ChemicalBook > CAS DataBase List > 4-Trifluoromethyl-3-fluorobenzyl alcohol

4-Trifluoromethyl-3-fluorobenzyl alcohol

Product Name
4-Trifluoromethyl-3-fluorobenzyl alcohol
CAS No.
230295-16-6
Chemical Name
4-Trifluoromethyl-3-fluorobenzyl alcohol
Synonyms
4-Trifluoromethyl-3-fluorob;(3-Fluoro-4-(trifluoromethyl)phenyl)meth;3-Fluoro-4-(trifluoromethyl)benzenemethanol;(3-Fluoro-4-(trifluoromethyl)phenyl)methanol;3-Fluoro-4-(trifluoromethyl)benzylalcohol97%;Benzenemethanol, 3-fluoro-4-(trifluoromethyl)-;2-Fluoro-4-(hydroxymethyl)benzotrifluoride, [3-Fluoro-4-(trifluoromethyl)phenyl]methanol
CBNumber
CB0971786
Molecular Formula
C8H6F4O
Formula Weight
194.13
MOL File
230295-16-6.mol
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4-Trifluoromethyl-3-fluorobenzyl alcohol Property

Melting point:
28-32°C
Boiling point:
209℃
Density 
1.377
Flash point:
80℃
storage temp. 
Sealed in dry,Room Temperature
pka
13.76±0.10(Predicted)
Appearance
Light green to green Solid-liquid mixture
CAS DataBase Reference
230295-16-6
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Safety

HS Code 
2906290090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
F598965
Product name
3-Fluoro-4-(trifluoromethyl)benzylalcohol
Packaging
100mg
Price
$45
Updated
2021/12/16
TRC
Product number
F598965
Product name
3-Fluoro-4-(trifluoromethyl)benzylalcohol
Packaging
250mg
Price
$55
Updated
2021/12/16
TRC
Product number
F598965
Product name
3-Fluoro-4-(trifluoromethyl)benzylalcohol
Packaging
500mg
Price
$65
Updated
2021/12/16
SynQuest Laboratories
Product number
2801-3-05
Product name
3-Fluoro-4-(trifluoromethyl)benzyl alcohol
Purity
97%
Packaging
1g
Price
$26
Updated
2021/12/16
Matrix Scientific
Product number
116482
Product name
3-Fluoro-4-(trifluoromethyl)benzyl alcohol
Packaging
5g
Price
$137
Updated
2021/12/16
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4-Trifluoromethyl-3-fluorobenzyl alcohol Chemical Properties,Usage,Production

Synthesis

204339-72-0

230295-16-6

Step A: Preparation of (3-fluoro-4-(trifluoromethyl)phenyl)methanol: 3-fluoro-4-(trifluoromethyl)benzaldehyde (2.0 g, 10 mmol) and anhydrous methanol (20 mL) were added to a round-bottomed flask fitted with stirring bar. The flask was cooled in an ice bath, followed by the addition of sodium borohydride (0.47 g, 12 mmol) in batches. The ice bath was removed and the reaction mixture was allowed to warm naturally to room temperature. Saturated ammonium chloride solution (2 mL) was added and the mixture was subsequently concentrated under vacuum. The residue was diluted with additional saturated ammonium chloride solution (30 mL) and extracted with ethyl acetate (3 x 30 mL). The organic phases were combined, dried over magnesium sulfate, filtered and concentrated. Yield: 1.8 g (80%). The resulting product was used in the next reaction without further purification.

References

[1] Patent: WO2014/78331, 2014, A1. Location in patent: Paragraph 00855

4-Trifluoromethyl-3-fluorobenzyl alcohol Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Trifluoromethyl-3-fluorobenzyl alcohol Suppliers

Alfa Aesar
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400-6106006
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021-67582001/03/05
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China
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18986259541
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027-87840182
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