4-(MethoxyMethoxy)benzoicacid
- Product Name
- 4-(MethoxyMethoxy)benzoicacid
- CAS No.
- 25458-44-0
- Chemical Name
- 4-(MethoxyMethoxy)benzoicacid
- Synonyms
- 4-(MethoxyMethoxy)benzoic;4-(MethoxyMethoxy)benzoicacid;Benzoic acid, 4-(methoxymethoxy)-
- CBNumber
- CB12696378
- Molecular Formula
- C9H10O4
- Formula Weight
- 182.17
- MOL File
- 25458-44-0.mol
4-(MethoxyMethoxy)benzoicacid Property
- Melting point:
- 70-71 °C
- Boiling point:
- 320.2±22.0 °C(Predicted)
- Density
- 1.223±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 4.34±0.10(Predicted)
- form
- solid
- Appearance
- White to off-white Solid
- InChI
- InChI=1S/C9H10O4/c1-12-6-13-8-4-2-7(3-5-8)9(10)11/h2-5H,6H2,1H3,(H,10,11)
- InChIKey
- XIFRBTZCMICRPL-UHFFFAOYSA-N
- SMILES
- C(O)(=O)C1=CC=C(OCOC)C=C1
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- CBR02123
- Product name
- 4-(Methoxymethoxy)benzoic acid
- Purity
- Aldrich<SUP>CPR</SUP>
- Packaging
- 1 g
- Price
- $179
- Updated
- 2025/07/31
- Product number
- M269530
- Product name
- 4-(Methoxymethoxy)benzoicAcid
- Packaging
- 500mg
- Price
- $110
- Updated
- 2021/12/16
- Product number
- M269530
- Product name
- 4-(Methoxymethoxy)benzoicAcid
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 6151CS
- Product name
- 4-(Methoxymethoxy)benzoicAcid
- Packaging
- 1g
- Price
- $99
- Updated
- 2021/12/16
- Product number
- OR961500
- Product name
- 4-(Methoxymethoxy)benzoicacid
- Purity
- 95%
- Packaging
- 1g
- Price
- $218
- Updated
- 2021/12/16
4-(MethoxyMethoxy)benzoicacid Chemical Properties,Usage,Production
Synthesis
107-30-2
99-96-7
25458-44-0
4-Hydroxybenzoic acid (2.00 g, 14.5 mmol) was suspended in dichloromethane (50 mL) and diisopropylethylamine (10.1 mL, 57.9 mmol) and chloromethylmethyl ether (2.20 mL, 29.0 mmol) were added sequentially under ice bath cooling. The reaction mixture was gradually warmed to room temperature with continuous stirring for 2.5 hours. Under ice bath cooling again, chloromethyl methyl ether (1.10 mL, 14.5 mmol) was added to the reaction mixture, followed by stirring at room temperature for 17 hours. After completion of the reaction, the solvent was removed by concentration under reduced pressure and methanol (50 mL) and 4 mol/L aqueous potassium hydroxide (50 mL) were added to the residue and stirred at room temperature for 3 hours. The solvent was again concentrated under reduced pressure to remove the solvent, and the residue was acidified with 4 mol/L hydrochloric acid, diluted with water and extracted with ethyl acetate. The organic phase was washed with saturated brine and dried over anhydrous sodium sulfate. The solvent was removed by concentration under reduced pressure to give white solid 4-(methoxymethyl)benzoic acid (2.63 g, 100% yield). The product was detected by ESI-MS showing m/z: 181 [M-H] ; 1H-NMR (CDCl3) δ (ppm): 3.37 (s, 3H), 5.26 (s, 2H), 7.00-7.16 (m, 2H), 7.80-7.96 (m, 2H), 12.65 (br s, 1H).
References
[1] Patent: EP2108642, 2009, A1. Location in patent: Page/Page column 122
[2] Patent: CN105593204, 2016, A. Location in patent: Paragraph 0352; 0353
[3] Patent: US2016/200662, 2016, A1. Location in patent: Paragraph 0232
[4] Patent: TWI557105, 2016, B. Location in patent: Paragraph 0237
4-(MethoxyMethoxy)benzoicacid Preparation Products And Raw materials
Raw materials
Preparation Products
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