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021-68882955 17721395025
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Suzhou Rovathin Foreign Trade Co.,Ltd
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Hefei TNJ Chemical Industry Co.,Ltd.
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+86-0551-65418671 +8618949823763
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HUNAN CHEMFISH SCIENTIFIC CO.,LTD
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Hubei Chanmol Biotech Co., Ltd.
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6004-79-1, hexahydro-3,6-methanophthalic anhydrideRelated Search:


  • hexahydro-3,6-methanophthalic anhydride
  • 3a,4,5,6,7,7a-Hexahydro-4,7-methanoisobenzofuran-1,3-dione
  • 4-Oxatricyclo[5.2.1.02,6]decane-3,5-dione
  • Bicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride
  • Einecs 227-852-8
  • Hexahydro-4,7-Methanoisobenzofuran-1,3-dione
  • 4,7-Methanoisobenzofuran-1,3-dione, hexahydro-
  • 6004-79-1