ChemicalBook > CAS DataBase List > 4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE

4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE

Product Name
4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE
CAS No.
2450-27-3
Chemical Name
4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE
Synonyms
4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE;3-Methoxy-2-nitro-4-(phenylmethoxy)benzaldehyde;Benzaldehyde, 3-methoxy-2-nitro-4-(phenylmethoxy)-
CBNumber
CB11109761
Molecular Formula
C15H13NO5
Formula Weight
287.27
MOL File
Mol file
More
Less

4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE Property

Melting point:
111.5-112.5 °C
Boiling point:
487.8±45.0 °C(Predicted)
Density 
1.296±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
More
Less

Hazard and Precautionary Statements (GHS)

More
Less

N-Bromosuccinimide Price

Matrix Scientific
Product number
114401
Product name
4-(Benzyloxy)-3-methoxy-2-nitrobenzaldehyde
Purity
97%
Packaging
1g
Price
$764
Updated
2021/12/16
AK Scientific
Product number
5479CC
Product name
4-(Benzyloxy)-3-methoxy-2-nitrobenzaldehyde
Packaging
5g
Price
$1680
Updated
2021/12/16
Alichem
Product number
2450273
Product name
4-(Benzyloxy)-3-methoxy-2-nitrobenzaldehyde
Packaging
1g
Price
$998
Updated
2021/12/16
Ambeed
Product number
A125613
Product name
4-(Benzyloxy)-3-methoxy-2-nitrobenzaldehyde
Purity
97%
Packaging
100mg
Price
$115
Updated
2021/12/16
Atlantic Research Chemicals
Product number
AH001223
Product name
4-(Benzyloxy)-3-methoxy-2-nitrobenaldehyde
Purity
95%
Packaging
250mgs:
Price
$173.19
Updated
2021/12/16
More
Less

4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE Chemical Properties,Usage,Production

Synthesis

2450-26-2

100-39-0

2450-27-3

Step 3: Preparation of 4-(benzyloxy)-3-methoxy-2-nitrobenzaldehyde; 4-hydroxy-3-methoxy-2-nitrobenzaldehyde (155 g, 786 mmol) was dissolved in N,N-dimethylformamide (DMF, 1500 mL), and potassium carbonate (217 g, 1.57 mol) and benzyl bromide (161 g, 0.94 mol). The reaction mixture was stirred at room temperature for 16 h. Most of the DMF was removed by distillation under reduced pressure. the organic layer was separated by partitioning the residue between water (2 L) and ethyl acetate (EtOAc, 2 L). The organic layer was washed with saturated saline (3 x 2 L), dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting solid was ground with ether (Et2O, 1 L) to afford the target compound 4-(benzyloxy)-3-methoxy-2-nitrobenzaldehyde (220 g, 97% yield).1H NMR (DMSO-d6) δ: 9.77 (1H, s), 7.87 (1H, d), 7.58 (1H, d), 7.51 (1H, m), 7.49 (1H, m) , 7.39 (3H, m), 5.36 (2H, s), 3.05 (3H, s).

References

[1] Patent: WO2008/70150, 2008, A1. Location in patent: Page/Page column 66
[2] Tetrahedron, 2009, vol. 65, # 16, p. 3246 - 3260
[3] Patent: WO2012/62748, 2012, A1. Location in patent: Page/Page column 56
[4] Patent: WO2012/62743, 2012, A1. Location in patent: Page/Page column 60
[5] Patent: WO2012/62745, 2012, A1. Location in patent: Page/Page column 61

