2-Methyl-tetrahydro-pyran-4-ol
- Product Name
- 2-Methyl-tetrahydro-pyran-4-ol
- CAS No.
- 89791-47-9
- Chemical Name
- 2-Methyl-tetrahydro-pyran-4-ol
- Synonyms
- 2-methyloxan-4-ol;2-Methyl-tetrahydro-pyran-4-ol;2-Methyltetrahydro-2H-pyran-4-ol;Tetrahydro-2-methyl-2H-pyran-4-ol;4-Hydroxy-2-methyltetrahydropyran;2H-Pyran-4-ol, tetrahydro-2-methyl-
- CBNumber
- CB12546758
- Molecular Formula
- C6H12O2
- Formula Weight
- 116.16
- MOL File
- 89791-47-9.mol
2-Methyl-tetrahydro-pyran-4-ol Property
- Boiling point:
- 210℃
- Density
- 1.014
- Flash point:
- 92℃
- storage temp.
- 2-8°C
- pka
- 14.63±0.40(Predicted)
- Appearance
- colorless liquid
- InChI
- InChI=1S/C6H12O2/c1-5-4-6(7)2-3-8-5/h5-7H,2-4H2,1H3
- InChIKey
- ZHPKAPJNEIKPGV-UHFFFAOYSA-N
- SMILES
- C1(C)OCCC(O)C1
- CAS DataBase Reference
- 89791-47-9
Safety
- RIDADR
- UN1993
- HS Code
- 2932990090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- M338140
- Product name
- 2-Methyl-tetrahydro-pyran-4-ol
- Packaging
- 500mg
- Price
- $90
- Updated
- 2021/12/16
- Product number
- 2H10-1-83
- Product name
- 2-Methyloxan-4-ol
- Purity
- 97.0%
- Packaging
- 250mg
- Price
- $90
- Updated
- 2021/12/16
- Product number
- 124026
- Product name
- 2-Methyltetrahydropyran-4-ol
- Purity
- 97.0%
- Packaging
- 1g
- Price
- $116
- Updated
- 2021/12/16
- Product number
- 2H10-1-83
- Product name
- 2-Methyloxan-4-ol
- Purity
- 97.0%
- Packaging
- 1g
- Price
- $190
- Updated
- 2021/12/16
- Product number
- OR321472
- Product name
- 2-Methyltetrahydro-2H-pyran-4-ol
- Purity
- 95%
- Packaging
- 5g
- Price
- $522
- Updated
- 2021/12/16
2-Methyl-tetrahydro-pyran-4-ol Chemical Properties,Usage,Production
Uses
2-Methyl-tetrahydro-pyran-4-ol is an important building block for synthesizing many kinds of organic matter, such as synthesis 2-methyloxan-4-one.
Synthesis
By the procedure of Ernst Hanschke (Chem. Ber., 1955, 88, 1053-1059), the acetaldehyde (1 equiv) and 3-buten-l-ol (1 equiv) are combined with 20% H2SO4 (10 vol) in a pressure tube. The tube was sealed and the reaction mixture was heated to 80 °C for 3 h. Reaction progress is monitored by TLC. After that, the reaction mixture is allowed to cool to rt, carefully neutralized (pH 8-9) by the coned ammonia, and extracted with EtOAc (3 x 5 vol). The combined organic phases are dried (Na2SO4), filtered, and the filtrate coned in vacuo providing the desired product 2-Methyl-tetrahydro-pyran-4-ol.
2-Methyl-tetrahydro-pyran-4-ol Preparation Products And Raw materials
Raw materials
Preparation Products
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