ChemicalBook > CAS DataBase List > CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID

CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID

Product Name
CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID
CAS No.
54162-90-2
Chemical Name
CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID
Synonyms
6-Aminocyclohex-3-ene-COOH(S,R);CIS-6-AMINO-CYCLOHEX-3-ENECARBOXYLIC ACID;CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID;(1S,6R)-6-aminocyclohex-3-ene-1-carboxylic acid;cis-2-Amino-4-cyclohexene-1-carboxylic acid, 98+%;CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID USP/EP/BP;3-Cyclohexene-1-carboxylic acid, 6-amino-, (1R,6S)-rel-;3-Cyclohexene-1-carboxylicacid,6-amino-,(1R,6S)-rel-(9CI)
CBNumber
CB1118984
Molecular Formula
C7H11NO2
Formula Weight
141.17
MOL File
54162-90-2.mol
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CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID Property

Melting point:
196-199 °C
Boiling point:
258.21°C (rough estimate)
Density 
1.1522 (rough estimate)
refractive index 
1.5026 (estimate)
CAS DataBase Reference
54162-90-2
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Safety

Hazard Codes 
Xn
Risk Statements 
36/37/38-20/21/22-43
Safety Statements 
36/37/39-26-36/37
HS Code 
2922498590
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
A605468
Product name
cis-6-Amino-cyclohex-3-enecarboxylicacid
Packaging
250mg
Price
$240
Updated
2021/12/16
SynQuest Laboratories
Product number
4457-1-00
Product name
cis-6-Aminocyclohex-3-enecarboxylic acid
Packaging
1g
Price
$496
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0014138
Product name
CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID
Purity
95.00%
Packaging
500MG
Price
$691.27
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0014138
Product name
CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID
Purity
95.00%
Packaging
1G
Price
$848.93
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0014138
Product name
CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID
Purity
95.00%
Packaging
5G
Price
$1661.47
Updated
2021/12/16
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CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID Chemical Properties,Usage,Production

Chemical Properties

BEIGE FINE POWDER

Purification Methods

Purify the free amino-acid by dissolving it in H2O and passing it through a Dowex 50W (acid form) column and eluting with 1M aqueous NH4OH. The eluate is evaporated (in vacuo) and the residue is dissolved in H2O. Me2CO is added to turbidity, cooled at 0o and the colourless crystals of the amino-acid are collected and dried in vacuo [Bernáth et al. Tetrahedron 41 1315 1958, cf Mazza & Crapetta Gazzetta 57 297 1927]. In earlier work, it was recrystallised from aqueous EtOH and had reported melting points of 265-265o [Kricheldorf Justus Liebigs Ann Chem 1378 1975] and 269-271o [Marconi & Mazzochi J Org Chem 31 1372 1966]. The hydrochloride [57266-56-5] M 177.6 has m 210-213o and the methyl ester hydrochloride [52766-61-2] has m 85-87o (from Et2O). The trans-(±)-(1RS,2RS)-amino-acid [97945-19-2] crystallises from aqueous Me2CO with m 267-269o. [Beilstein 14 II 203.]

CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID Suppliers

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