ChemicalBook > CAS DataBase List > 3-Hydroxy-2-methylbenzonitrile

3-Hydroxy-2-methylbenzonitrile

Product Name: 3-Hydroxy-2-methylbenzonitrile
CAS No.: 55289-04-8
Chemical Name: 3-Hydroxy-2-methylbenzonitrile
Synonyms: 3-Hydroxy-2-methylbenzonitrile;Benzonitrile, 3-hydroxy-2-methyl-
CBNumber: CB0971685
Molecular Formula: C8H7NO
Formula Weight: 133.15
MOL File: 55289-04-8.mol

Less

3-Hydroxy-2-methylbenzonitrile Property

Melting point:: 110-111 °C
Boiling point:: 263.4±28.0 °C(Predicted)
Density: 1.17±0.1 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 8.93±0.10(Predicted)
Appearance: Light yellow to yellow Solid

Less

Hazard and Precautionary Statements (GHS)

Less

N-Bromosuccinimide Price

TRC

Product number: H972650
Product name: 3-Hydroxy-2-methylbenzonitrile
Packaging: 100mg
Price: $230
Updated: 2021/12/16

TRC

Product number: H972650
Product name: 3-Hydroxy-2-methylbenzonitrile
Packaging: 250mg
Price: $415
Updated: 2021/12/16

Matrix Scientific

Product number: 119039
Product name: 3-Hydroxy-2-methylbenzonitrile
Purity: 95+%
Packaging: 250mg
Price: $252
Updated: 2021/12/16

AK Scientific

Product number: Z4876
Product name: 3-Hydroxy-2-methylbenzonitrile
Packaging: 250mg
Price: $127
Updated: 2021/12/16

Matrix Scientific

Product number: 119039
Product name: 3-Hydroxy-2-methylbenzonitrile
Purity: 95+%
Packaging: 1g
Price: $630
Updated: 2021/12/16

Less

3-Hydroxy-2-methylbenzonitrile Chemical Properties,Usage,Production

Synthesis

77533-17-6

55289-04-8

General procedure: Preparation of 3-hydroxy-2-methylbenzonitrile (Compound 74): 3-methoxy-2-methylbenzonitrile (1 g, 6.79 mmol) and tetra-n-butylammonium iodide (4.12 g, 17 mmol) were dissolved in dichloromethane (15 mL), the solution was cooled to -78 °C and purged with nitrogen. Boron trichloride (1 M solution in dichloromethane, 17 mL, 17 mmol) was added dropwise at -78 °C and the mixture was then stirred at -78 °C for 15 min, followed by warming to room temperature and continued stirring for 3 hours. Upon completion of the reaction, the reaction mixture was quenched with water, stirred for 30 minutes and subsequently concentrated under vacuum. The aqueous residue was extracted with ether, the organic phases were combined and washed five times with water, dried with magnesium sulfate and finally concentrated under vacuum to give 3-hydroxy-2-methylbenzonitrile as a brown solid in 91% yield (826 mg). The product was confirmed by 1H NMR (400 MHz, CDCl3): δ 2.20 (s, 3H), 7.10 (m, 1H), 7.20 (d, 1H), 10.10 (s, 1H); LRMS APCI m/z 132 [M-H]-.

References

[1] Patent: US2006/160786, 2006, A1. Location in patent: Page/Page column 36-37

3-Hydroxy-2-methylbenzonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

Less

3-Hydroxy-2-methylbenzonitrile Suppliers

China 43 Germany 1 India 1 Slovakia 1 United Kingdom 1 United States 6 Global 53

Shanghai yirong biology science and technology co., ltd

Tel: 18049974220
Fax: +86 (21) 51062076
Email: 3060526242@qq.com
Country: China
ProdList: 995
Advantage: 60

SynAsst Chemical.

Tel: 021-60343070
Fax: 021-35122006
Country: China
ProdList: 12740
Advantage: 55

Shanghai Raise Chemical Technology Co.,Ltd

Tel: +86-021-50935922
Fax: +86-021-33847795
Country: China
ProdList: 7865
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

ShangHai Yuchuan Pharmaceutical Technology Co., Ltd.

Tel: 02161555100
Fax: -
Country: China
ProdList: 820
Advantage: 58

NovoChemy Ltd.

