ChemicalBook > CAS DataBase List > 4-(ETHOXYCARBONYL)PHENYLZINC IODIDE

4-(ETHOXYCARBONYL)PHENYLZINC IODIDE

Product Name
4-(ETHOXYCARBONYL)PHENYLZINC IODIDE
CAS No.
131379-16-3
Chemical Name
4-(ETHOXYCARBONYL)PHENYLZINC IODIDE
Synonyms
Ethyl 4-(iodozincio)benzoate;4-(ETHOXYCARBONYL)PHENYLZINC IODIDE;4-(Iodozincio)benzoic acid ethyl ester;(4-(Ethoxycarbonyl)phenyl)zinc(II) iodide;4-(ethoxycarbonyl)phenylzinc iodide solution;4-(Ethoxycarbonyl)phenylzinc iodide solution 0.5 in THF;4-(Ethoxycarbonyl)phenylzinc iodide solution 0.5M in THF;4-(ETHOXYCARBONYL)PHENYLZINC IODIDE, 0.5 M SOLUTION IN TETRAHYDROFURAN;4-(Ethoxycarbonyl)phenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles;4-(Ethoxycarbonyl)butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal&trade
CBNumber
CB1157590
Molecular Formula
C9H9IO2Zn
Formula Weight
341.46
MOL File
131379-16-3.mol
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4-(ETHOXYCARBONYL)PHENYLZINC IODIDE Property

Density 
1.018 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
2-8°C
Water Solubility 
Reacts with water.
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
CAS DataBase Reference
131379-16-3
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Safety

Hazard Codes 
F,Xn
Risk Statements 
14-19-22-36/38-40-36/37-11
Safety Statements 
16-26-33-36-36/37
RIDADR 
UN 2056 3/PG 2
WGK Germany 
1
HazardClass 
4.3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H319Causes serious eye irritation

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
498475
Product name
4-(Ethoxycarbonyl)phenylzinc iodide solution
Purity
0.5M in THF
Packaging
50ml
Price
$304
Updated
2023/06/20
Alfa Aesar
Product number
H58484
Product name
4-(Ethoxycarbonyl)phenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
Packaging
50ml
Price
$408
Updated
2024/03/01
Rieke Metals
Product number
2016
Product name
4-Ethoxycarbonylphenylzinciodide
Packaging
100mL
Price
$503
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0005709
Product name
4-(ETHOXYCARBONYL)PHENYLZINC IODIDE
Purity
95.00%
Packaging
100ML
Price
$2841.3
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0005709
Product name
4-(ETHOXYCARBONYL)PHENYLZINC IODIDE
Purity
95.00%
Packaging
500ML
Price
$5428.5
Updated
2021/12/16
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4-(ETHOXYCARBONYL)PHENYLZINC IODIDE Chemical Properties,Usage,Production

Uses

4-(Ethoxycarbonyl)phenylzinc iodide is used as pharmaceutical intermediates.

Uses

4-(Ethoxycarbonyl)phenylzinc iodide can be used as:

  • A substrate in the transition metal-catalyzed cross-coupling reactions with unsaturated thioethers and thiomethyl-substituted N-heterocycles.
  • A starting material in the synthesis of indazole derived glucagon receptor antagonists.
  • A substrate in the Pd-catalyzed synthesis of 5-aryl-2-furaldehydes by reacting with 5-bromo-2-furaldehyde.

4-(ETHOXYCARBONYL)PHENYLZINC IODIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(ETHOXYCARBONYL)PHENYLZINC IODIDE Suppliers

J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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86-10-82849933
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jkinfo@jkchemical.com
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China
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Beijing Ouhe Technology Co., Ltd
Tel
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Fax
+86-10-82967029
Email
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Tel
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Sigma-Aldrich
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131379-16-3, 4-(ETHOXYCARBONYL)PHENYLZINC IODIDERelated Search:


  • 4-(ETHOXYCARBONYL)PHENYLZINC IODIDE
  • 4-(ETHOXYCARBONYL)PHENYLZINC IODIDE, 0.5 M SOLUTION IN TETRAHYDROFURAN
  • 4-(ethoxycarbonyl)phenylzinc iodide solution
  • 4-(Iodozincio)benzoic acid ethyl ester
  • Ethyl 4-(iodozincio)benzoate
  • 4-(Ethoxycarbonyl)phenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles
  • 4-(Ethoxycarbonyl)phenylzinc iodide solution 0.5M in THF
  • 4-(Ethoxycarbonyl)phenylzinc iodide solution 0.5 in THF
  • 4-(Ethoxycarbonyl)butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal&trade
  • (4-(Ethoxycarbonyl)phenyl)zinc(II) iodide
  • 131379-16-3
  • C2H5O2CC6H4ZnI
  • Aryl
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  • Aryl
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