4-(4-Bromothiazol-2-yl)morpholine

Product Name: 4-(4-Bromothiazol-2-yl)morpholine
CAS No.: 1017781-60-0
Chemical Name: 4-(4-Bromothiazol-2-yl)morpholine
Synonyms: 4-BROMO-2-MORPHOLINOTHIAZOLE;4-(4-Bromo-2-thiazolyl)morpholine;4-(4-Bromothiazol-2-yl)morpholine;Morpholine, 4-(4-bromo-2-thiazolyl)-;4-Bromo-2-(morpholin-4-yl)-1,3-thiazole;4-(4-Bromo-1,3-thiazol-2-yl)morpholine 97%;4-(4-Bromo-1,3-thiazol-2-yl)morpholine, 97%
CBNumber: CB11503194
Molecular Formula: C7H9BrN2OS
Formula Weight: 249.13
MOL File: 1017781-60-0.mol

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4-(4-Bromothiazol-2-yl)morpholine Property

Boiling point:: 348.6±52.0 °C(Predicted)
Density: 1.642±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: 2.31±0.50(Predicted)
Appearance: Off-white to light yellow Solid

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Safety

Hazard Codes: T
Risk Statements: 25
Safety Statements: 45
HS Code: 2934100090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B688413
Product name: 4-(4-Bromothiazol-2-yl)morpholine
Packaging: 100mg
Price: $45
Updated: 2021/12/16

TRC

Product number: B688413
Product name: 4-(4-Bromothiazol-2-yl)morpholine
Packaging: 500mg
Price: $95
Updated: 2021/12/16

TRC

Product number: B688413
Product name: 4-(4-Bromothiazol-2-yl)morpholine
Packaging: 1g
Price: $130
Updated: 2021/12/16

Ark Pharm

Product number: P000102515
Product name: 4-(4-Bromothiazol-2-yl)morpholine
Purity: 98%
Packaging: 250mg
Price: $24
Updated: 2021/12/16

Apolloscientific

Product number: OR16542
Product name: 4-(4-Bromo-1,3-thiazol-2-yl)morpholine
Purity: 97%
Packaging: 250mg
Price: $30
Updated: 2021/12/16

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4-(4-Bromothiazol-2-yl)morpholine Chemical Properties,Usage,Production

Synthesis

110-91-8

4175-77-3

1017781-60-0

Example 89: A reaction was carried out with 2,4-dibromothiazole (500 mg, 2.06 mmol) and morpholine (4.0 mL, 22.3 mmol) in a sealed tube at 50°C for 16 hours. Upon completion of the reaction, the mixture was cooled to room temperature, diluted with 20 mL of water and extracted with three 30 mL portions of diethyl ether. The organic layers were combined, washed sequentially with five parts of 30 mL of water, 30 mL of brine, dried over magnesium sulfate, filtered and concentrated in vacuum. The residue was purified by silica gel column chromatography using ethyl acetate in hexane (0-30% gradient) as eluent to give 458 mg (89% yield) of the target product 4-(4-bromothiazol-2-yl)morpholine.

References

[1] Patent: WO2008/70507, 2008, A2. Location in patent: Page/Page column 179
[2] Patent: WO2016/206101, 2016, A1. Location in patent: Page/Page column 91; 92
[3] Chemical Biology and Drug Design, 2018, vol. 91, # 1, p. 172 - 180

4-(4-Bromothiazol-2-yl)morpholine Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(4-Bromothiazol-2-yl)morpholine Suppliers

China 54 India 1 Switzerland 1 Ukraine 1 United Kingdom 2 United States 9 Global 68

J & K SCIENTIFIC LTD.

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View Lastest Price from 4-(4-Bromothiazol-2-yl)morpholine manufacturers

Career Henan Chemica Co

Product: 4-(4-Bromothiazol-2-yl)morpholine 1017781-60-0
Price: US $17.00/g
Min. Order: 1g
Purity: 95%
Supply Ability: 1KG
Release date: 2020-10-28

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1017781-60-0

C7H9BrN2OS