N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos

ChemicalBook > CAS DataBase List > N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos

N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos

Reaction

Product Name: N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos
CAS No.: 1237588-12-3
Chemical Name: N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos
Synonyms: Mor-DalPhos;Di(1-adamantyl)-2-morpholinophenylphosphine;MorDalphos 97%;98% Mor-DalPhos;N-[2-(di-1-adamantyL;2-Morpholinophenyldi(1-adamantyl)phosphine;Bis(adamant-1-yl)(2-morpholinophenyl)phosphine;N-[2-(di-1-adaMantylphosphino)phenyl]Morpholine;4-[2-[Di(1-Adamantyl)phosphino]phenyl]morpholine;bis(1-adamantyl)-(2-morpholin-4-ylphenyl)phosphane
CBNumber: CB12512504
Molecular Formula: C30H42NOP
Formula Weight: 463.63
MOL File: 1237588-12-3.mol

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N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Property

Melting point:: 219-224°C
storage temp.: 2-8°C
form: crystal
pka: 4.75±0.40(Predicted)
color: white to yellow
Sensitive: air sensitive
CAS DataBase Reference: 1237588-12-3

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 751618
Product name: Di(1-adamantyl)-2-morpholinophenylphosphine
Purity: 97%
Packaging: 1g
Price: $344
Updated: 2024/03/01

Sigma-Aldrich

Product number: 751618
Product name: Di(1-adamantyl)-2-morpholinophenylphosphine
Purity: 97%
Packaging: 5g
Price: $1010
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1092
Product name: N-[2-(di-1-adamantylphosphino)phenyl]morpholine, 98% Mor-DalPhos
Packaging: 250mg
Price: $76
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1092
Product name: N-[2-(di-1-adamantylphosphino)phenyl]morpholine, 98% Mor-DalPhos
Packaging: 1g
Price: $232
Updated: 2024/03/01

Sigma-Aldrich

Product number: 751618
Product name: Di(1-adamantyl)-2-morpholinophenylphosphine
Purity: 97%
Packaging: 250mg
Price: $90.6
Updated: 2024/03/01

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N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Chemical Properties,Usage,Production

Reaction

P-N-ligand for use in the Pd-catalyzed cross-coupling of ammonia and hydrazine. Ref. (2) with a diverse range of sterically hindered, unbiased aryl chlorides. Low catalyst loading and mild conditions. Ref (5) with diamines in a chemoselective arylation process. Ref (6) with solvent-free or aqueous conditions.
P-N-ligand for the gold-catalyzed stereoselective hydroamination of internal alkynes with dialkylamines to afford E-amines.
P-N-ligand for use in the Pd-catalyzed for mono-α-arylation of ketones employing aryl chlorides, bromides, iodides, mesylates (Ref. 7) and tosylates.

Uses

Mor-DalPhos is a versatile and efficient green catalytic system for Buchwald-Hartwig cross-coupling reaction of aryl bromides or chlorides with a large set amines, amides, ureas, and carbamates.

Uses

MorDalphos is an electronically rich, sterically hindered P,N-based ancillary ligand developed by the Stradiotto group that can be used in the Buchwald-Hartwig Amination reaction, alkyne hydroamination and monoarylation of compounds such as ammonia, hydrazine, and acetone.

N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.

Product: N-[2-(di-1-adamantylphosphino) phenyl]morpholine 1237588-12-3
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 0.99
Supply Ability: 500kg
Release date: 2021-11-30

Career Henan Chemical Co

Product: N-[2-(di-1-adamantylphosphino) phenyl]morpholine,98% Mor-DalPhos 1237588-12-3
Price: US $9.80/KG
Min. Order: 1g
Purity: ≥99%
Supply Ability: 100kg
Release date: 2020-01-08

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C30H42NOP

Achiral Phosphine

Aryl Phosphine

organophosphine ligand