(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE

Product Name: (2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE
CAS No.: 66283-23-6
Chemical Name: (2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE
Synonyms: (2S,2''S)-(-)-2-HYDROXYMETHYL-1-[(1-METHY;2-hydroxymethyl-(1-methylpyrrolidin-2ylmethyl)pyrrolidine;(-)-2-HYDROXYMETHYL-(1-METHYLPYRROLIDIN- 2-YLME)PYRROLIDINE;(1-((1-Methylpyrrolidin-2-yl)methyl)pyrrolidin-2-yl)methanol;(2S,2S)-1-(1-Methyl-2-pyrrolidinylmethyl)pyrrolidine-2-methanol;2-PyrrolidineMethanol,1-[[(2S)-1-Methyl-2-pyrrolidinyl]Methyl]-, (2S)-;(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE;(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDINE-2-YL)-METHYL]-PYRROLIDINE
CBNumber: CB1272323
Molecular Formula: C11H22N2O
Formula Weight: 198.31
MOL File: 66283-23-6.mol

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(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE Property

Boiling point:: 275-277 °C
alpha: [α]28D -130° (c 0.36, EtOH)
refractive index: n20/D 1.494
solubility: sol hexane, toluene, Me2O, Et2O, n-Pr2O, THF, dimethoxymethane.

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: 1760
HazardClass: 8
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

American Custom Chemicals Corporation

Product number: CHM0004584
Product name: (2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE
Purity: 95.00%
Packaging: 5MG
Price: $501.06
Updated: 2021/12/16

Labseeker

Product number: SC-58427
Product name: (2S,2'S)-(-)-2-Hydroxymethyl-1-[(1-methylpyrrolidin-2-yl)-methyl]-pyrrolidine
Purity: 95
Packaging: 5g
Price: $1150
Updated: 2021/12/16

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(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE Chemical Properties,Usage,Production

Uses

(2S,2′S)-2-Hydroxymethyl-1-[(1-methylpyrrolidin-2-yl)methyl]pyrrolidine is a chiral ligand for alkyllithium, dialkylmagnesium, alkynyllithium, and functionalized organolithiums in the enantioselective addition to aldehydes; accelerates the basicity of alkyllithiums; catalyzes the addition of dialkylzinc to aldehyde.

Preparation

Preparative Method of (2S,2′S)-2-Hydroxymethyl-1-[(1-methylpyrrolidin-2-yl)methyl]pyrrolidine: reduction of N-[N(-benzyloxycarbonyl)prolyl]proline methyl ester with Lithium Aluminum Hydride affords the title reagent in 81% yield.

(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE Suppliers

China 2 France 1 Germany 2 Switzerland 1 United Kingdom 1 United States 2 Global 9

Shanghai Holy Biohemdeviser Co., Ltd

Tel: 021-61551100
Fax: 021-61551100
Country: China
ProdList: 444
Advantage: 57

66283-23-6, (2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINERelated Search:

BPP 9A Fmoc-Pro-Pro-OH (2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE BOC-PRO-PRO-OH H-PRO-PRO-PRO-OH Z-PRO-PRO-OH BRADYKININ POTENTIATOR B BIG ENDOTHELIN-2 (22-37), HUMAN GLY-PRO-HYDROXY-PRO ACETATE SALT H-GLY-PRO-HYP-OH FMOC-GLY-PRO-HYP-OH HIV (GP120) FRAGMENT (421-438) H-GLY-PRO-PRO-OH BOC-PRO-PRO-PRO-PRO-OH BRADYKININ POTENTIATOR C DOLASTATIN 15 H-PRO-PRO-PRO-PRO-OH H-ARG-PRO-PRO-OH SULFATE SALT

(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE

(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDINE-2-YL)-METHYL]-PYRROLIDINE

(-)-2-HYDROXYMETHYL-(1-METHYLPYRROLIDIN- 2-YLME)PYRROLIDINE

2-hydroxymethyl-(1-methylpyrrolidin-2ylmethyl)pyrrolidine

(2S,2S)-1-(1-Methyl-2-pyrrolidinylmethyl)pyrrolidine-2-methanol

(2S,2''S)-(-)-2-HYDROXYMETHYL-1-[(1-METHY

2-PyrrolidineMethanol,1-[[(2S)-1-Methyl-2-pyrrolidinyl]Methyl]-, (2S)-

(1-((1-Methylpyrrolidin-2-yl)methyl)pyrrolidin-2-yl)methanol

66283-23-6