2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl

ChemicalBook > CAS DataBase List > 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl

2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl

Reaction

Product Name: 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl
CAS No.: 1262046-34-3
Chemical Name: 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl
Synonyms: Rockphos;Di-tert-butyl(2′,4′,6′-triisopropyl-3-methoxy-6-methyl-[1,1′-biphenyl]-2-yl)phosphine;Rockpahos;RockPhos 97%;Bis(1,1-dimethylethyl)[3-me;2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2',4',6'-triisopro;2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2'-4'-6'-triisopropylbiphenyl;2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2'-4'-6'-triisopropylbiphenyl;2-Di(tert-butyl)phosphino-2′,4′,6′-triisopropyl-3-methoxy-6-methylbiphenyl;Di-tert-butyl(2',4',6'-triisopropyl-3-methoxy-6-methyl-2-biphenylyl)phosphine
CBNumber: CB12642764
Molecular Formula: C31H49OP
Formula Weight: 468.69
MOL File: 1262046-34-3.mol

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2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl Property

Melting point:: 129-130°C
Boiling point:: 526.6±50.0 °C(Predicted)
storage temp.: 15-25°C
form: crystal
color: white
CAS DataBase Reference: 1262046-34-3

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 791016
Product name: 2-Di(tert-butyl)phosphino-2′,4′,6′-triisopropyl-3-methoxy-6-methylbiphenyl
Purity: 97%
Packaging: 500mg
Price: $599
Updated: 2024/03/01

Sigma-Aldrich

Product number: 791016
Product name: 2-Di(tert-butyl)phosphino-2′,4′,6′-triisopropyl-3-methoxy-6-methylbiphenyl
Purity: 97%
Packaging: 2g
Price: $1340
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1168
Product name: 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl, min. 98% RockPhos
Packaging: 100mg
Price: $125
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1168
Product name: 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl, min. 98% RockPhos
Packaging: 500mg
Price: $499
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1168
Product name: 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl, min. 98% RockPhos
Packaging: 2g
Price: $1288
Updated: 2024/03/01

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2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl Chemical Properties,Usage,Production

Reaction

Ligand used in the palladium-catalyzed C-O bond forming reactions of secondary and primary alcohols with a range of aryl halides. Heterocyclic halides and, for the first time, electron-rich aryl halides can be coupled with secondary alcohols.

Uses

Rockpahos is commonly used as a catalyst in organic reactions along with a palladium compound catalyst.

Uses

RockPhos is a biphenyl-based phosphine ligand used with Pd(0) catalyst for carbon-carbon and carbon-heteroatom bond formation reactions.
It can also be employed in the:

2-fluroethoxylation of bromo-chalcones in the presence of palladium catalyst.
Conversion of aryl chlorides into aryl methoxides using RockPhos Pd G3 as a catalyst.

2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl manufacturers

Speranza Chemical Co., Ltd.

Product: 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl 1262046-34-3
Price: US $0.00-0.00/KG
Min. Order: 5KG
Purity: 98%
Supply Ability: 25KG
Release date: 2024-01-05

Shaanxi Dideu Medichem Co. Ltd

Product: 2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2'-4'-6'-triisopropylbiphenyl 1262046-34-3
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 tons
Release date: 2020-01-16

1262046-34-3, 2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenylRelated Search:

2-(Di-t-butylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% t-butylBrettPhos

Rockphos

2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2'-4'-6'-triisopropylbiphenyl, 98% Min

2-(Di-t-butylphosphino)-3-Methoxy-6-Methyl-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, Min. 98% RockPhos

Bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine

2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2',4',6'-triisopropyl-1,1'-biphenyl

Di-tert-butyl(2′,4′,6′-triisopropyl-3-methoxy-6-methyl-[1,1′-biphenyl]-2-yl)phosphine

RockPhos 97%

2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2'-4'-6'-triisopropylbiphenyl

2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl

2-Di(tert-butyl)phosphino-2′,4′,6′-triisopropyl-3-methoxy-6-methylbiphenyl

2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl, RockPhos

Bis(1,1-dimethylethyl)[3-me

2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2',4',6'-triisopro

Di-tert-butyl(2',4',6'-triisopropyl-3-methoxy-6-methyl-[1,1'-biphenyl]-2-yl)phosphane

2-Di-tert-butylphosphino-3- Methoxy-6-Methyl-2,4',6'- triisopropylbiphenyl (Rockphos)

ditert-butyl-[6-methoxy-3-methyl-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane

Phosphine, bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]-

Rockpahos

Di-tert-butyl(2',4',6'-triisopropyl-3-methoxy-6-methyl-2-biphenylyl)phosphine

2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propylbiphenyl (Rockphos)

2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl

Di-tert-butyl(2',4',6'-triisopropyl-3-methoxy-6-methyl-[1,1'-biphenyl]-2-yl)phosphine

ditert-butyl-[6-methoxy-3-methyl-2-(2,4,6-triisopropylphenyl)phenyl]phosphane

Bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine

Di-tert-butyl(2’,4’,6’-triisopropyl-3-methoxy-6-methyl-2-biphenylyl)phosphine

2-Di-tert-butylphosphino-3-Methoxy-6-Methyl-2'-4'-6'-triisopropylbiphenyl

Phosphine, bis(1,1-dimethylethyl)[3-methoxy-6-methyl-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]-

2-(Di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propylbiphenyl (Rockphos)

1262046-34-3

1260246-34-3

C31H49OP

Achiral Phosphine

Aryl Phosphine

Buchwald Ligands Series

Buchwald Ligands&Precatalysts