3-(3-AMINOPHENOXY)ANILINE
- Product Name
- 3-(3-AMINOPHENOXY)ANILINE
- CAS No.
- 15268-07-2
- Chemical Name
- 3-(3-AMINOPHENOXY)ANILINE
- Synonyms
- 3,3'-Oxydianiline;3,3-Oxybisbenzolamine;Bis(3-aminophenyl) Ether;BenzenaMine, 3,3'-oxybis-;3-(3-AMINOPHENOXY)ANILINE;3,3'-Diaminodiphenyl ether;3,3- DIAMINODIPHENYL ETHER(33ODA)
- CBNumber
- CB11010207
- Molecular Formula
- C12H12N2O
- Formula Weight
- 200.24
- MOL File
- 15268-07-2.mol
3-(3-AMINOPHENOXY)ANILINE Property
- Melting point:
- 37 °C(Solv: benzene (71-43-2); ligroine (8032-32-4))
- Boiling point:
- 315 °C
- Density
- 1.216±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Acetonitrile (Slightly), Chloroform(Slightly)
- form
- Solid
- pka
- 4.37±0.10(Predicted)
- color
- Light Brown
- InChI
- InChI=1S/C12H12N2O/c13-9-3-1-5-11(7-9)15-12-6-2-4-10(14)8-12/h1-8H,13-14H2
- InChIKey
- LXJLFVRAWOOQDR-UHFFFAOYSA-N
- SMILES
- O(C1C=CC=C(N)C=1)C1C=CC=C(N)C=1
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- O0568
- Product name
- 3,3'-Oxydianiline
- Purity
- min. 98.0 %
- Packaging
- 1G
- Price
- $266
- Updated
- 2025/07/31
- Product number
- O870685
- Product name
- 3,3''-Oxydianiline
- Packaging
- 250mg
- Price
- $195
- Updated
- 2021/12/16
- Product number
- O870685
- Product name
- 3,3''-Oxydianiline
- Packaging
- 1g
- Price
- $540
- Updated
- 2021/12/16
- Product number
- FD36723
- Product name
- 3,3'-Diamino diphenyl ether
- Packaging
- 50mg
- Price
- $100
- Updated
- 2021/12/16
- Product number
- FD36723
- Product name
- 3,3'-Diamino diphenyl ether
- Packaging
- 100mg
- Price
- $160
- Updated
- 2021/12/16
3-(3-AMINOPHENOXY)ANILINE Chemical Properties,Usage,Production
Uses
3,3''-Oxydianiline was used as a reactant in the synthesis of a deep blue electrophosphorescent Pt(II) emitter.
Synthesis
626-01-7
591-27-5
15268-07-2
The general procedure for the synthesis of 3,3'-oxydiphenylamine from 3-iodoaniline and 3-aminophenol was as follows: 3-aminophenol (6.0 g, 54.8 mmol), 3-iodoaniline (10.0 g, 45.7 mmol), pyridine carboxylic acid (0.56 g, 4.6 mmol), cuprous iodide (I) and potassium phosphate (19.4 g, 91 mmol). DMSO (100 mL) was added as solvent and the reaction mixture was degassed by blowing in nitrogen for 1 hour. Subsequently, the reaction flask was placed in a preheated 80 °C oil bath and the reaction was stirred for 15 hours. After completion of the reaction, the mixture was cooled to room temperature. The reaction mixture was poured into 150 mL of water and extracted with ethyl acetate (3 x 50 mL). The organic phases were combined and washed sequentially with 50 mL of water and 50 mL of brine, dried and the solvent evaporated. The crude product was purified by silica gel column chromatography, eluting first with 80/20 (v/v) hexane/ethyl acetate solvent mixture and then with 50/50 (v/v) hexane/ethyl acetate solvent mixture to give 7.2 g (79% yield) of 3,3'-oxydiphenylamine as a white solid. The structure of the product was confirmed by GC/MS and NMR.
References
[1] Angewandte Chemie - International Edition, 2013, vol. 52, # 2, p. 650 - 654
[2] Angew. Chem., 2013, vol. 125, # 2, p. 678 - 682,5
[3] Patent: US9461254, 2016, B2. Location in patent: Page/Page column 195-196
[4] Journal of the American Chemical Society, 2009, vol. 131, # 47, p. 17423 - 17429
3-(3-AMINOPHENOXY)ANILINE Preparation Products And Raw materials
Raw materials
Preparation Products
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