9-(3-Bromophenyl)-9-phenyl-9H-fluorene
Uses- Product Name
- 9-(3-Bromophenyl)-9-phenyl-9H-fluorene
- CAS No.
- 1257251-75-4
- Chemical Name
- 9-(3-Bromophenyl)-9-phenyl-9H-fluorene
- Synonyms
- 3-BPF;9-(3-Bromophenyl)-9-phenyl-fluorene;9-(3-bromophenyl)-9-phenyl-9H-fluoren;9-(3-Bromophenyl)-9-phenyl-9H-fluorene;9H-Fluorene, 9-(3-bromophenyl)-9-phenyl-;9-(3-Bromophenyl)-9-phenyl-9H-fluorene ISO 9001：2015 REACH
- CBNumber
- CB13044385
- Molecular Formula
- C25H17Br
- Formula Weight
- 397.31
- MOL File
- 1257251-75-4.mol
9-(3-Bromophenyl)-9-phenyl-9H-fluorene Property
- Melting point:
- 131.0 to 135.0 °C
- Boiling point:
- 480.5±24.0 °C(Predicted)
- Density
- 1.363±0.06 g/cm3(Predicted)
- solubility
- soluble in Toluene
- form
- powder to crystal
- color
- White to Almost white
- CAS DataBase Reference
- 1257251-75-4
Safety
- HS Code
- 2903.99.8001
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P330Rinse mouth.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- B5616
- Product name
- 9-(3-Bromophenyl)-9-phenyl-9H-fluorene
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $73
- Updated
- 2024/03/01
- Product number
- B5616
- Product name
- 9-(3-Bromophenyl)-9-phenyl-9H-fluorene
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $221
- Updated
- 2024/03/01
- Product number
- B807928
- Product name
- 9-(3-Bromophenyl)-9-phenyl-9H-fluorene
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- AS009872
- Product name
- 9-(3-Bromophenyl)-9-phenyl-9H-fluorene
- Packaging
- 25g
- Price
- $427
- Updated
- 2021/12/16
- Product number
- 1257251754
- Product name
- 9-(3-Bromophenyl)-9-phenyl-9H-fluorene
- Packaging
- 100g
- Price
- $499
- Updated
- 2021/12/16
9-(3-Bromophenyl)-9-phenyl-9H-fluorene Chemical Properties,Usage,Production
Uses
9-(3-Bromophenyl)-9-phenyl-9H-fluorene is a useful research chemical.
Description
9-(3-Bromophenyl)-9-phenyl-9H-fluorene (9-(3-bromophenyl)-9-phenylfluorene) is an important organic intermediate to synthetize its substituted products.
Synthesis
A solution of 10.0 g of 2-bromobiphenyl (42.9 mmol) in 70 ml of anhydrous THF was added to a 500 mE 3-neck flask and cooled to -78 C. 27 ml of a 1.58 M hexane solution of n-BuEi (42.9 mmol) was then added dropwise while stirring, and the reaction was stirred for about 2.5 hours. A solution of 9.30 g (35.6 mmol) of 3-bromobenzophenone in 85 mE of an anhydrous THF was added dropwise, and the resulting mixture was stirred for about 2 hours at -78 C. followed by stirring for about 3 hours at room temperature. 1 N hydrochloric acid (HC1) was then added to the mixture and stirred for about 1 hour. The mixture was washed with water, and the resultant organic phase was concentrated to afford a material having a candy-like consistency. The candy-like material, 50 ml of acetic acid, and 2.4 ml of hydrochloric acid were added to a 500 mL recovery flask, and the mixture was stirred and reacted at 130 C. under a nitrogen atmosphere for about 2 hours. After the reaction, the reaction mixture was added dropwise to 350 ml of ice-cold water, precipitating white crystals, and the crystals were isolated by filtration. The crystals were washed with methanol and allowed to dry. About 13.3 g of Compound A was obtained as a white powder (yield: about 78%).
9-(3-Bromophenyl)-9-phenyl-9H-fluorene Preparation Products And Raw materials
Raw materials
Preparation Products
9-(3-Bromophenyl)-9-phenyl-9H-fluorene Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
View Lastest Price from 9-(3-Bromophenyl)-9-phenyl-9H-fluorene manufacturers
- Product
- 9-(3-Bromophenyl)-9-phenyl-9H-fluorene 1257251-75-4
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 150KG /month
- Release date
- 2021-11-18
- Product
- 9-(3-Bromophenyl)-9-phenyl-9H-fluorene 1257251-75-4
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2024-07-19
- Product
- 9-(3-Bromophenyl)-9-phenyl-9H-fluorene 1257251-75-4
- Price
- US $200.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-01-02