Tel: 86-(0)21-31261262 373522135
Fax: 86-(0)21-33250524
Email: sales@novochemy.com
Country: China
ProdList: 6498
Advantage: 58

Shanghai Kahn Pharmaceutical Co., Ltd.

Tel: 021-34979681; 17701870669
Fax: 021-34979681
Email: 41513101@qq.com
Country: China
ProdList: 1785
Advantage: 55

Shanghai Chenzhu Pharmaceutical Co., Ltd.

Tel: 13162380607
Fax: QQ:1696175688
Email: 1696175688@qq.com
Country: China
ProdList: 817
Advantage: 55

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Sichuan BaiPeng Biotechnology Co., Ltd.

Tel: 028-65791793 18140026355
Fax: QQ568470422
Email: 568470422@qq.com
Country: China
ProdList: 9997
Advantage: 58

Aikon International Limited

Tel: 025-66113011 13155353615
Fax: (7)02557626880
Email: qzhang@aikonchem.com
Country: China
ProdList: 15394
Advantage: 58

Suzhou Nuoouman Biological Technology Co., Ltd.

Tel: 15026866316
Email: 180642609@qq.com
Country: China
ProdList: 4967
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 400821072
Fax: 021-58955996
Email: malulu@leyan.com
Country: China
ProdList: 25000
Advantage: 58

Shanghai ZiHao Pharmaceutical Co., Ltd.

Tel: 021-13482410-12 13482410112
Fax: -
Email: 362383684@qq.com
Country: China
ProdList: 737
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 4009004166/18616739031 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52687
Advantage: 58

Shanghai Baoyisheng Biotechnology Co., LTD

Tel: 15221020695
Email: 502277408@qq.com
Country: China
ProdList: 459
Advantage: 58

Cool Pharm, Ltd

Tel: 021-58581007 18019463053
Fax: 021-50966098
Email: sales@coolpharm.com
Country: China
ProdList: 12878
Advantage: 58

wuhan Dekray Biomedical Technology Co.,Ltd

Tel: 027-69573188 18221423799
Email: 1503407886@qq.com
Country: China
ProdList: 1439
Advantage: 58

Xinyi Kangda Biological Technology Co., Ltd.

Tel: 13013943931 15152133928
Email: xinyikangda@163.com
Country: China
ProdList: 610
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: +86-0571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: China
ProdList: 52846
Advantage: 58

Career Henan Chemica Co

Tel: +86-0371-86658258 +8613203830695
Fax: 0371-86658258
Email: laboratory@coreychem.com
Country: China
ProdList: 30229
Advantage: 58

Xinyi Huaju Pharmaceutical Technology Co., Ltd.

Tel: 13761372795
Email: huajupharm@163.com
Country: China
ProdList: 806
Advantage: 58

Shaanxi Dideu Medichem Co. Ltd

Tel: +86-29-87569266 +86-17392581500
Fax: 029-88380327
Email: 1015@dideu.com
Country: China
ProdList: 3987
Advantage: 58

Wuhan chuanghao Biotechnology Co., Ltd

Tel: 13361917963
Email: 876725023@qq.com
Country: China
ProdList: 281
Advantage: 58

Fuxin Pharmaceutical

Tel: +86-021-021-50872116 +8613122107989
Email: contact@fuxinpharm.com
Country: China
ProdList: 10000
Advantage: 58

Yuzhou Enthalpy Carbon Pharmaceutical Technology Co. LTD

Tel: 19963477321; 19963477321
Fax: QQ:2041275825
Email: 2041275825@qq.com
Country: China
ProdList: 1447
Advantage: 58

Suzhou Chenrui Biotechnology Co. LTD

Tel: 17625585511
Fax: qq：1580084073
Email: 1580084073@qq.com
Country: China
ProdList: 961
Advantage: 58

Zhengzhou Convergence Chemical Co. LTD

Tel: 0371-0371-53736046 13393710386
Fax: QQ:2853979814
Email: 2853979814@qq.com
Country: China
ProdList: 9947
Advantage: 58

Energy Chemical

Tel: 021-58432009 400-005-6266
Fax: 021-58436166
Email: marketing@energy-chemical.com
Country: China
ProdList: 44918
Advantage: 58

Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Tel: 021-51816796-820 13611835272
Fax: 021-5161 3951
Email: sales2@sunwaypharm.com
Country: China
ProdList: 44119
Advantage: 58

Shanghai Hanlin biology science and technology co., ltd

Tel: 183-0212-4410 18302124410
Email: Djt18302124410@163.com
Country: China
ProdList: 3000
Advantage: 58

Hubei Co-prosperity Medicine Technonlogy Co., Ltd

Tel: 2383948258 19172820304
Email: 2383948258@qq.com
Country: China
ProdList: 12987
Advantage: 58

Beijing Jin Ming Biotechnology Co., Ltd.

