9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one
- Product Name
- 9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one
- CAS No.
- 81514-40-1
- Chemical Name
- 9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one
- Synonyms
- 9-Benzyl-3-oxa-9-azabicyc...;9-benzyl-3-oxa-9-azabicyclo[3.3.1]nonanone;N-benzyl-7-oxa-9-azabicyclo<3.3.1>nonan-3-one;9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one;3-Oxa-9-azabicyclo[3.3.1]nonan-7-one, 9-(phenylmethyl)-;3H-1,2,4-Triazole-3-thione,4-amino-2,4-dihydro-5-(5-methoxyphenyl)-
- CBNumber
- CB12521166
- Molecular Formula
- C14H17NO2
- Formula Weight
- 231.29
- MOL File
- 81514-40-1.mol
9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one Property
- Boiling point:
- 371.1±42.0 °C(Predicted)
- Density
- 1.170±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C
- pka
- 6.01±0.20(Predicted)
- Appearance
- White to off-white Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- B131215
- Product name
- 9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one
- Packaging
- 100mg
- Price
- $90
- Updated
- 2021/12/16
- Product number
- FB55855
- Product name
- 9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one
- Packaging
- 25mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 4H56-1-024
- Product name
- 9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one
- Packaging
- 250mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FB55855
- Product name
- 9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one
- Packaging
- 50mg
- Price
- $102.5
- Updated
- 2021/12/16
- Product number
- FB55855
- Product name
- 9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one
- Packaging
- 100mg
- Price
- $164
- Updated
- 2021/12/16
9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one Chemical Properties,Usage,Production
Synthesis
1126795-00-3
100-39-0
81514-40-1
A solution of potassium carbonate (2.94 g, 14.16 mmol) in DMF (10 mL) was slowly added dropwise at room temperature to a stirred solution of 3-oxa-9-azabicyclo[3.3.1]nonan-7-one hydrochloride (1.26 g, 7.08 mmol, CAS: 1126795-00-3, purchased from PharmaBlock (Nanjing) R&D Co. 14.16 mmol) in DMF (10 mL) solution at room temperature. Benzyl bromide (1.33 g, 7.78 mmol) was then added. The reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, the mixture was concentrated and the residue was partitioned between water (5 mL) and ethyl acetate (20 mL). The organic layer was separated, dried over anhydrous sodium sulfate, filtered and concentrated. Purification of the residue by column chromatography afforded the target compound 9-benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one (1.38 g, 84.2% yield). The structure of the product was confirmed by 1H NMR (CDCl3, 400 MHz) and LC/MS: 1H NMR (CDCl3, 400 MHz) δ 7.36 (m, 5H), 3.93 (s, 2H), 3.86 (d, J = 11.0 Hz, 2H), 3.73 (d, J = 10.8 Hz, 2H), 3.18 (d, J = 5.6 Hz, 2H), 2.76 (d, J = 5.6 Hz, 2H), 3.18 (d, J = 5.6 Hz, 2H). 2H), 2.76 (dd, J = 15.9, 5.6 Hz, 2H), 2.35 (d, J = 15.6 Hz, 2H); LC/MS: Calculated value 232 (MH+), Experimental value 232 (MH+).
References
[1] Patent: WO2014/184328, 2014, A1. Location in patent: Page/Page column 112
9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one manufacturers
- Product
- 9-Benzyl-3-oxa-9-azabicyclo[3.3.1]nonan-7-one 81514-40-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%-99%
- Supply Ability
- 1kg-100kg
- Release date
- 2020-01-07