(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

Product Name: (R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
CAS No.: 256390-47-3
Chemical Name: (R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Synonyms: SL-A104-1;(R)-3,4,5-MeO-MeOBIPHEP;-diyl)bis[bis(3，4，5-trimethoxyphenyl)phosphine;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine;(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine];(R)-2,2'-Bis[bis(3,4,5-trimethoxyphenyl)phosphino]-6,6'- dimethoxy-1,1'-biphenyl;(R)-(+)-2,2'-Bis[di(3,4,5-tnimethoxyphenylphosphin0]-6,6'-dimethoxy-1.1'-bip henyl;(R)-(+)-2,2'-Bis[di-(3,4,5-trimethoxyphenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(R)-(+)-2,2''-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6''-dimethoxy-1,1''-biphenyl;(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min
CBNumber: CB11180979
Molecular Formula: C50H56O14P2
Formula Weight: 942.92
MOL File: 256390-47-3.mol

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(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Property

Boiling point:: 883.4±65.0 °C(Predicted)
form: Powder
color: off-white
Sensitive: air sensitive, store cold
CAS DataBase Reference: 256390-47-3

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Safety

WGK Germany: 3
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 15-0158
Product name: (R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging: 100mg
Price: $74
Updated: 2021/12/16

Strem Chemicals

Product number: 15-0158
Product name: (R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging: 500mg
Price: $278
Updated: 2021/12/16

Sigma-Aldrich

Product number: 29526
Product name: (R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine]
Packaging: 500mg
Price: $315
Updated: 2022/05/15

Strem Chemicals

Product number: 15-0158
Product name: (R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging: 2g
Price: $946
Updated: 2021/12/16

Strem Chemicals

Product number: 15-0158
Product name: (R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging: 10g
Price: $3784
Updated: 2021/12/16

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(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Usage,Production

Chemical Properties

Light yellow powder

Uses

Atropisomeric MeOBIPHEP ligands

Reactions

In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
1. Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
2. Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
3. Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
4. Conjugate addition using 2-heteroaryl titanates and zinc reagents.

General Description

sold in collaboration with Solvias AG

(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers

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256390-47-3, (R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%Related Search:

n-Butyllithium Potassium pyrophosphate

(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(R)-(+)-2,2''-BIS[DI(3,4,5-TRIMETHOXYPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%

(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine]

(R)-3,4,5-MeO-MeOBIPHEP, SL-A104-1, (R)-2,2μ-Bis[bis(3,4,5-trimethoxyphenyl)phosphino]-6,6μ-dimethoxy-1,1μ-biphenyl

(R)-3,4,5-MeO-MeOBIPHEP

SL-A104-1

(R)-(+)-2,2'-Bis[di-(3,4,5-trimethoxyphenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl

(R)-(6,6'-DiMethoxybiphenyl-2,2'-diyl)bis[bis(3,4,5-triMethoxyphenyl)phosphine] >=97%, optical purity ee: >=99%

1,1'-[(1R)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(3,4,5-trimethoxyphenyl)phosphine]

Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(3,4,5-trimethoxyphenyl)-

(R)-2,2'-Bis[bis(3,4,5-trimethoxyphenyl)phosphino]-6,6'- dimethoxy-1,1'-biphenyl

-diyl)bis[bis(3，4，5-trimethoxyphenyl)phosphine

(R)-(+)-2,2''-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6''-dimethoxy-1,1''-biphenyl

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine

Phosphine，1，1'-[(1R)-6，6'-dimethoxy[1，1'-biphenyl]-2，2'-diyl]bis[1，1-bis(3，4，5-trimethoxyphenyl)-

(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min

(R)-(+)-2,2'-Bis[di(3,4,5-tnimethoxyphenylphosphin0]-6,6'-dimethoxy-1.1'-bip henyl

1,1'-[(1R)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(3,4,5-trimethoxyphenyl)phosphine

(<i>R</i>)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine]

256390-47-3

Chiral Phosphine

MeOBIPHEP Series