Tel: 010-60605840 15801484223;
Email: psaitong@jm-bio.com
Country: China
ProdList: 29757
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-6005915
Email: sales@picasso-e.com
Country: China
ProdList: 39653
Advantage: 58

Jiaxing Zhejia Biotechnology Co., LTD

Tel: 0573-85609002 18367600069;
Email: zhejia01@163.com
Country: China
ProdList: 8886
Advantage: 58

Beijing Solarbio Science & Tecnology Co., Ltd.

Tel: 010-50973130 17801761073
Email: Gsiyu@solarbio.com
Country: China
ProdList: 50464
Advantage: 58

Shanghai Huasige Pharmaceutical Technology Co., LTD

Tel: 13611612777
Email: 3627377363@qq.com
Country: China
ProdList: 4015
Advantage: 58

Shanghai Jieshikai Biotechnology Co. , Ltd.

Tel: 021-57520305 13795461237
Email: zhuruyan@jskchem.com
Country: China
ProdList: 49234
Advantage: 58

Zhuhai Aobokai Biomedical Technology Co., Ltd.

Tel: 400-0628126 18736790110;
Email: sales-team@aobchem.com.cn
Country: China
ProdList: 50000
Advantage: 58

Shanghai Zhenzhi Pharmaceutical Technology Co., Ltd

Tel: 15262370735
Email: 404840704@qq.com
Country: China
ProdList: 109
Advantage: 58

ATK CHEMICAL COMPANY LIMITED

Tel: +undefined-21-51877795
Fax: +86 21 5161 9052/ 5187 7796
Email: ivan@atkchemical.com
Country: China
ProdList: 33024
Advantage: 60

GIHI CHEMICALS CO.,LIMITED

Tel: +8618058761490
Email: info@gihichemicals.com
Country: China
ProdList: 49941
Advantage: 58

Shanghai Hao Zhun Biological Technology Co., Ltd.

Tel: --
Fax: --
Email: info@zzsrm.com
Country: CHINA
ProdList: 6650
Advantage: 58

55289-04-8, 3-Hydroxy-2-methylbenzonitrileRelated Search:

1,4-DIHYDROXY-2,3-NAPHTHALENEDICARBONITRILE 1,4-DIACETOXY-2,3-DICYANOBENZENE 3,6-Dihydroxyphthalonitrile 3 6-DIBUTOXY-1 2-BENZENEDICARBONITRILE 3-PHENOXYPHTHALONITRILE 98 3-Hydroxy-2-methylbenzonitrile 2,3-DICYANO-1,4-DIHYDROXY-5-NITRONAPHTHALENE 3-(4-METHYLPHENOXY)-1,2-BENZENEDICARBONITRILE 1 4-DIBUTOXY-2 3-NAPHTHALENEDI- 2-(2-aminoethyl)-3-methoxybenzonitrile hydrochloride 1,4-DIBUTOXY-2,3-DICHLORO-5,6-DICYANOBENZENE 5-CHLORO-7-ISOPROPYL-2,2,4-TRIMETHYL-2,3-DIHYDRO-1-BENZOFURAN-6-CARBONITRILE 1,2-DICYANO-3-(4-NITRILEPHENYL)BENZENE 3,4-DIMETHOXY-2-METHYLBENZONITRILE 3-(2-METHOXYCARBONYL PHENOXY)-PHTHALONITRILE 3-HYDROXY-2,4,5-TRIMETHYL-BENZONITRILE 3-METHOXY-2,4,5-TRIMETHYL-BENZONITRILE

3-Hydroxy-2-methylbenzonitrile

Benzonitrile, 3-hydroxy-2-methyl-

55289-04-8