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N-BENZYLPHTHALIMIDE

Product Name
N-BENZYLPHTHALIMIDE
CAS No.
2142-01-0
Chemical Name
N-BENZYLPHTHALIMIDE
Synonyms
BENZYLPHTHALIMIDE;N-BENZYLPHTALIMIDE;N-BENZYLPHTHALIMIDE;SALOR-INT L253022-1EA;Phthalimide, N-benzyl-;N-Benzylphthalimide >N-Benzylphthalimide;2-Benzylisoindoline-1,3-dione;2-Benzyl-1,3-isoindolinedione;N-BenzylphthaliMide, 98.0%(LC)
CBNumber
CB1272626
Molecular Formula
C15H11NO2
Formula Weight
237.25
MOL File
2142-01-0.mol
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N-BENZYLPHTHALIMIDE Property

Melting point:
114-116 °C(lit.)
Boiling point:
379.79°C (rough estimate)
Density 
1.3430
refractive index 
1.5500 (estimate)
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
pka
-2.12±0.20(Predicted)
color 
White to Light yellow
CAS DataBase Reference
2142-01-0(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38-22
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29251900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
404756
Product name
N-Benzylphthalimide
Purity
99%
Packaging
25g
Price
$89.5
Updated
2022/05/15
TCI Chemical
Product number
B1997
Product name
N-Benzylphthalimide
Purity
>98.0%(HPLC)
Packaging
25g
Price
$134
Updated
2024/03/01
TRC
Product number
B130190
Product name
N-Benzylphthalimide
Packaging
500mg
Price
$60
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK324016
Product name
N-Benzylphthalimide
Purity
98%
Packaging
5g
Price
$28
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK324016
Product name
N-Benzylphthalimide
Purity
98%
Packaging
25g
Price
$91
Updated
2021/12/16
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N-BENZYLPHTHALIMIDE Chemical Properties,Usage,Production

Chemical Properties

white crystalline powder

Uses

N-Benzylphthalimide may be used in the following syntheses:

  • 2-benzyl-1,1,3,3-tetraphenylisoindoline
  • tailor-made highly fluorous porphyrin derivatives
  • N-benzylisoindole

Definition

ChEBI: N-Benzylphthalimide is a member of isoindoles.

Preparation

In a flask equipped with a reflux condenser, a mixture of 300 gm (2.04 mole) of phthalimide, 140 gm (1.09 mole) of potassium carbonate, and 300 gm (2.37 mole) of benzyl chloride is refluxed for 3 hr. The excess benzyl chloride is removed by steam distillation and the benzyl phthalimide which crystallizes out is filtered by suction. The product is washed with water, with 400 ml of 60% ethanol, and then dried to afford 360-375 gm (74-77%), m.p. 116°C (recrystallized from acetic acid).

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 2, p. 83, 1943
The Journal of Organic Chemistry, 47, p. 2785, 1982 DOI: 10.1021/jo00135a021
Tetrahedron Letters, 11, p. 2691, 1970

General Description

N-Benzylphthalimide (NBPT), also known as 2-benzylisoindoline-1,3-dione, is an N-substituted phthalimide. It has been prepared by reacting phthalic anhydride with benzyl amine in glacial acetic acid. Vibrational spectra of NBPT has been recorded and assigned. NBPT is a roof-shaped molecule with a planar cyclic imide and a phenyl ring connected by a methylene group. Crystal structure of N-benzylphthalimide has parallel layers of phthalimides stack along the a axis.

N-BENZYLPHTHALIMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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N-BENZYLPHTHALIMIDE Suppliers

Creasyn Finechem(Tianjin) Co., Ltd.
Tel
022-83946278 13820503911
Fax
022-83945176
Email
sales@creasyn.com
Country
China
ProdList
982
Advantage
68
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9809
Advantage
59
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
19179
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527768850
Email
1791901229@qq.com
Country
China
ProdList
8836
Advantage
52
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
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View Lastest Price from N-BENZYLPHTHALIMIDE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
N-BENZYLPHTHALIMIDE 2142-01-0
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Career Henan Chemical Co
Product
N-BENZYLPHTHALIMIDE 2142-01-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-08

2142-01-0, N-BENZYLPHTHALIMIDERelated Search:


  • BENZYLPHTHALIMIDE
  • N-BENZYLPHTHALIMIDE
  • SALOR-INT L253022-1EA
  • N-BENZYLPHTALIMIDE
  • 4-[[[(2-chloro-4-nitrophenyl)methylamino]-oxomethyl]amino]benzenesulfonyl fluoride
  • 2-Benzyl-1,3-isoindolinedione
  • 2-Benzylisoindoline-1,3-dione
  • 2-Benzyl-1H-isoindole-1,3(2H)-dione
  • 2-(benzyl)isoindoline-1,3-quinone
  • 2-(phenylmethyl)isoindole-1,3-dione
  • 1H-Isoindole-1,3(2H)-dione, 2-(phenylMethyl)-
  • N-BenzylphthaliMide, 98.0%(LC)
  • <i>N</i>-Benzylphthalimide
  • 2-benzyl-2,3-dihydro-1H-isoindole-1,3-dione
  • N-Benzylphthalimide &gt
  • Phthalimide, N-benzyl-
  • 2-(Phenylmethyl)-1H-isoindole-1,3(2H)-dione
  • 2142-01-0
  • 2140-01-0
  • C15H11NO2
  • N-Substituted Maleimides, Succinimides & Phthalimides
  • N-Substituted Phthalimides
  • Organic Building Blocks
  • Cyclic Imides
  • Building Blocks
  • Carbonyl Compounds
  • Carbonyl Compounds
  • Cyclic Imides
  • Organic Building Blocks
  • N-Substituted Maleimides, Succinimides & Phthalimides
  • N-Substituted Phthalimides