(S)-methyl thiobenzoate
- Product Name
- (S)-methyl thiobenzoate
- CAS No.
- 5925-68-8
- Chemical Name
- (S)-methyl thiobenzoate
- Synonyms
- Einecs 227-656-2;S-Ethyl benzothioate;S-METHYL-BENZOTHIOATE;(S)-methyl thiobenzoate;S-methylbenzenecarbothioate;Thiobenzoic acid S-methyl ester;METHYLSULFANYL-PHENYL-METHANONE;Benzenecarbothioic acid, S-methyl ester
- CBNumber
- CB0931269
- Molecular Formula
- C8H8OS
- Formula Weight
- 152.21
- MOL File
- 5925-68-8.mol
(S)-methyl thiobenzoate Property
- Boiling point:
- 134 °C(Press: 25 Torr)
- Density
- 1.1381 g/cm3(Temp: 25 °C)
- FEMA
- 3857 | S-METHYL BENZOTHIOATE
- Odor
- at 0.10 % in propylene glycol. sulfurous cabbage garlic potato vegetable
- Odor Type
- sulfurous
- JECFA Number
- 504
- LogP
- 2.23
- CAS DataBase Reference
- 5925-68-8
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P330Rinse mouth.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- S918059
- Product name
- S-METHYL THIOBENZOATE
- Purity
- AldrichCPR
- Packaging
- 50mg
- Price
- $179
- Updated
- 2024/03/01
- Product number
- CCH0007496
- Product name
- (S)-METHYL THIOBENZOATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $504.8
- Updated
- 2021/12/16
(S)-methyl thiobenzoate Chemical Properties,Usage,Production
Definition
ChEBI: S-Methyl benzenecarbothioate is a member of benzoic acids.
Synthesis Reference(s)
[1] Controllable Phosphorylation of Thioesters: Selective Synthesis of Aryl and Benzyl Phosphoryl Compounds. J. Org. Chem. 2020, 85, 22, 14653–14663.
Synthesis
A mixture of a well-powdered benzoic anhydride (6.0 mmol), thiourea (6.5 mmol), and Et3N (2.5 mL) was stirred at 40 °C until the starting anhydride was completely consumed and a two-phase system containing Et3N and a thick brick-red liquid was formed. Then, water (5.0 mL) and CH3I (5.0 mmol) were added to the mixture, and stirring was continued at room temperature. After consumption of starting CH3I (3 h), the crude product was extracted with EtOAc (15 mL × 2). The crude product was purified by column chromatography over silica gel (300–400 mesh) using petroleum ether/ethyl acetate as an eluent to give analytically pure product (S)-methyl thiobenzoate.
(S)-methyl thiobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (S)-methyl thiobenzoate manufacturers
- Product
- (S)-methyl thiobenzoate 5925-68-8
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10ton
- Release date
- 2024-07-22