4-Bromo-2-iodobenzaldehyde
- Product Name
- 4-Bromo-2-iodobenzaldehyde
- CAS No.
- 1261470-87-4
- Chemical Name
- 4-Bromo-2-iodobenzaldehyde
- Synonyms
- 4-Bromo-2-iodobenzaldehyde;2-IODO-4-BROMO BENZALDEHYDE;Benzaldehyde, 4-bromo-2-iodo-;4-Bromo-2-iodobenzaldehyde97%;4-Bromo-2-iodobenzaldehyde 97%
- CBNumber
- CB12696505
- Molecular Formula
- C7H4BrIO
- Formula Weight
- 310.91
- MOL File
- 1261470-87-4.mol
4-Bromo-2-iodobenzaldehyde Property
- Boiling point:
- 323.2±37.0 °C(Predicted)
- Density
- 2.231±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- powder
- color
- Off white to faint cream
- InChI
- InChI=1S/C7H4BrIO/c8-6-2-1-5(4-10)7(9)3-6/h1-4H
- InChIKey
- JFFYPBIPKMTEEQ-UHFFFAOYSA-N
- SMILES
- C(=O)C1=CC=C(Br)C=C1I
Safety
- HS Code
- 2913000090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B681413
- Product name
- 4-Bromo-2-Iodobenzaldehyde
- Packaging
- 100mg
- Price
- $90
- Updated
- 2021/12/16
- Product number
- B681413
- Product name
- 4-Bromo-2-Iodobenzaldehyde
- Packaging
- 50mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- B681413
- Product name
- 4-Bromo-2-Iodobenzaldehyde
- Packaging
- 500mg
- Price
- $330
- Updated
- 2021/12/16
- Product number
- 2692AJ
- Product name
- 4-Bromo-2-iodobenzaldehyde
- Packaging
- 5g
- Price
- $995
- Updated
- 2021/12/16
- Product number
- OR40677
- Product name
- 4-Bromo-2-iodobenzaldehyde
- Purity
- 97%
- Packaging
- 5g
- Price
- $743
- Updated
- 2021/12/16
4-Bromo-2-iodobenzaldehyde Chemical Properties,Usage,Production
Synthesis
885681-96-9
1261470-87-4
General procedure for the synthesis of 4-bromo-2-iodobenzaldehyde (17b) from 4-bromo-1-(bromomethyl)-2-iodobenzene: A solution of N-methylmorpholine-N-oxide (2.81 g, 23.2 mmol) and 4A molecular sieves (19 g) in acetonitrile (60 mL) was added to a dry 250 mL Schlenk flask under nitrogen protection and cooled to 0 °C. This was followed by rapid addition of benzyl bromide 15b (2.9 g, 7.7 mmol). The reaction mixture was kept at 0 °C for 2 h and then slowly warmed up to room temperature. Upon completion of the reaction, it was filtered through a short column of silica gel (SiO2:hexane) to afford the off-white solid product 17b (2.15 g, 6.92 mmol, 90% yield). The product was characterized as follows: 1H-NMR (400 MHz, CDCl3) δ: 9.99 (s, 1H), 8.13 (d, 1H, J = 0.8 Hz), 7.73 (dd, 1H, J = 8.3, 0.8 Hz), 7.61 (dd, 1H, J = 8.3, 0.8 Hz); 13C-NMR (100 MHz, CDCl3) δ: 194.7, 142.8, 134.1, 132.3, 131.1, 130.2, 100.9; HRMS (EI) m/z calculated value of C7H4BrIO [M?]+: 309.8490, measured value: 309.8489.
References
[1] Journal of Organic Chemistry, 2011, vol. 76, # 7, p. 2227 - 2239
[2] Synthesis, 2011, # 15, p. 2387 - 2391
[3] Patent: WO2011/127383, 2011, A2. Location in patent: Page/Page column 75
4-Bromo-2-iodobenzaldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
4-Bromo-2-iodobenzaldehyde Suppliers
- Tel
- --
- Fax
- --
- sales@apolloscientific.co.uk
- Country
- United Kingdom
- ProdList
- 6084
- Advantage
- 88
View Lastest Price from 4-Bromo-2-iodobenzaldehyde manufacturers
- Product
- 4-Bromo-2-iodobenzaldehyde 1261470-87-4
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 99%
- Supply Ability
- 200g
- Release date
- 2020-02-01