N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide
- Product Name
- N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide
- CAS No.
- 851786-15-7
- Chemical Name
- N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide
- Synonyms
- M8104;PDT32;PDI26-2Br;N,N'-bis(2-ethylhexyl)-1,7-dibr;5,12-Dibromo-2,9-bis(2-ethylhexyl)anthra[2,1,...;N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide;5,12-dibromo-2,9-bis(2-ethylhexyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoqu;N,N'-bis(2-ethylhexyl)-1,7-dibromo-3,4,9,10-perylene tetracarboxylic diimide;N,N'-bis(2-ethylhexyl)-1,7-dibromoperylene-3,4:9,10-tetracarboxylic acid diimide;N,N'-bis(2-ethylhexyl)-1,7-dibromo-3,4,9,10-perylene tetracarboxylic diimideiimide
- CBNumber
- CB12669880
- Molecular Formula
- C40H40Br2N2O4
- Formula Weight
- 772.56
- MOL File
- 851786-15-7.mol
N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide Property
- Boiling point:
- 833.5±65.0 °C(Predicted)
- Density
- 1.461±0.06 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- pka
- -2.83±0.20(Predicted)
- Appearance
- Orange to red Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 851786157
- Product name
- 5,12-Dibromo-2,9-bis(2-ethylhexyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone
- Packaging
- 100mg
- Price
- $152.25
- Updated
- 2021/12/16
- Product number
- CD11045905
- Product name
- 5,12-Dibromo-2,9-bis(2-ethylhexyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $230
- Updated
- 2021/12/16
- Product number
- 851786157
- Product name
- 5,12-Dibromo-2,9-bis(2-ethylhexyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone
- Packaging
- 250mg
- Price
- $257.52
- Updated
- 2021/12/16
- Product number
- CD11045905
- Product name
- 5,12-Dibromo-2,9-bis(2-ethylhexyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone
- Purity
- 95+%
- Packaging
- 1g
- Price
- $574
- Updated
- 2021/12/16
- Product number
- 851786157
- Product name
- 5,12-Dibromo-2,9-bis(2-ethylhexyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone
- Packaging
- 1g
- Price
- $609
- Updated
- 2021/12/16
N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide Chemical Properties,Usage,Production
Synthesis
104-75-6
118129-60-5
851786-15-7
Part A: Preparation of N,N'-bis(2-ethylhexyl)-1,7-dibromoperylene-3,4:9,10-bis(dicarboxylic imide) (PDI2EH-Br2) 1,7-Dibromoperylene-3,4:9,10-dianhydride (PDABr2) (5.10 g, 9.35 mmol) was mixed with 2-ethylhexylamine (5.60 mL, 34.2 mmol) in propionic acid (80 mL). The reaction mixture was heated to reflux for 16 h. After cooling to room temperature, the resulting solid was collected by filtration. It was washed several times with propionic acid and then with methanol (MeOH), dried overnight and filtered to give 7.57 g of crude product. Purification by column chromatography (with CHCl3 as eluent) afforded PDI2EH-Br2 red solid (5.12 g, 6.63 mmol, yield 65.2%). Melting point >200 °C; 1H NMR (CDCl3, 500 MHz): δ 9.48 (d, 2H, J = 8.0 Hz), 8.92 (s, 2H), 8.69 (d, 2H, J = 8.0 Hz), 4.20-4.11 (m, 4H), 2.00-1.92 (m, 2H), 1.50-1.35 (m, 8H), 1.35 -1.24(m, 8H), 0.96(d, 6H, J = 7.5 Hz), 0.91(t, 6H, J = 7.0 Hz); Elemental Analysis (Calculated values: C, 62.19; H, 5.22; N, 3.63): C, 62.20; H, 5.43; N, 3.33.
References
[1] Polymer, 2010, vol. 51, # 13, p. 2897 - 2902
[2] Journal of Materials Chemistry, 2010, vol. 20, # 12, p. 2362 - 2368
[3] Macromolecules, 2011, vol. 44, # 12, p. 4767 - 4776
[4] RSC Advances, 2014, vol. 4, # 49, p. 25616 - 25624
[5] Chemical Communications, 2008, # 45, p. 6034 - 6036
N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide manufacturers
- Product
- N,N'-Bis(2-ethylhexyloxy)-1,7-dibromo-3,4,9,10-perylene diimide 851786-15-7
- Price
- US $1.10-9.90/kg
- Min. Order
- 1kg
- Purity
- 99%min
- Supply Ability
- 100kg
- Release date
- 2025-08-18
- Product
- N,N'-Bis(2-ethylhexyloxy)-1,7-dibroMo-3,4,9,10-perylene diiMide 851786-15-7
- Price
- US $0.10/KG
- Min. Order
- 1KG
- Purity
- 95%-99%
- Supply Ability
- 1kg; 50kg; 500kg
- Release date
- 2019-12-24