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4,5-Dibromo-2H-1,2,3-triazole

Product Name
4,5-Dibromo-2H-1,2,3-triazole
CAS No.
22300-52-3
Chemical Name
4,5-Dibromo-2H-1,2,3-triazole
Synonyms
2H-1,2,3-Triazole, 4,5-dibromo-
CBNumber
CB12500709
Molecular Formula
C2HBr2N3
Formula Weight
226.86
MOL File
22300-52-3.mol
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4,5-Dibromo-2H-1,2,3-triazole Property

Boiling point:
347.5±22.0 °C(Predicted)
Density 
2.620
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
5.22±0.70(Predicted)
Appearance
Off-white to light yellow Solid
InChI
InChI=1S/C2HBr2N3/c3-1-2(4)6-7-5-1/h(H,5,6,7)
InChIKey
GUQUYKTWVBJKFL-UHFFFAOYSA-N
SMILES
N1=C(Br)C(Br)=NN1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC
Product number
D426248
Product name
4,5-Dibromo-2H-triazole
Packaging
5g
Price
$220
Updated
2021/12/16
Ark Pharm
Product number
P000087782
Product name
4,5-Dibromo-2H-1,2,3-triazole
Purity
98%
Packaging
250mg
Price
$5
Updated
2021/12/16
Ark Pharm
Product number
P000087782
Product name
4,5-Dibromo-2H-1,2,3-triazole
Purity
98%
Packaging
1g
Price
$9
Updated
2021/12/16
Ark Pharm
Product number
P000087782
Product name
4,5-Dibromo-2H-1,2,3-triazole
Purity
98%
Packaging
5g
Price
$33
Updated
2021/12/16
AK Scientific
Product number
J20520
Product name
4,5-Dibromo-2H-1,2,3-triazole
Packaging
1g
Price
$40
Updated
2021/12/16
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4,5-Dibromo-2H-1,2,3-triazole Chemical Properties,Usage,Production

Uses

4,5-Dibromo-2H-triazole was a useful reagent in discovery of selective small molecular inhibitors of monoacylglycerol acyltransferase 3.

Synthesis

288-36-8

22300-52-3

To a 3000 mL three-necked round-bottomed flask was added 2H-1,2,3-triazole (100 g, 1.45 mol, 1.00 eq.) and water (1000 mL), followed by the slow addition of bromine (Br2, 522 g, 3.27 mol, 2.25 eq.). The reaction mixture was placed in a 50 °C oil bath and the reaction was stirred overnight. Upon completion of the reaction, the reaction was quenched by the slow addition of 1000 mL of aqueous sodium sulfite (Na2SO3). The reaction mixture was separated by filtration and the solid product was collected. The resulting solid was dried in an oven under reduced pressure to give 4,5-dibromo-2H-1,2,3-triazole (313 g, 95% yield) as a white solid.

References

[1] Organic Letters, 2010, vol. 12, # 20, p. 4632 - 4635
[2] Patent: US2017/166584, 2017, A1. Location in patent: Paragraph 0718; 0719
[3] Patent: WO2012/151512, 2012, A2. Location in patent: Page/Page column 151
[4] Patent: WO2015/74064, 2015, A2. Location in patent: Paragraph 0260
[5] Patent: WO2018/111803, 2018, A1. Location in patent: Page/Page column 24

4,5-Dibromo-2H-1,2,3-triazole Preparation Products And Raw materials

Raw materials

Preparation Products

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4,5-Dibromo-2H-1,2,3-triazole Suppliers

Shan Xian Lan Platinum Biotechnology Co., Ltd.
Tel
15854067352
Email
sxqzhg@163.com
Country
China
ProdList
298
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58
Shanghai Hecheng Medical Technology Co., LTD
Tel
13564747822
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QQ774046800
Email
669027880@qq.com
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China
ProdList
996
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58
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44802
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61
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9892
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59
Bide Pharmatech Ltd.
Tel
400-400-164-7117 18317119277
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
40000
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60
Changsha Luxing Bio-Chem Technology Co., Ltd.
Tel
0731-88827538 15873153880
Fax
0731-88827238
Email
luxingbc@126.com
Country
China
ProdList
1998
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Shanghai Macklin Biochemical Co.,Ltd.
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15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
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15872
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Shanghai HuanChuan Industry Co.,Ltd.
Tel
021-61478794
Fax
021-61478794
Email
sales@hcshhai.com
Country
China
ProdList
9793
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50
Shanghai Tombiopharma Chemical Co. Ltd.
Tel
13391076197
Email
tombiopharma@163.com
Country
China
ProdList
4987
Advantage
55
Cool Pharm, Ltd
Tel
021-60455363 18019463053
Fax
50966098
Email
sales@coolpharm.com
Country
China
ProdList
12346
Advantage
58
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View Lastest Price from 4,5-Dibromo-2H-1,2,3-triazole manufacturers

Shenzhen Nexcon Pharmatechs Ltd.
Product
4,5-Dibromo-2H-1,2,3-triazole 22300-52-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
2000
Release date
2025-09-04
Career Henan Chemical Co
Product
4,5-Dibromo-2H-1,2,3-triazole 22300-52-3
Price
US $1.00/KG
Min. Order
1KG
Purity
95%~99%
Supply Ability
1ton
Release date
2019-12-18

22300-52-3, 4,5-Dibromo-2H-1,2,3-triazoleRelated Search:


  • 2H-1,2,3-Triazole, 4,5-dibromo-
  • 22300-52-3