4-Vinylbenzocyclobutene
- Product Name
- 4-Vinylbenzocyclobutene
- CAS No.
- 99717-87-0
- Chemical Name
- 4-Vinylbenzocyclobutene
- Synonyms
- VBCB;4-VBCB;Vinylbenzocyclobutene;4-vinylbenzocyclobutene;4-Vinylbenzocyclobutene 97%;3-vinylbicyclo[4.2.0]octa-1;99717-87-0 4-Vinylbenzocyclobutene;3-vinylbicyclo[4.2.0]octa-1,3,5-triene;1-(cyclobut-1-en-1-yl)-4-ethenylbenzene;3-Ethenylbicyclo[4,2,0]octa-1,3,5-triene
- CBNumber
- CB0966450
- Molecular Formula
- C10H10
- Formula Weight
- 130.19
- MOL File
- 99717-87-0.mol
4-Vinylbenzocyclobutene Property
- Boiling point:
- 225.3±30.0 °C(Predicted)
- Density
- 0.962 g/mL at 25 °C
- refractive index
- n20/D1.578
- Flash point:
- 76℃
- storage temp.
- 2-8°C
- form
- liquid
- Appearance
- Colorless to light yellow Liquid
- InChI
- InChI=1S/C10H10/c1-2-8-3-4-9-5-6-10(9)7-8/h2-4,7H,1,5-6H2
- InChIKey
- UIJKVOGFQPSFQN-UHFFFAOYSA-N
- SMILES
- C12C(CC1)=CC=C(C=C)C=2
- CAS DataBase Reference
- 99717-87-0
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H227Combustible liquid
H302Harmful if swallowed
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P270Do not eat, drink or smoke when using this product.
P273Avoid release to the environment.
N-Bromosuccinimide Price
- Product number
- 733377
- Product name
- 4-Vinylbenzocyclobutene
- Purity
- 97%
- Packaging
- 1g
- Price
- $236
- Updated
- 2025/07/31
- Product number
- V375200
- Product name
- 4-Vinylbenzocyclobutene
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- V375200
- Product name
- 4-Vinylbenzocyclobutene
- Packaging
- 500mg
- Price
- $150
- Updated
- 2021/12/16
- Product number
- V375200
- Product name
- 4-Vinylbenzocyclobutene
- Packaging
- 1g
- Price
- $230
- Updated
- 2021/12/16
- Product number
- CS-W006426
- Product name
- 3-Vinylbicyclo[4.2.0]octa-1,3,5-triene
- Purity
- 99.76%
- Packaging
- 250mg
- Price
- $57
- Updated
- 2021/12/16
4-Vinylbenzocyclobutene Chemical Properties,Usage,Production
Chemical Properties
corloliquid
Uses
4-Vinylbenzocyclobutene is a reagent used in the process of improving the mechanical properties of carbon nanotube fibers through crosslinking.
Preparation
4-Vinylbenzocyclobutene is prepared from 4-bromobenzocyclobutene and ethylene with Pd catalyst in one step.
Synthesis
112892-88-3
99717-87-0
General procedure for the synthesis of 4-vinylbenzocyclobutene from 4-formylbenzocyclobutene: Triphenylmethylphosphonium bromide ((Ph)3PCH3Br, 24.3 g, 68.1 mmol) and 110 mL of anhydrous tetrahydrofuran (THF) were added to a 500 mL round-bottomed flask, and the solution was cooled to -78 °C. Dropwise n-butyllithium (n-BuLi, 2.5 M hexane solution, 26.4 mL, 66 mmol) was added, and then the reaction mixture was slowly warmed to room temperature. The resulting yellow-orange solution was cooled again to -78 °C and 4-formylbenzocyclobutene (7.16 g, 54.2 mmol) dissolved in 34 mL of anhydrous THF was slowly added. The mixture was warmed to room temperature and stirring was continued for 2 hours. Upon completion of the reaction, the reaction mixture was treated sequentially with saturated ammonium chloride (NH4Cl) solution and saturated sodium bicarbonate (NaHCO3) solution, and the crude product was obtained by filtration through diatomaceous earth, washed with a solvent mixture of ethyl ether/hexane (1:1), and then evaporated to dryness at room temperature. The crude product was further purified by column chromatography using 5% diethyl ether/hexane as eluent followed by Kugelrohr distillation (75 °C, 1.0 mmHg) to afford pure 4-vinylbenzocyclobutene (5.50 g, 78% yield) as a colorless liquid. The product was identified by infrared spectroscopy (IR), with the main absorption peaks located at 2925, 1627, 1473, 989, 901 and 829 cm-1 ; 1H NMR (400 MHz, CDCl3) δ 7.26 (d, 1H, J = 7.4 Hz, ArH), 7.20 (s, 1H, ArH), 7.04 (d, 1H, J = 7.4 Hz. ArH), 6.74 (dd, 1H, J = 17.5 Hz, J = 10.8 Hz, CH), 5.70 (d, 1H, J = 17.5 Hz, CH2), 5.20 (d, 1H, J = 10.8 Hz, CH2), 3.19 (s, 4H, CH2); 13C NMR (100 MHz, CDCl3) δ 146.09, 145.75, 137.94, 136.69, 125.71, 122.58, 119.90, 112.38, 29.52, and 29.35. Elemental analysis (C10H10) Calculated values: C, 92.2%; H, 7.80%. Measured values: C, 92.0%; H, 8.03%.
References
[1] Patent: WO2008/24435, 2008, A2. Location in patent: Page/Page column 95
4-Vinylbenzocyclobutene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Vinylbenzocyclobutene manufacturers
- Product
- 4-Vinylbenzocyclobutene 99717-87-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 97%
- Supply Ability
- 1000KG
- Release date
- 2025-08-13
- Product
- 3-Vinylbicyclo[4.2.0]octa-1,3,5-triene 99717-87-0
- Price
- US $3.00-9.00/KG
- Min. Order
- 0.1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2025-07-03
- Product
- 4-Vinylbenzocyclobutene 99717-87-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-09-19