TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)

Product Name: TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)
CAS No.: 76262-87-8
Chemical Name: TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)
Synonyms: Titanocene ditriflate;TITANOCENE BIS(TRIFLUOROMETHANESULFONATE);Bis(cyclopentadienyl)di(triflato)titanium;TITANOCENE BIS(TRIFLUOROMETHANESULPHONATE);Bis(cyclopentadienyl)bis(trifluoromethanesulfonato)titanium;Bis(trifluoromethanesulfonate)dicyclopentadienyltitanium(IV);BIS(CYCLOPENTADIENYL)TITANIUM BIS(TRIFLUOROMETHANESULFONATE);di(cyclopentadienyl)titanium(iv) bis(trifluoromethanesulfonate);BIS(CYCLOPENTADIENYL)TITANIUM(IV) BIS(TRIFLUOROMETHANESULFONATE);Titanocene bis(trifluoromethanesulfonate), Di(cyclopentadienyl)titanium(IV) bis(trifluoromethanesulfonate)
CBNumber: CB1163434
Molecular Formula: C12F6O6S2Ti
Formula Weight: 466.1
MOL File: 76262-87-8.mol

More

Less

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Property

solubility: sol CH2Cl2, MeNO2; insol benzene, hexane.
form: powder to crystal
color: Orange to Amber to Dark red
CAS DataBase Reference: 76262-87-8

More

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
F: 10-23
HS Code: 2931.90.6000

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 416681
Product name: Bis(cyclopentadienyl)titanium(IV) bis(trifluoromethanesulfonate)
Purity: 98%
Packaging: 1g
Price: $240
Updated: 2023/06/20

TCI Chemical

Product number: T1658
Product name: Titanocene Bis(trifluoromethanesulfonate)
Purity: >97.0%(T)
Packaging: 100mg
Price: $78
Updated: 2024/03/01

TCI Chemical

Product number: T1658
Product name: Titanocene Bis(trifluoromethanesulfonate)
Purity: >97.0%(T)
Packaging: 1g
Price: $268
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: OGM0000704
Product name: BIS(CYCLOPENTADIENYL)TITANIUM(IV) BIS(TRIFLUOROMETHANESULFONATE)
Purity: 95.00%
Packaging: 100MG
Price: $286.23
Updated: 2021/12/16

AK Scientific

Product number: 9164AL
Product name: Titanocene Bis(trifluoromethanesulfonate)
Packaging: 1g
Price: $373
Updated: 2021/12/16

More

Less

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Chemical Properties,Usage,Production

Uses

Catalyst for:

Transesterification
Stereoselective carbonyl-ene cyclization reactions
Sakurai reactions
Mukaiyama cross-aldol reactions

Reactant for synthesis of heterobimetallic bridging dinitrogen complexes

Application

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) is used as a catalyst for Diels-Alder reaction, Mukaiyama crossed-aldol reaction, and Sakurai reaction.

Preparation

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) is prepared by treatment of a 0.06 M THF solution of Dichlorobis(cyclopentadienyl)titanium with 5.5 equiv of a 0.19 M THF solution of Silver(I) Trifluoromethanesulfonate. After stirring for 15 min the reaction mixture is filtered, the red filtrate is layered with hexane, and the resulting red crystals are collected. Recrystallization from CH2Cl2/pentane or THF/hexane affords Cp2Ti(OSO2CF3)2 (25-30%) as red needles.

storage

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) [Cp2Ti(OSO2CF3)2] and Cp2Zr(OSO2CF3)2 can be handled for short periods of time in air, but are best handled and stored in a glove box. Both can be prepared in situ. The pentamethylcyclopentadienyl analog Cp*2Ti(OH2)2²⁺ is air and water stable. Titanium(IV) is reputed to be of low toxicity.

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE) Suppliers

China 32 Germany 2 India 1 Japan 1 Switzerland 1 United Kingdom 3 United States 6 Global 46

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44689
Advantage: 61

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
Advantage: 64

Shandong Xiya Chemical Co., Ltd

Tel: 4009903999 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18738
Advantage: 57

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22514
Advantage: 55

Suzhou yacoo science co.,Ltd

Tel: 0512-87182056 18013166090
Fax: 0512-87182056
Email: lingling.qi@yacoo.com.cn
Country: China
ProdList: 7295
Advantage: 60

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51456
Advantage: 80

76262-87-8, TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)Related Search:

FLUOROSULFONIC ACID titanocene TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)

TITANOCENE BIS(TRIFLUOROMETHANESULFONATE)

BIS(CYCLOPENTADIENYL)TITANIUM(IV) BIS(TRIFLUOROMETHANESULFONATE)

BIS(CYCLOPENTADIENYL)TITANIUM BIS(TRIFLUOROMETHANESULFONATE)

TITANOCENE BIS(TRIFLUOROMETHANESULPHONATE)

di(cyclopentadienyl)titanium(iv) bis(trifluoromethanesulfonate)

Bis(cyclopentadienyl)bis(trifluoromethanesulfonato)titanium

Bis(cyclopentadienyl)di(triflato)titanium

Bis(trifluoromethanesulfonate)dicyclopentadienyltitanium(IV)

Titanocene ditriflate

Titanocene bis(trifluoromethanesulfonate), Di(cyclopentadienyl)titanium(IV) bis(trifluoromethanesulfonate)

76262-87-8

C12H10F6O6S2Ti

Titanium

Catalysis and Inorganic Chemistry

Titanocene, etc.

Metallocenes

Classes of Metal Compounds

Transition Metal Compounds

Ti (Titanium) Compounds

Classes of Metal Compounds

Metallocenes

Ti (Titanium) Compounds

Titanocene, etc.

Transition Metal Compounds