Bis(2-mercaptoethyl) sulfone
- Product Name
- Bis(2-mercaptoethyl) sulfone
- CAS No.
- 145626-87-5
- Chemical Name
- Bis(2-mercaptoethyl) sulfone
- Synonyms
- Bis(2-thioethyl) sulphone;2,2'-Sulfonylbis-ethanethiol;Ethanethiol, 2,2'-sulfonylbis-;Bis(2-mercaptoethyl) sulphone, 2,2'-Sulphonyldiethanethiol
- CBNumber
- CB11176170
- Molecular Formula
- C4H10O2S3
- Formula Weight
- 186.32
- MOL File
- 145626-87-5.mol
Bis(2-mercaptoethyl) sulfone Property
- Melting point:
- 57-58°C
- Boiling point:
- 375.6±27.0 °C(Predicted)
- Density
- 1.296±0.06 g/cm3(Predicted)
- storage temp.
- -20°C Freezer, Under Inert Atmosphere
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- solid
- pka
- pKa (aqueous soln at 25°): 7.9, 9.0
- color
- Pale yellow
- Stability:
- Moisture Sensitive
- CAS DataBase Reference
- 145626-87-5
Safety
- HS Code
- 2930909899
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- B482500
- Product name
- Bis(2-mercaptoethyl)sulfone
- Packaging
- 1g
- Price
- $310
- Updated
- 2021/12/16
- Product number
- 1514CH
- Product name
- Bis(2-mercaptoethyl)sulfone
- Packaging
- 500mg
- Price
- $441
- Updated
- 2021/12/16
- Product number
- FB18676
- Product name
- Bis(2-mercaptoethyl)sulfone
- Packaging
- 1g
- Price
- $460
- Updated
- 2021/12/16
- Product number
- 7507
- Product name
- Bis(2-mercaptoethyl)sulfone
- Packaging
- 1g
- Price
- $830
- Updated
- 2021/12/16
- Product number
- 7507
- Product name
- Bis(2-mercaptoethyl)sulfone
- Packaging
- 5G
- Price
- $1640
- Updated
- 2021/12/16
Bis(2-mercaptoethyl) sulfone Chemical Properties,Usage,Production
Chemical Properties
White Crystalline Solid
Uses
Bis(2-mercaptoethyl) sulfone is a useful reagent for the reduction of disulfides in aquous solutions. It is a superior substitute for DTT.
Uses
Reagent for reduction of disulfide bonds in aqueous solutions.
Purification Methods
BMS recrystallises from hexane as white fluffy crystals. Large amounts are best recrystallised from de-oxygenated H2O (charcoal). It is a good alternative reducing agent to dithiothreitol. Its IR (film) has 2995, 2657, 1306, 1248, 1124 and 729 cm-1 . The synthetic intermediate thioacetate has m 82-83o (white crystals from CCl4). The disulfide is purified by flash chromatography on SiO2 and elution with 50% EtOAc/hexane and recrystallised from hexane, and has m 137-139o. [Lamoureux & Whitesides J Org Chem 58 633 1993, Beilstein 1 IV 2455.]
Bis(2-mercaptoethyl) sulfone Preparation Products And Raw materials
Raw materials
Preparation Products
Bis(2-mercaptoethyl) sulfone Suppliers
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