4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE Suppliers

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19913
Advantage
55
Shanghai potentpharm CO.,Ltd
Tel
13524892556
Fax
(86) 21 51969655, QQ: 263541193
Email
sales-cn@potentpharm.com
Country
China
ProdList
1011
Advantage
55
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Cool Pharm, Ltd
Tel
021-60455363 18019463053
Fax
50966098
Email
sales@coolpharm.com
Country
China
ProdList
12346
Advantage
58
Shanghai YuanQi Biotechnology Co., Ltd.
Tel
+86-2332782371 +86-18120098618
Email
sales@adobechem.com
Country
China
ProdList
1250
Advantage
50
SuZhou ShiYa Biopharmaceuticals, Inc.
Tel
0512-0512-52358471 17715136450
Fax
05125235 6881
Email
sales@shiyabiopharm.com
Country
China
ProdList
12127
Advantage
58
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Adobe Chem Co., Ltd.
Tel
2332782371
Fax
QQ: 2332782371
Email
adobechem@qq.com
Country
China
ProdList
7980
Advantage
58
Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
4009004166/18616739031 18616739031
Email
3007523370@qq.com
Country
China
ProdList
52687
Advantage
58
Shanghai Kaiwei Chemical Technology Co., Ltd.
Tel
021-58461859 15821823057
Email
service@aiviche.com
Country
China
ProdList
49312
Advantage
58
Energy Chemical
Tel
021-58432009 400-005-6266
Fax
021-58436166
Email
marketing1@energy-chemical.com
Country
China
ProdList
44894
Advantage
58
cjbscvictory
Tel
13348960310
Email
3003867561@qq.com
Country
China
ProdList
10503
Advantage
58
Hubei Co-prosperity Medicine Technonlogy Co., Ltd
Tel
2383948258 19172820304
Email
2383948258@qq.com
Country
China
ProdList
12987
Advantage
58
Beijing Jin Ming Biotechnology Co., Ltd.
Tel
010-60605840 15801484223;
Email
psaitong@jm-bio.com
Country
China
ProdList
29757
Advantage
58
Bide Pharmatech Ltd.
Tel
400-6005915
Email
sales@picasso-e.com
Country
China
ProdList
39653
Advantage
58
Shanghai Maclean Biochemical Technology Co., LTD
Tel
021-021-50706066 15221275939
Email
shenlinxing@macklin.cn
Country
China
ProdList
29784
Advantage
58
Shanghai Haohong Scientific Co., Ltd.
Tel
400-8210725 4008210725
Email
malulu@leyan.com
Country
China
ProdList
40000
Advantage
58
Yantai Shengkailun Chemical Technology Co., Ltd.
Tel
13356901049
Email
mark@sklnchem.cn
Country
China
ProdList
9995
Advantage
58
Shanghai Zunlijia Life Technology Co., Ltd
Tel
021-34045219 13062664914
Email
huji@zunlijia.com
Country
China
ProdList
10027
Advantage
58
Tianjin Xinkangyou Biotechnology Co., LTD
Tel
19922659386
Email
niuli@tjxkys.cn
Country
China
ProdList
2995
Advantage
58
Jilin Chinese Academy of Sciences-yanshen Technology
Tel
+undefined18143011203
Email
info@chemextension.com
Country
China
ProdList
42056
Advantage
58
Nanjing Fred Technology Co., Ltd
Tel
+86-25-84696168 +86-15380713688
Email
Austin@fredbio.com
Country
China
ProdList
2428
Advantage
58
Beijing Luyuan Bird Biotechnology Co., Ltd.
Tel
--
Fax
--
Email
15810802415@139.com
Country
CHINA
ProdList
6750
Advantage
58
Shanghai Hao Zhun Biological Technology Co., Ltd.
Tel
--
Fax
--
Email
info@zzsrm.com
Country
CHINA
ProdList
6650
Advantage
58
Shanghai Qiming Biological Technology Co., Ltd.
Tel
--
Fax
--
Country
CHINA
ProdList
6502
Advantage
58
Xiamen Research Biotechnology Co., Ltd.
Tel
--
Fax
--
Email
1562893815@qq.com
Country
CHINA
ProdList
6936
Advantage
58
Shanghai Hao Biological Technology Co., Ltd.
Tel
--
Fax
--
Email
shxiyuanbio@163.com
Country
CHINA
ProdList
6906
Advantage
58
Xiamen Huijia Biological Technology Co., Ltd.
Tel
--
Fax
--
Country
CHINA
ProdList
6973
Advantage
58
Shanghai Caiyou Industrial Co., Ltd.
Tel
--
Fax
--
Email
15821073967@163.com
Country
CHINA
ProdList
6748
Advantage
58

2450-27-3, 4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDERelated Search:


  • 4-BENZYLOXY-3-METHOXY-2-NITROBENZALDEHYDE
  • Benzaldehyde, 3-methoxy-2-nitro-4-(phenylmethoxy)-
  • 3-Methoxy-2-nitro-4-(phenylmethoxy)benzaldehyde
  • 2450-27-3