1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane
- Product Name
- 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane
- CAS No.
- 52667-89-7
- Chemical Name
- 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane
- Synonyms
- 1,4,7-Tritosyl-1,4,7-triazonane;147-Triplebenzenesulfonyl-147-Sanwu;147-Trip-toluene sulfonaki-149-Sanwu;1,4,7-Tritosyl-1,4,7-triazacyclononane;1,4,7-tri-p-Tosyl-1,4,7-triazacyclononane;1,4,7-tris(phenylsulfonyl)-1,4,7-triazonane;1,4,7-Tri(p-tolylsulfonyl)-1,4,7-triazacyclononane;1,4,7-tris(p-tolylsulfonyl)-1,4,7-triazacyclononane;1,4,7-Tris(p-toluenesulfonyl)-1,4,7-triazacyclononane;1,4,7-Tris(4-toluenesulfonyl)-1,4,7-triazacyclononane
- CBNumber
- CB12562963
- Molecular Formula
- C27H33N3O6S3
- Formula Weight
- 591.76
- MOL File
- 52667-89-7.mol
1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane Property
- Melting point:
- 222-224℃
- Boiling point:
- 749.4±70.0 °C(Predicted)
- Density
- 1.334±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- -7.08±0.20(Predicted)
- InChIKey
- BLZOXONTWBENEK-UHFFFAOYSA-N
- SMILES
- N1(S(C2=CC=C(C)C=C2)(=O)=O)CCN(S(C2=CC=C(C)C=C2)(=O)=O)CCN(S(C2=CC=C(C)C=C2)(=O)=O)CC1
N-Bromosuccinimide Price
- Product number
- 7447AB
- Product name
- 1,4,7-Tritosyl-1,4,7-triazonane
- Packaging
- 5g
- Price
- $253
- Updated
- 2021/12/16
- Product number
- CHM0386790
- Product name
- 1,4,7-TRITOSYL-1,4,7-TRIAZONANE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $501.5
- Updated
- 2021/12/16
- Product number
- 090617
- Product name
- 1,4,7-Tritosyl-1,4,7-triazonane
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $1853
- Updated
- 2021/12/16
- Product number
- CM253413
- Product name
- 1,4,7-Tritosyl-1,4,7-triazonane
- Purity
- 95%
- Packaging
- 5g
- Price
- $365
- Updated
- 2021/12/16
- Product number
- CD51000843
- Product name
- 1,4,7-Tritosyl-1,4,7-triazonane
- Purity
- 95+%
- Packaging
- 5g
- Price
- $386
- Updated
- 2021/12/16
1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane Chemical Properties,Usage,Production
Uses
1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane is mainly used in pharmaceutical synthesis and scientific research.
Synthesis
6315-52-2
52601-80-6
52667-89-7
General procedure for the synthesis of 1,4,7-tris-tosyl-1,4,7-triazacyclononane from 1,2-bis(tolyloxy)ethane and N,N′,N′′-tris(p-toluenesulfonyl)diethylidene tris(amine) disodium salt: a solution of bis(p-toluenesulfonyl)ethylene glycol (59.5 g, 0.16 mol) in DMF (300 ml) was added slowly and dropwise over a period of three hours to a solution containing tris (p-toluenesulfonyl) diethylenetriamine disodium salt (98 g, 0.16 mol) solution in DMF (950 ml). The reaction mixture was heated and stirred at 100°C. After completion of the reaction, heating was stopped and distilled water (575 ml) was added to induce precipitation of the product. The immediately formed white precipitate was collected by filtration and dried under vacuum to afford the target macrocyclic compound 1,4,7-tri-tosyl-1,4,7-triazacyclononane (71.8 g, 76% yield). The product was characterized as follows: 1H NMR (200 MHz, CDCl3) δ 7.67 (d, 6H), 7.29 (d, 6H), 3.39 (s, 12H), 2.41 (s, 9H).
References
[1] Patent: US2007/218010, 2007, A1. Location in patent: Page/Page column 14; 19
1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane manufacturers
- Product
- 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane 52667-89-7
- Price
- US $0.00/kg/paper drum
- Min. Order
- 25kg/paper drum
- Purity
- 98%
- Supply Ability
- 20 tons
- Release date
- 2026-01-06
- Product
- 1,4,7-tris[(4-Methylphenyl)sulfonyl]-1,4,7-triazonane 52667-89-7
- Price
- US $0.50/g
- Min. Order
- 1g
- Purity
- 98%min
- Supply Ability
- 10g,100g,1kg
- Release date
- 2020-01-09