ChemicalBook > CAS DataBase List > 2-(bromomethyl)-4-phenylthiazole

2-(bromomethyl)-4-phenylthiazole

Product Name
2-(bromomethyl)-4-phenylthiazole
CAS No.
78502-79-1
Chemical Name
2-(bromomethyl)-4-phenylthiazole
Synonyms
2-(bromomethyl)-4-phenylthiazole;Thiazole, 2-(broMoMethyl)-4-phenyl-;2-(BroMoMethyl)-4-phenyl-1,3-thiazole;2-Bromomethyl-4-phenylthiazole, 97% (H51780)
CBNumber
CB12470231
Molecular Formula
C10H8BrNS
Formula Weight
254.15
MOL File
78502-79-1.mol
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2-(bromomethyl)-4-phenylthiazole Property

storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
CAS DataBase Reference
78502-79-1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Biosynth Carbosynth
Product number
FB144144
Product name
2-(Bromomethyl)-4-phenylthiazole
Packaging
250mg
Price
$90
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB144144
Product name
2-(Bromomethyl)-4-phenylthiazole
Packaging
500mg
Price
$160
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB144144
Product name
2-(Bromomethyl)-4-phenylthiazole
Packaging
1g
Price
$277
Updated
2021/12/16
AK Scientific
Product number
2289AC
Product name
2-(Bromomethyl)-4-phenylthiazole
Packaging
1g
Price
$423
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB144144
Product name
2-(Bromomethyl)-4-phenylthiazole
Packaging
2g
Price
$481
Updated
2021/12/16
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2-(bromomethyl)-4-phenylthiazole Chemical Properties,Usage,Production

Synthesis

65384-99-8

78502-79-1

General procedure for the synthesis of 2-bromomethyl-4-phenylthiazole from 4-phenyl-2-hydroxymethylthiazole: (4-phenylthiazol-2-yl)methanol (Example 4C, 0.530 g, 2.77 mmol) was dissolved in dichloromethane (10 mL) and cooled to 0°C (ice bath). Phosphorus tribromide (0.118 mL, 1.247 mmol) was added dropwise over 2 min, and a thick white gel formed immediately.After 10 min, the ice bath was removed and the reaction mixture was stirred for 4 h at 22°C. Upon completion of the reaction, the reaction was quenched with ice (~10 g) and the mixture was poured into a mixture of ethyl acetate (150 mL) and saturated sodium bicarbonate solution (50 mL). The organic phase was separated, washed with brine, dried over anhydrous magnesium sulfate and subsequently concentrated under vacuum. The solid residue obtained was purified by silica gel column chromatography (2.5 x 6 cm, toluene as eluent) to afford the target product 2-bromomethyl-4-phenylthiazole (0.561 g, 80% yield) as a light yellow oil, which solidified to a light yellow solid in the refrigerator.LC (Method C): retention time 2.062 min.HRMS (ESI) calculated value C10H9BrSNa [M+Na]+ m/z 253.9634, measured value 253.9655. 1H NMR (CDCl3, 400 MHz) δ ppm: 4.81 (s, 2H), 7.34-7.39 (m, 1H), 7.41-7.47 (m, 2H), 7.52 (s, 1H), 7.86-7.92 (m , 2H).

References

[1] Patent: WO2013/163279, 2013, A1. Location in patent: Paragraph 00150
[2] Acta Chemica Scandinavica (1947-1973), 1953, vol. 7, p. 885,887
[3] Journal of the American Chemical Society, 1931, vol. 53, p. 1470,1472
[4] Patent: US2013/289238, 2013, A1. Location in patent: Page/Page column

2-(bromomethyl)-4-phenylthiazole Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-(bromomethyl)-4-phenylthiazole manufacturers

Career Henan Chemical Co
Product
2-(bromomethyl)-4-phenylthiazole 78502-79-1
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2018-08-20

78502-79-1, 2-(bromomethyl)-4-phenylthiazoleRelated Search:

2,2-Dimethylthiazolidine 4-METHYLTHIAZOLE-2-THIOL 2-mercapto-4-methylthiazole

  • 2-(bromomethyl)-4-phenylthiazole
  • 2-Bromomethyl-4-phenylthiazole, 97% (H51780)
  • Thiazole, 2-(broMoMethyl)-4-phenyl-
  • 2-(BroMoMethyl)-4-phenyl-1,3-thiazole
  • 78502-79-1