ChemicalBook > CAS DataBase List > 2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE

2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE

Product Name
2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE
CAS No.
89466-59-1
Chemical Name
2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE
Synonyms
2-chloro-4-Methylthio-6-methylpyrimidine;2-Chloro-4-Methyl-6-(Methylthio)pyriMidine;PyriMidine,2-chloro-4-Methyl-6-(Methylthio)-;2-Chloro-4-methylsulfanyl-6-methylpyrimidine;2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE;2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE ISO 9001：2015 REACH
CBNumber
CB11010050
Molecular Formula
C6H7ClN2S
Formula Weight
174.65
MOL File
89466-59-1.mol
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2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE Property

Melting point:
120-122 °C
Boiling point:
166-168 °C(Press: 70 Torr)
Density 
1.30±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
0.27±0.30(Predicted)
Appearance
Light yellow to yellow Solid
InChI
InChI=1S/C6H7ClN2S/c1-4-3-5(10-2)9-6(7)8-4/h3H,1-2H3
InChIKey
GLWCUQHONLZTOE-UHFFFAOYSA-N
SMILES
C1(Cl)=NC(SC)=CC(C)=N1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
C993835
Product name
2-Chloro-4-methyl-6-methylsulfanylpyrimidine
Packaging
50mg
Price
$45
Updated
2021/12/16
TRC
Product number
C993835
Product name
2-Chloro-4-methyl-6-methylsulfanylpyrimidine
Packaging
500mg
Price
$200
Updated
2021/12/16
Biosynth Carbosynth
Product number
FM12099
Product name
2-Chloro-4-methyl-6-methylsulfanylpyrimidine
Packaging
500mg
Price
$100
Updated
2021/12/16
Biosynth Carbosynth
Product number
FM12099
Product name
2-Chloro-4-methyl-6-methylsulfanylpyrimidine
Packaging
2g
Price
$210
Updated
2021/12/16
Biosynth Carbosynth
Product number
FM12099
Product name
2-Chloro-4-methyl-6-methylsulfanylpyrimidine
Packaging
5G
Price
$350
Updated
2021/12/16
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2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE Chemical Properties,Usage,Production

Synthesis

5424-21-5

5188-07-8

89466-59-1

Step 1: Synthesis of 2-chloro-4-methyl-6-(methylthio)pyrimidine. 2,4-Dichloro-6-methylpyrimidine (20.0 g, 0.123 mol) was dissolved in tetrahydrofuran (THF, 200 mL). Sodium methanethiol (20% aqueous solution, 43 g, 0.129 mol) was added slowly and dropwise at -5 °C. After the dropwise addition was completed, the reaction mixture was stirred at room temperature overnight. After completion of the reaction, water (100 mL) and ethyl acetate (EtOAc, 100 mL) were added for extraction and the organic layer was separated. The organic layer was washed twice with saturated brine, dried over anhydrous sodium sulfate and concentrated under reduced pressure to give a yellow solid. The solid was washed with petroleum ether (PE, 100 mL) to afford the target product 2-chloro-4-methyl-6-(methylthio)pyrimidine (9.1 g). Mass spectrometry (electrospray positive ion mode, ES+) analysis: the theoretical molecular weight of C6H7ClN2S was 174 and the measured value was 175 [M+H]+.

References

[1] Organic Letters, 2016, vol. 18, # 9, p. 2180 - 2183
[2] Patent: WO2015/57945, 2015, A1. Location in patent: Paragraph 00127
[3] Patent: WO2016/168619, 2016, A1. Location in patent: Paragraph 00178
[4] Patent: WO2017/79140, 2017, A1. Location in patent: Page/Page column 49
[5] Patent: WO2017/210545, 2017, A1. Location in patent: Paragraph 00181; 00182

2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE Suppliers

China 79 Germany 1 India 1 United Kingdom 4 United States 7 Global 92
NovoChemy Ltd.
Tel
021-31261262/ 49 (0)17662837245
Fax
(0)21-33250524
Email
sales@novochemy.com
Country
Germany
ProdList
6328
Advantage
58
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View Lastest Price from 2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE manufacturers

Jiangsu Liyang Kunlun Biological Technology Co., Ltd.
Product
2-Chloro-4-methyl-6-methylsulfanyl-pyrimidine 89466-59-1
Price
US $0.00/kg
Min. Order
1000kg
Purity
0.99
Supply Ability
20 tons
Release date
2025-03-18
Nanjing Fred Technology Co., Ltd
Product
2-Chloro-4-methyl-6-methylsulfanyl-pyrimidine 89466-59-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1 ton
Release date
2024-01-02
Dideu Industries Group Limited
Product
2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE 89466-59-1
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons Min
Release date
2021-12-14

89466-59-1, 2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINERelated Search:

2-Chloropyrazine 4-CHLORO-6-METHYL-2-METHYLSULFANYL-PYRIMIDINE-5-CARBOXYLIC ACID ETHYL ESTER 4-CHLORO-6-METHYL-2-METHYLSULFANYL-PYRIMIDINE 4-CHLORO-5-METHYL-2-METHYLSULFANYL-PYRIMIDINE 2-CHLORO-4-METHYLSULFANYL-PYRIMIDINE 2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE

  • 2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE
  • 2-chloro-4-Methylthio-6-methylpyrimidine
  • 2-Chloro-4-methylsulfanyl-6-methylpyrimidine
  • PyriMidine,2-chloro-4-Methyl-6-(Methylthio)-
  • 2-Chloro-4-Methyl-6-(Methylthio)pyriMidine
  • 2-CHLORO-4-METHYL-6-METHYLSULFANYL-PYRIMIDINE ISO 9001：2015 REACH
  • 89466-59-1
  • C6H7N2ClS