ChemicalBook > CAS DataBase List > 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride

4,4'-(Hexafluoroisopropylidene)diphthalic anhydride

Product Name
4,4'-(Hexafluoroisopropylidene)diphthalic anhydride
CAS No.
1107-00-2
Chemical Name
4,4'-(Hexafluoroisopropylidene)diphthalic anhydride
Synonyms
6FDA;HFDA;2,2-bis(3,4-;DAIKIN YZ0002;6f-dianhydride;High purity 6FDA;4,4'-(Hexafluoroisop;6f-dianhydride(6FDA);Hexafluorodianhydride;uoropropane dianhydride
CBNumber
CB1298806
Molecular Formula
C19H6F6O6
Formula Weight
444.24
MOL File
1107-00-2.mol
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4,4'-(Hexafluoroisopropylidene)diphthalic anhydride Property

Melting point:
244-247 °C(lit.)
Boiling point:
494.5±45.0 °C(Predicted)
Density 
1.697±0.06 g/cm3(Predicted)
vapor pressure 
7.7Pa at 20℃
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
powder to crystal
color 
White to Almost white
Water Solubility 
Miscible with water.
Sensitive 
Moisture Sensitive
BRN 
7057916
InChI
InChI=1S/C19H6F6O6/c20-18(21,22)17(19(23,24)25,7-1-3-9-11(5-7)15(28)30-13(9)26)8-2-4-10-12(6-8)16(29)31-14(10)27/h1-6H
InChIKey
QHHKLPCQTTWFSS-UHFFFAOYSA-N
SMILES
C(C1C=CC2C(=O)OC(=O)C=2C=1)(C1C=CC2C(=O)OC(=O)C=2C=1)(C(F)(F)F)C(F)(F)F
LogP
5.59 at 25℃
CAS DataBase Reference
1107-00-2(CAS DataBase Reference)
EPA Substance Registry System
1,3-Isobenzofurandione, 5,5'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis- (1107-00-2)
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Safety

Hazard Codes 
C,Xi
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
1
21
Hazard Note 
Irritant
TSCA 
T
HazardClass 
8
PackingGroup 
II
HS Code 
29173990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
386448
Product name
4,4′-(Hexafluoroisopropylidene)diphthalic anhydride
Purity
99%
Packaging
5g
Price
$88.7
Updated
2024/03/01
Sigma-Aldrich
Product number
386448
Product name
4,4′-(Hexafluoroisopropylidene)diphthalic anhydride
Purity
99%
Packaging
25g
Price
$338
Updated
2024/03/01
TCI Chemical
Product number
H0771
Product name
4,4'-(Hexafluoroisopropylidene)diphthalic Anhydride
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$42
Updated
2024/03/01
TCI Chemical
Product number
H0771
Product name
4,4'-(Hexafluoroisopropylidene)diphthalic Anhydride
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$144
Updated
2024/03/01
Alfa Aesar
Product number
L16150
Product name
4,4'-(Hexafluoroisopropylidene)diphthalic anhydride, 99%
Packaging
5g
Price
$57.65
Updated
2024/03/01
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4,4'-(Hexafluoroisopropylidene)diphthalic anhydride Chemical Properties,Usage,Production

Description

4,4'-(Hexafluoroisopropylidene)diphthalic anhydride (6FDA) is an aromatic organofluorine compound that is utilized as a dianhydride monomer. It is among the most frequently used dianhydride monomers due to its exceptional balance of mechanical and electrical properties. It is particularly prominent in the construction of colorless and transparent polyimides.

Physical properties

Beige crystal

Uses

4,4'-(Hexafluoroisopropylidene) diphthalic anhydride is involved in the synthesis of polyamides derived from terphenylenes, which is used for gas separation.

Advantages

The 4,4'-(hexafluoroisopropylidene) diphthalic anhydride (6FDA) monomer contains rigid benzene ring groups, and so, the resulting polymer has excellent mechanical properties. 6FDA contained a stable benzene ring and fluorine atoms. Due to the strong electronegativity of the fluorine atoms and the stability of the benzene ring, the produced polycarbonate had better thermal stability[1-2].

