Matridin-15-one, (5.beta.,7.beta.,11.alpha.)-
- Product Name
- Matridin-15-one, (5.beta.,7.beta.,11.alpha.)-
- CAS No.
- 6783-60-4
- Chemical Name
- Matridin-15-one, (5.beta.,7.beta.,11.alpha.)-
- Synonyms
- Leontine;Aids087429;Isoleontine;Aids-087429;ALLOMATRINE(RG);(-)-Allomatrine;Matrine Impurity 1;Matridin-15-one, (5.beta.,7.beta.,11.alpha.)-;1H,5H,10H-Dipyrido[2,1-F:3',2',1'-ij][1,6]naphthyridin-10-one, dodecahydro-, (7ar,13as,13bs,13cs)-
- CBNumber
- CB12496552
- Molecular Formula
- C15H24N2O
- Formula Weight
- 248.36
- MOL File
- 6783-60-4.mol
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Matridin-15-one, (5.beta.,7.beta.,11.alpha.)- Property
- Melting point:
- 107～108℃
- Boiling point:
- 190-210 °C(Press: 7 Torr)
- Density
- 1.16±0.1 g/cm3(Predicted)
- pka
- 9.47±0.20(Predicted)
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Matridin-15-one, (5.beta.,7.beta.,11.alpha.)- Chemical Properties,Usage,Production
Description
A tetracyclic alkaloid present in Leontice Eversmanii Bge. this base is laevorotatory with [α]D - 7S.2°. It gives crystallines salts, e.g. the perchlorate, m.p. 252°C; methiodide, m.p. 297°C and the picrate as yellow needles, m.p. 177-9°C. The structure has been determined from the NMR and mass spectra. The optically inactive form has been synthesized and has m.p. S5-7° C, giving a crystalline hydrochloride, m.p. 215-7° C.
References
Platonova, Kuzovkov, Massagetov., 1. Gen. Chern. USSR, 23,880 (1953)
Rulko, Proskurnina., ibid, 31, 308 (1961)
Synthesis:
Mandell et ai., 1. A mer. Chern. Soc., 87, 5234 (1965)
Matridin-15-one, (5.beta.,7.beta.,11.alpha.)- Preparation Products And Raw materials
Raw materials
Preparation Products
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Matridin-15-one, (5.beta.,7.beta.,11.alpha.)- Suppliers
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