MONO-2-(METHACRYLOYLOXY)ETHYL SUCCINATE Property

Boiling point:

267 °C(lit.)

Density 

1.19 g/mL at 25 °C(lit.)

vapor pressure 

14hPa at 20℃

refractive index 

n20/D 1.464(lit.)

Flash point:

>230 °F

storage temp. 

2-8°C

pka

4.35±0.17(Predicted)

InChIKey

ZEWLHMQYEZXSBH-UHFFFAOYSA-N

LogP

0.782 at 23℃ and pH4.2-4.4

Surface tension

60.1mN/m at 1g/L and 21℃

EPA Substance Registry System

Butanedioic acid, mono[2-[(2-methyl-1-oxo-2-propenyl)oxy]ethyl] ester (20882-04-6)

Safety

Hazard Codes 

Xi

Risk Statements 

36/38

Safety Statements 

26-36

WGK Germany 

3

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H317May cause an allergic skin reaction

H318Causes serious eye damage

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

MONO-2-(METHACRYLOYLOXY)ETHYL SUCCINATE Chemical Properties,Usage,Production

Synthesis

mono-2-(Methacryloyloxy)ethyl succinate is prepared by the reaction of 2-Hydroxyethyl methacrylate and succinic acid anhydride. The specific synthesis steps are as follows:
10 gm of 2-hydroxyethylmethacrylate, 7.7 gm of succinic anhydride and 50 mg of hydroquinone monomethyl ether were added into a 50m1 flask with a stir bar. The flask was purged with argon, sealed and heated to 90 C with stifling for 18 hours. The flask was cooled to RT to afford mono-2-(Methacryloyloxy)ethyl succinate in quantitative yield.