Precautions

The storage precautions for 6FDA are as follows: The chemical must be stored in a cool and well-ventilated warehouse, away from sources of heat and fire. Proper sealing is required to prevent contact with air, and it should always be kept separate from oxidants, edible chemicals, and acids. The storage area should have explosion-proof lighting and ventilation facilities and must not allow any mechanical equipment or tools that may cause sparks to prevent accidents. Leakage emergency treatment equipment and suitable storage materials must be readily available in the storage area.

References

[1] Yile Zhang. “Poly(propylene carbonate) networks with excellent properties: Terpolymerization of carbon dioxide, propylene oxide, and 4,4?-(hexafluoroisopropylidene) diphthalic anhydride.” e-Polymers 21 1 (2021): 511–519.
[2] C. D. Simone, D. A. Scola. “Phenylethynyl End-Capped Polyimides Derived from 4,4‘-(2,2,2-Trifluoro-1-phenylethylidene)diphthalic Anhydride, 4,4‘-(Hexafluoroisopropylidene)diphthalic Anhydride, and 3,3‘,4,4‘-Biphenylene Dianhydride: Structure?Viscosity Relationship.” Macromolecules 36 18 (2003): 6780–6790.
[3] MARYANNE MORES Patrick E C. Polyimidines. XI. Polyimidines from 3,3′,4,4′-benzophenonetetracarboxylic dianhydride and 4,4′-(hexafluoroisopropylidene) diphthalic anhydride[J]. Journal of Polymer Science Part A: Polymer Chemistry, 1990, 28 4: 811-823. DOI:10.1002/pola.1990.080280410.
[4] HUI WU  Hezhou L Hua Li. Synthesis and Properties of a High-Molecular-Weight Polyimide Based on 4, 4’-(hexafluoroisopropylidene) Diphthalic Anhydride[J]. Advanced Materials Research, 2012, 35 1: 742-746. DOI:10.4028/www.scientific.net/AMR.550-553.742.

4,4'-(Hexafluoroisopropylidene)diphthalic anhydride Preparation Products And Raw materials

Raw materials

Preparation Products

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4,4'-(Hexafluoroisopropylidene)diphthalic anhydride Suppliers

CHINATECH(TIANJIN) CHEMICAL CO.,LTD.
Tel
138-0219-6363 18222223751
Fax
022-83726200
Email
sales7@chinatechem.com
Country
China
ProdList
65
Advantage
58
Shenzhen Feiming Science and Technology Co.,Ltd.
Tel
0755-85232577
Fax
+86-755-84594577
Email
sale@fmect.com
Country
China
ProdList
98
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62
Changzhou Sunlight Pharmaceutical Co., Ltd
Tel
0519-83131668 15995063688
Fax
+86-519-83138041
Email
info@sunlightchem.com
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China
ProdList
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69
Chengdu Yuanda chemical co.,ltd
Tel
028-85356300 18980937689
Fax
+86-28-85356300
Email
chenquanxing@126.com
Country
China
ProdList
100
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55
Yurui (Shanghai) Chemical Co., Ltd.
Tel
02150456736 13818239876
Fax
021-50761379
Email
xin@riyngroup.com
Country
China
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30
LinkChem Co.,Ltd.
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21-21-20222982 13124863828
Email
sales@linkchem.cn
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China
ProdList
2998
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SHANG FLUORO
Tel
021-021-65170832 15601903708
Email
qinba_1@163.com
Country
China
ProdList
302
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J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
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40241
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INTATRADE GmbH
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+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
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View Lastest Price from 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride manufacturers

Speranza Chemical Co., Ltd.
Product
4,4'-(Hexafluoroisopropylidene)diphthalic anhydride 1107-00-2
Price
US $25.00/KG
Min. Order
1KG
Purity
99%+
Supply Ability
100MT/year
Release date
2023-06-16
Henan Fengda Chemical Co., Ltd
Product
4,4'-(hexafluoroisopropylidene)diphthalicanhydride 1107-00-2
Price
US $158.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-05
Shanghai Daken Advanced Materials Co.,Ltd
Product
4,4'-(Hexafluoroisopropylidene)diphthalic anhydride(6FDA) 1107-00-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99.5%
Supply Ability
1500KG/month
Release date
2021-10-26

1107-00-2, 4,4'-(Hexafluoroisopropylidene)diphthalic anhydrideRelated Search:


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  • 2,2-Bis(1,3-dihydro-1,3-dioxobenzo[c]furan-5-yl)hexafluoropropane 99%
  • 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride, 5,5'-(1,1,1,3,3,3-Hexafluoropropane-2,2-diyl)bis(2-benzofuran-1,3-dione)
  • 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride SynonyMs 2,2-Bis(3,4-anhydrodicarboxyphenyl)hexafluoropropane
  • 5,5'-(Perfluoropropane-2,2-diyl)bis(isobenzofuran-1,3-dione)
  • 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride(6FDA)
  • 4,4'-(Hexafluoroisopropylidene)diphthalic Anhydride (purified by sublimation)
  • 4,4,4'-(Hexafluoroisopropylidene)diphthalic anhydride (6FDA)
  • 5-[2-(1,3-Dioxo-2-benzofuran-5-yl)-1,1,1,3,3,3-hexafluoropropan-2-yl]-2-benzofuran-1,3-dione
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  • 2,2-Bis(1,3-dihydro-1,3-dioxoisobenzofuran-5-yl)-1,1,1,3,3,3-hexafluoropropane
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  • 5,5'-(1,1,1,3,3,3-Hexafluoropropane-2,2-diyl)bis(1,3-isobenzofurandione)
  • 5,5'-[2,2,2-Trifluoro-1-(trifluoromethyl)ethylidene]bis(1,3-isobenzofurandione)
  • 2,2-Bis(1,3-dihydro-1,3-dioxobenzo[c]furan-5-yl)hex
  • 2,2'-BIS(3,4-ANHYDRODICARBOXYLPHENYL)HEXAFLUOROPROPANE
  • 2,2-BIS(3,4-ANHYDRODICARBOXYPHENYL)HEXAFLUOROPROPANE
  • 5-[1-(1,3-dioxoisobenzofuran-5-yl)-2,2,2-trifluoro-1-(trifluoromethyl)ethyl]isobenzofuran-1,3-dione
  • 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride 1107-00-2 6FDA
  • 2,2-Bis(3,4-anhydrodicarboxyphenyl)hexafluoropropane 1107-00-2 6FDA
  • HFDA
  • 2,2-BIS(3,4-DICARBOXYPHENYL)-1,1,1,3,3,3-HEXAFLUOROPROPANE DIANHYDRIDE
  • 2,2'-BIS-(3,4-DICARBOXYPHENYL)HEXAFLUOROPROPANE DIANHYDRIDE
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  • 4,4'-(HEXAFLUOROISOPROPYLIDENE)DIPHTHALIC ANHYDRIDE
  • 6f-dianhydride
  • 6FDA
  • DAIKIN YZ0002
  • 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride 99%
  • 4,4'-(Hexafluoroisopropylidene)diphthalicanhydride99%
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  • 4,4''-(Hexafluoroisopropylidene)-2,2-bis-(phthalic anhydride)
  • 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]diphthalic anhydride
  • HEXAFLUOROISOPROPYLIDENE-2,2-BISPHTHALIC ANHYDRIDE
  • 2,2'-Bis(3,4-dicarboxyphenyL
  • uoropropane dianhydride
  • 4,4’(Hexafluoroisopropylidene)Bisphthalic Dianhydride (6Fda)
  • 4,4'-(Hexafluoroisopropylidene)diphthalicAnhydride&gt
  • 4,4'-(Hexafluoroisopropylidene)diphthalicAnhydride(purifiedbysublimation)&gt
  • 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride, 99%, for synthesis
  • High purity 6FDA
  • 4,4'-(Hexafluoroisopropylidene)diphthalicanhydride,98%
  • 2,2-bis(3,4-
  • ,4'-(Hexafluoroisopropylidene)diphthalic anhydride
  • ,5'-(Hexafluoroisopropylidene)diphthalic anhydride
  • Hexafluorodianhydride (6FDA)
  • 6f-dianhydride(6FDA)
  • 2,2-Bis(3,4-anhydrodicarboxyphenyl)
  • 6f-dianhydride,4,4,-(Hexafluoroisopropylidene)diphthalic anhydride
  • Hexafluorodianhydride
  • 1107-00-2
  • C55H86N17O25S4
  • C19H6F6O6
  • Reagent for High-Performance Polymer Research
  • Bisphenol AF type Compounds (for High-Performance Polymer Research)